REQUEST_ID SAMPLE_SITE FIELD_ID STORET_STATION SAMPLE_DATE SAMPLE_TIME SAMPLE_ID PARAM_CODE PARAM_NAME RESULT VALUE_QUAL MDL UOM PQL LAB_COMMENTS PREP_DATE PREP_TIME ANALYSIS_DATE ANALYSIS_TIME ANALYSIS_METHOD SAMPLER RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252279 Total Alkalinity 7.1 0.65 mg CaCO3/L 2.5 06-08-2021 18:24 SM 2320 B-2011 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252279 76 Turbidity 1.8 0.10 NTU 0.13 06-04-2021 15:02 EPA 180.1 Rev. 2.0 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252279 940 Chloride 5.6 0.20 mg Cl/L 0.50 06-10-2021 18:50 EPA 300.0 Rev. 2.1 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252279 80 Color (true) 58 2.5 PCU 6.0 06-04-2021 16:43 SM 2120 B-2011 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252279 951 Fluoride 0.082 I 0.035 mg F/L 0.10 06-08-2021 18:24 SM 4500 F-C-2011 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252279 945 Sulfate 4.6 0.20 mg SO4/L 0.50 06-10-2021 18:50 EPA 300.0 Rev. 2.1 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252279 70300 TDS 44 15 mg/L 25 06-08-2021 14:56 SM 2540 C-2011 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252279 530 TSS 2 I 2.0 mg/L 10 Batch relative percent difference is unavailable because of low analyte concentration in the QC sample. 06-08-2021 14:56 SM 2540 D-2011 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252280 610 Ammonia-N 0.008 0.0020 mg N/L 0.0050 06-10-2021 14:01 EPA 350.1 Rev. 2.0 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252280 630 NO2NO3-N 0.041 0.0040 mg N/L 0.010 06-07-2021 11:04 EPA 353.2 Rev. 2.0 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252280 665 Total-P 0.15 0.0050 mg P/L 0.050 06-15-2021 10:37 06-16-2021 08:35 EPA 365.1 Rev. 2.0 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252280 625 Kjeldahl Nitrogen 0.22 0.080 mg N/L 0.20 Batch matrix spike recoveries are unavailable because of high analyte concentration in the QC sample. 06-11-2021 14:07 06-14-2021 15:17 EPA 351.2 Rev. 2.0 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252280 680 Organic Carbon 4.9 0.50 mg C/L 1.0 06-10-2021 01:59 SM 5310 B-2011 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252281 671 O-Phosphate-P 0.13 0.0040 mg P/L 0.010 06-04-2021 17:42 EPA 365.1 Rev. 2.0 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 AMPA 0.10 U 0.10 ug/L 0.40 06-07-2021 08:00 06-07-2021 13:30 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 Acesulfame K 0.10 U 0.10 ug/L 0.40 06-07-2021 08:00 06-07-2021 14:06 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 Endothall 0.25 U 0.25 ug/L 1.0 06-07-2021 08:00 06-07-2021 14:06 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 Glufosinate 0.10 U 0.10 ug/L 0.40 06-07-2021 08:00 06-07-2021 13:30 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 Glyphosate 0.10 U 0.10 ug/L 0.40 06-07-2021 08:00 06-07-2021 13:30 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 Sucralose 0.66 0.010 ug/L 0.040 06-07-2021 08:00 06-07-2021 14:06 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 39740 2,4,5-T 0.0040 U 0.0040 ug/L 0.016 06-07-2021 09:00 06-12-2021 08:44 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 39730 2,4-D 0.0020 U 0.0020 ug/L 0.0080 06-07-2021 09:00 06-12-2021 08:44 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 Acetaminophen 0.0080 U 0.0080 ug/L 0.032 06-07-2021 09:00 06-12-2021 08:44 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 Acetamiprid 0.0020 U 0.0020 ug/L 0.0080 06-07-2021 09:00 06-12-2021 08:44 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 Afidopyropen 0.0020 U 0.0020 ug/L 0.0080 06-07-2021 09:00 06-12-2021 08:44 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 Bentazon 8.0E-04 U 8.0E-04 ug/L 0.0032 06-07-2021 09:00 06-12-2021 08:44 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 Benzovindiflupyr 0.0020 U 0.0020 ug/L 0.0080 06-07-2021 09:00 06-12-2021 08:44 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 Carbamazepine 8.0E-04 U 8.0E-04 ug/L 0.0032 06-07-2021 09:00 06-12-2021 08:44 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 Clothianidin 0.0020 U 0.0020 ug/L 0.0080 06-07-2021 09:00 06-12-2021 08:44 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 Dinotefuran 0.0020 U 0.0020 ug/L 0.0080 06-07-2021 09:00 06-12-2021 08:44 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 Diuron 0.0020 U 0.0020 ug/L 0.0080 06-07-2021 09:00 06-12-2021 08:44 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 Fenuron 0.016 U 0.016 ug/L 0.064 06-07-2021 09:00 06-12-2021 08:44 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 Fluridone 8.0E-04 U 8.0E-04 ug/L 0.0032 06-07-2021 09:00 06-12-2021 08:44 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 Hydrocodone 0.0020 U 0.0020 ug/L 0.0080 06-07-2021 09:00 06-12-2021 08:44 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 Ibuprofen 0.020 U 0.020 ug/L 0.080 06-07-2021 09:00 06-12-2021 08:44 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 Imazapyr 0.020 0.0040 ug/L 0.016 06-07-2021 09:00 06-12-2021 08:44 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 Imidacloprid 0.0020 U 0.0020 ug/L 0.0080 06-07-2021 09:00 06-12-2021 08:44 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 Linuron 0.0040 U 0.0040 ug/L 0.016 06-07-2021 09:00 06-12-2021 08:44 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 MCPP 0.0020 U 0.0020 ug/L 0.0080 06-07-2021 09:00 06-12-2021 08:44 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 Mandestrobin 0.0020 U 0.0020 ug/L 0.0080 06-07-2021 09:00 06-12-2021 08:44 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 Naproxen 0.0080 U 0.0080 ug/L 0.032 06-07-2021 09:00 06-12-2021 08:44 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 Primidone 0.0040 U 0.0040 ug/L 0.016 06-07-2021 09:00 06-12-2021 08:44 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 Pyraclostrobin 0.0020 U 0.0020 ug/L 0.0080 06-07-2021 09:00 06-12-2021 08:44 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 Thiamethoxam 0.0020 U 0.0020 ug/L 0.0080 06-07-2021 09:00 06-12-2021 08:44 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 Tolfenpyrad 0.0020 U 0.0020 ug/L 0.0080 06-07-2021 09:00 06-12-2021 08:44 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252287 Triclopyr 0.0040 U 0.0040 ug/L 0.016 06-07-2021 09:00 06-12-2021 08:44 EPA 8321B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252297 46570 Hardness 15.6 0.35 mg/L 1.4 06-11-2021 12:39 SM 2340B Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252297 1007 Barium 4.8 1.0 ug/L 4.0 06-09-2021 17:35 06-11-2021 12:39 EPA 200.7 Rev. 4.4 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252297 916 Calcium 4.30 0.075 mg/L 0.30 06-09-2021 17:35 06-11-2021 12:39 EPA 200.7 Rev. 4.4 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252297 1045 Iron 240 30 ug/L 120 06-09-2021 17:35 06-11-2021 12:39 EPA 200.7 Rev. 4.4 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252297 927 Magnesium 1.18 0.040 mg/L 0.16 06-09-2021 17:35 06-11-2021 12:39 EPA 200.7 Rev. 4.4 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252297 1055 Manganese 2.4 I 1.0 ug/L 4.0 06-09-2021 17:35 06-11-2021 12:39 EPA 200.7 Rev. 4.4 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252297 937 Potassium 0.30 U 0.30 mg/L 1.2 06-09-2021 17:35 06-11-2021 12:39 EPA 200.7 Rev. 4.4 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252297 929 Sodium 3.7 0.50 mg/L 2.0 06-09-2021 17:35 06-11-2021 12:39 EPA 200.7 Rev. 4.4 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252297 1092 Zinc 5.0 U 5.0 ug/L 20 06-09-2021 17:35 06-11-2021 12:39 EPA 200.7 Rev. 4.4 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252297 1105 Aluminum 118 5.0 ug/L 20 06-09-2021 17:35 06-16-2021 19:32 EPA 200.8 Rev. 5.4 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252297 1097 Antimony 0.050 U 0.050 ug/L 0.20 06-09-2021 17:35 06-16-2021 19:32 EPA 200.8 Rev. 5.4 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252297 1002 Arsenic 0.22 0.050 ug/L 0.20 06-09-2021 17:35 06-16-2021 19:32 EPA 200.8 Rev. 5.4 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252297 1012 Beryllium 0.014 I 0.010 ug/L 0.040 06-09-2021 17:35 06-16-2021 19:32 EPA 200.8 Rev. 5.4 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252297 1022 Boron 11.8 2.0 ug/L 8.0 06-09-2021 17:35 06-16-2021 19:32 EPA 200.8 Rev. 5.4 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252297 1027 Cadmium 0.020 U 0.020 ug/L 0.080 06-09-2021 17:35 06-16-2021 19:32 EPA 200.8 Rev. 5.4 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252297 1034 Chromium 0.40 U 0.40 ug/L 1.6 06-09-2021 17:35 06-16-2021 19:32 EPA 200.8 Rev. 5.4 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252297 1042 Copper 0.40 U 0.40 ug/L 0.80 06-09-2021 17:35 06-16-2021 19:32 EPA 200.8 Rev. 5.4 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252297 1051 Lead 0.20 U 0.20 ug/L 0.40 06-09-2021 17:35 06-16-2021 19:32 EPA 200.8 Rev. 5.4 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252297 1067 Nickel 0.50 U 0.50 ug/L 2.0 06-09-2021 17:35 06-16-2021 19:32 EPA 200.8 Rev. 5.4 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252297 1147 Selenium 0.20 U 0.20 ug/L 0.80 06-09-2021 17:35 06-16-2021 19:32 EPA 200.8 Rev. 5.4 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252297 1077 Silver 0.010 U 0.010 ug/L 0.040 06-09-2021 17:35 06-17-2021 15:28 EPA 200.8 Rev. 5.4 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252297 1059 Thallium 0.10 U 0.10 ug/L 0.40 06-09-2021 17:35 06-16-2021 19:32 EPA 200.8 Rev. 5.4 Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Acetochlor 0.24 U 0.24 ng/L 0.96 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Alachlor 0.24 U 0.24 ng/L 0.96 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 82184 Ametryn 0.58 U 0.58 ng/L 2.3 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 39033 Atrazine 0.24 U 0.24 ng/L 0.96 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Atrazine Desethyl 1.4 U 1.4 ng/L 5.8 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Azinphos Methyl 1.9 U 1.9 ng/L 7.7 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Azoxystrobin 0.48 U 0.48 ng/L 1.9 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Bromacil 0.48 U 0.48 ng/L 1.9 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Butylate 0.39 U 0.39 ng/L 1.5 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Caffeine 7.2 U 7.2 ng/L 29 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Carbophenothion 0.48 U 0.48 ng/L 1.9 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Carfentrazone Ethyl 0.096 U 0.096 ng/L 0.39 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 38932 Chlorpyrifos Ethyl 0.24 U 0.24 ng/L 0.96 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 38740 Chlorpyrifos Methyl 0.048 U 0.048 ng/L 0.19 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Cyanazine 3.1 U 3.1 ng/L 13 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Demeton 1.4 U 1.4 ng/L 5.8 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Diazinon 0.12 U 0.12 ng/L 0.48 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Difenoconazole 0.58 U 0.58 ng/L 2.3 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Dimethenamid 0.096 U 0.096 ng/L 0.39 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 81888 Disulfoton 0.48 U 0.48 ng/L 1.9 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Dithiopyr 0.17 U 0.17 ng/L 0.68 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 EPTC 1.2 U 1.2 ng/L 4.8 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 39398 Ethion 0.14 U 0.14 ng/L 0.58 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 81758 Ethoprop 0.096 U 0.096 ng/L 0.39 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Fenamiphos 0.48 U 0.48 ng/L 1.9 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Fenbuconazole 0.12 U 0.12 ng/L 0.48 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Fipronil 0.24 U 0.24 ng/L 0.96 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Fipronil Desulfinyl 0.12 U 0.12 ng/L 0.48 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Fipronil Sulfide 0.14 U 0.14 ng/L 0.58 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Fipronil Sulfone 0.14 U 0.14 ng/L 0.58 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Fluazifop-P-butyl 0.096 U 0.096 ng/L 0.39 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Fludioxonil 0.12 U 0.12 ng/L 0.48 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Flumioxazin 1.7 U 1.7 ng/L 6.8 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Flutolanil 0.096 U 0.096 ng/L 0.39 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Fluxapyroxad 0.096 U 0.096 ng/L 0.39 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Fonofos 0.19 U 0.19 ng/L 0.77 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 38815 Hexazinone 3.3 0.48 ng/L 1.9 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-11-2021 21:54 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Imazalil 0.72 U 0.72 ng/L 2.9 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Iprodione 0.58 U 0.58 ng/L 2.3 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 39530 Malathion 0.34 U 0.34 ng/L 1.4 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Metalaxyl 0.72 U 0.72 ng/L 2.9 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Metolachlor 0.34 U 0.34 ng/L 1.4 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 81408 Metribuzin 3.1 U 3.1 ng/L 13 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 39610 Mevinphos 1.0 U 1.0 ng/L 4.1 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Molinate 0.29 U 0.29 ng/L 1.2 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Myclobutanil 0.24 U 0.24 ng/L 0.96 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Naled 1.4 U 1.4 ng/L 5.8 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 78064 Norflurazon 0.48 U 0.48 ng/L 1.9 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Oxadiazon 0.29 U 0.29 ng/L 1.2 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Oxyfluorfen 0.14 U 0.14 ng/L 0.58 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Parathion Ethyl 0.24 U 0.24 ng/L 0.96 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Parathion Methyl 0.53 U 0.53 ng/L 2.1 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Pendimethalin 0.96 U 0.96 ng/L 3.9 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 46313 Phorate 0.51 U 0.51 ng/L 2.0 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Prodiamine 0.17 U 0.17 ng/L 0.68 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 39056 Prometon 0.87 U 0.87 ng/L 3.4 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 39057 Prometryn 0.19 U 0.19 ng/L 0.77 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Pronamide 0.14 U 0.14 ng/L 0.58 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Propiconazole 0.48 U 0.48 ng/L 1.9 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Pyriproxyfen 0.12 U 0.12 ng/L 0.48 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 39055 Simazine 0.48 U 0.48 ng/L 1.9 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Sulfentrazone 0.48 U 0.48 ng/L 1.9 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Tebuconazole 0.48 U 0.48 ng/L 1.9 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 82088 Terbufos 0.096 U 0.096 ng/L 0.39 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby RQ-2021-05-17-18 Black CR South Fork at SR 16 20030247 20030247 06-03-2021 09:30 2252300 Terbuthylazine 0.41 U 0.41 ng/L 1.6 MS accuracy for atrazine and caffeine not assessed due to high content of these parameters in the sample spiked. 06-07-2021 08:00 06-08-2021 19:18 EPA 8270E Jeremy Parrish, Kimberly Appleby