REQUEST_ID SAMPLE_SITE FIELD_ID STORET_STATION SAMPLE_DATE SAMPLE_TIME SAMPLE_ID PARAM_CODE PARAM_NAME RESULT VALUE_QUAL MDL UOM PQL LAB_COMMENTS PREP_DATE PREP_TIME ANALYSIS_DATE ANALYSIS_TIME ANALYSIS_METHOD SAMPLER RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291021 Total Alkalinity 20 0.65 mg CaCO3/L 2.5 11-24-2021 23:23 SM 2320 B-2011 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291021 76 Turbidity 3.3 0.10 NTU 0.13 11-23-2021 16:13 EPA 180.1 Rev. 2.0 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291021 940 Chloride 14 0.20 mg Cl/L 0.50 12-07-2021 00:19 EPA 300.0 Rev. 2.1 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291021 80 Color (true) 300 12 PCU 30 11-23-2021 15:44 SM 2120 B-2011 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291021 951 Fluoride 0.044 I 0.035 mg F/L 0.10 Batch matrix spike recoveries are unavailable because of high analyte concentration in the QC sample. 11-24-2021 23:23 SM 4500 F-C-2011 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291021 945 Sulfate 8.8 0.20 mg SO4/L 0.50 12-07-2021 00:19 EPA 300.0 Rev. 2.1 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291021 70300 TDS 117 15 mg/L 25 11-24-2021 14:26 SM 2540 C-2011 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291021 530 TSS 2 I 2.0 mg/L 10 Batch relative percent difference is unavailable because of low analyte concentration in the QC sample. 11-24-2021 14:26 SM 2540 D-2011 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291022 610 Ammonia-N 0.006 0.0020 mg N/L 0.0050 12-06-2021 15:09 EPA 350.1 Rev. 2.0 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291022 630 NO2NO3-N 0.004 U 0.0040 mg N/L 0.010 11-24-2021 09:44 EPA 353.2 Rev. 2.0 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291022 665 Total-P 0.028 0.0020 mg P/L 0.0050 11-24-2021 15:46 12-02-2021 12:19 EPA 365.1 Rev. 2.0 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291022 625 Kjeldahl Nitrogen 0.71 0.080 mg N/L 0.20 12-01-2021 11:50 12-03-2021 11:23 EPA 351.2 Rev. 2.0 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291022 680 Organic Carbon 30 0.50 mg C/L 1.0 11-27-2021 08:14 SM 5310 B-2011 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291023 671 O-Phosphate-P 0.004 U 0.0040 mg P/L 0.010 11-23-2021 14:33 EPA 365.1 Rev. 2.0 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 Cushing Creek at Lem Turner Rd. G4NE0306 G4NE0306 11-22-2021 13:45 2291024 Total Alkalinity 59 0.65 mg CaCO3/L 2.5 11-24-2021 23:36 SM 2320 B-2011 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 Cushing Creek at Lem Turner Rd. G4NE0306 G4NE0306 11-22-2021 13:45 2291024 76 Turbidity 1.2 0.10 NTU 0.13 11-23-2021 16:13 EPA 180.1 Rev. 2.0 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 Cushing Creek at Lem Turner Rd. G4NE0306 G4NE0306 11-22-2021 13:45 2291024 940 Chloride 21 0.20 mg Cl/L 0.50 12-07-2021 03:09 EPA 300.0 Rev. 2.1 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 Cushing Creek at Lem Turner Rd. G4NE0306 G4NE0306 11-22-2021 13:45 2291024 80 Color (true) 300 12 PCU 30 11-23-2021 15:45 SM 2120 B-2011 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 Cushing Creek at Lem Turner Rd. G4NE0306 G4NE0306 11-22-2021 13:45 2291024 951 Fluoride 0.14 0.035 mg F/L 0.10 Batch matrix spike recoveries are unavailable because of high analyte concentration in the QC sample. 11-24-2021 23:36 SM 4500 F-C-2011 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 Cushing Creek at Lem Turner Rd. G4NE0306 G4NE0306 11-22-2021 13:45 2291024 945 Sulfate 32 0.20 mg SO4/L 0.50 12-07-2021 03:09 EPA 300.0 Rev. 2.1 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 Cushing Creek at Lem Turner Rd. G4NE0306 G4NE0306 11-22-2021 13:45 2291024 70300 TDS 205 A 15 mg/L 25 11-24-2021 14:26 SM 2540 C-2011 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 Cushing Creek at Lem Turner Rd. G4NE0306 G4NE0306 11-22-2021 13:45 2291024 530 TSS 2 UA 2.0 mg/L 10 Batch relative percent difference is unavailable because of low analyte concentration in the QC sample. 11-24-2021 14:26 SM 2540 D-2011 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 Cushing Creek at Lem Turner Rd. G4NE0306 G4NE0306 11-22-2021 13:45 2291025 610 Ammonia-N 0.004 I 0.0020 mg N/L 0.0050 12-06-2021 15:11 EPA 350.1 Rev. 2.0 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 Cushing Creek at Lem Turner Rd. G4NE0306 G4NE0306 11-22-2021 13:45 2291025 630 NO2NO3-N 0.004 U 0.0040 mg N/L 0.010 11-24-2021 09:46 EPA 353.2 Rev. 2.0 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 Cushing Creek at Lem Turner Rd. G4NE0306 G4NE0306 11-22-2021 13:45 2291025 665 Total-P 0.052 0.0020 mg P/L 0.0050 11-24-2021 15:46 12-02-2021 12:20 EPA 365.1 Rev. 2.0 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 Cushing Creek at Lem Turner Rd. G4NE0306 G4NE0306 11-22-2021 13:45 2291025 625 Kjeldahl Nitrogen 0.66 0.080 mg N/L 0.20 12-01-2021 11:50 12-03-2021 11:25 EPA 351.2 Rev. 2.0 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 Cushing Creek at Lem Turner Rd. G4NE0306 G4NE0306 11-22-2021 13:45 2291025 680 Organic Carbon 29 0.50 mg C/L 1.0 11-27-2021 08:25 SM 5310 B-2011 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 Cushing Creek at Lem Turner Rd. G4NE0306 G4NE0306 11-22-2021 13:45 2291026 671 O-Phosphate-P 0.024 0.0040 mg P/L 0.010 11-23-2021 14:34 EPA 365.1 Rev. 2.0 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291033 46570 Hardness 43.3 0.35 mg/L 1.4 12-01-2021 17:26 SM 2340B Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291033 916 Calcium 11.7 0.075 mg/L 0.30 Batch matrix spike recoveries for calcium are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-01-2021 17:26 EPA 200.7 Rev. 4.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291033 1045 Iron 940 30 ug/L 120 Batch matrix spike recoveries for calcium are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-01-2021 17:26 EPA 200.7 Rev. 4.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291033 927 Magnesium 3.43 0.040 mg/L 0.16 Batch matrix spike recoveries for calcium are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-01-2021 17:26 EPA 200.7 Rev. 4.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291033 937 Potassium 1.4 0.30 mg/L 1.2 Batch matrix spike recoveries for calcium are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-01-2021 17:26 EPA 200.7 Rev. 4.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291033 929 Sodium 8.6 0.50 mg/L 2.0 Batch matrix spike recoveries for calcium are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-01-2021 17:26 EPA 200.7 Rev. 4.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291033 1082 Strontium 45.3 2.0 ug/L 8.0 Batch matrix spike recoveries for calcium are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-01-2021 17:26 EPA 200.7 Rev. 4.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291033 1102 Tin 3.0 U 3.0 ug/L 12 Batch matrix spike recoveries for calcium are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-01-2021 17:26 EPA 200.7 Rev. 4.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291033 1152 Titanium 2.4 I 0.75 ug/L 3.0 Batch matrix spike recoveries for calcium are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-01-2021 17:26 EPA 200.7 Rev. 4.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291033 1087 Vanadium 2.0 U 2.0 ug/L 8.0 Batch matrix spike recoveries for calcium are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-01-2021 17:26 EPA 200.7 Rev. 4.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291033 1092 Zinc 5.1 I 5.0 ug/L 20 Batch matrix spike recoveries for calcium are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-01-2021 17:26 EPA 200.7 Rev. 4.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291033 1105 Aluminum 427 5.0 ug/L 20 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-06-2021 14:32 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291033 1097 Antimony 0.057 I 0.050 ug/L 0.20 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-03-2021 17:20 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291033 1002 Arsenic 0.51 0.050 ug/L 0.20 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-03-2021 17:20 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291033 1007 Barium 28.2 0.20 ug/L 0.80 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-03-2021 17:20 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291033 1012 Beryllium 0.042 0.010 ug/L 0.040 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-03-2021 17:20 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291033 1022 Boron 23.7 2.0 ug/L 8.0 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-03-2021 17:20 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291033 1027 Cadmium 0.020 U 0.020 ug/L 0.080 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-03-2021 17:20 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291033 1034 Chromium 0.74 I 0.40 ug/L 1.6 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-03-2021 17:20 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291033 1037 Cobalt 0.228 0.020 ug/L 0.080 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-03-2021 17:20 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291033 1042 Copper 0.42 I 0.40 ug/L 0.80 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-03-2021 17:20 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291033 1051 Lead 0.50 0.20 ug/L 0.40 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-03-2021 17:20 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291033 1055 Manganese 26.6 0.10 ug/L 0.40 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-03-2021 17:20 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291033 1062 Molybdenum 0.15 U 0.15 ug/L 0.60 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-03-2021 17:20 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291033 1067 Nickel 0.56 I 0.50 ug/L 2.0 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-03-2021 17:20 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291033 1147 Selenium 0.20 U 0.20 ug/L 0.80 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-03-2021 17:20 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291033 1077 Silver 0.010 U 0.010 ug/L 0.040 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-03-2021 17:20 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 LITTLE ST. MARYS @ CR 121A 19010046 19010046 11-22-2021 10:50 2291033 1059 Thallium 0.10 U 0.10 ug/L 0.40 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-06-2021 14:32 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 MILLS CREEK AT US 301/US1 19020048 19020048 11-22-2021 12:10 2291034 46570 Hardness 17.9 0.35 mg/L 1.4 12-01-2021 17:34 SM 2340B Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 MILLS CREEK AT US 301/US1 19020048 19020048 11-22-2021 12:10 2291034 916 Calcium 4.59 0.075 mg/L 0.30 Batch matrix spike recoveries for calcium are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-01-2021 17:34 EPA 200.7 Rev. 4.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 MILLS CREEK AT US 301/US1 19020048 19020048 11-22-2021 12:10 2291034 1045 Iron 1.49E+03 30 ug/L 120 Batch matrix spike recoveries for calcium are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-01-2021 17:34 EPA 200.7 Rev. 4.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 MILLS CREEK AT US 301/US1 19020048 19020048 11-22-2021 12:10 2291034 927 Magnesium 1.57 0.040 mg/L 0.16 Batch matrix spike recoveries for calcium are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-01-2021 17:34 EPA 200.7 Rev. 4.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 MILLS CREEK AT US 301/US1 19020048 19020048 11-22-2021 12:10 2291034 937 Potassium 1.8 0.30 mg/L 1.2 Batch matrix spike recoveries for calcium are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-01-2021 17:34 EPA 200.7 Rev. 4.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 MILLS CREEK AT US 301/US1 19020048 19020048 11-22-2021 12:10 2291034 929 Sodium 7.0 0.50 mg/L 2.0 Batch matrix spike recoveries for calcium are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-01-2021 17:34 EPA 200.7 Rev. 4.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 MILLS CREEK AT US 301/US1 19020048 19020048 11-22-2021 12:10 2291034 1082 Strontium 20.6 2.0 ug/L 8.0 Batch matrix spike recoveries for calcium are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-01-2021 17:34 EPA 200.7 Rev. 4.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 MILLS CREEK AT US 301/US1 19020048 19020048 11-22-2021 12:10 2291034 1102 Tin 3.0 U 3.0 ug/L 12 Batch matrix spike recoveries for calcium are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-01-2021 17:34 EPA 200.7 Rev. 4.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 MILLS CREEK AT US 301/US1 19020048 19020048 11-22-2021 12:10 2291034 1152 Titanium 1.3 I 0.75 ug/L 3.0 Batch matrix spike recoveries for calcium are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-01-2021 17:34 EPA 200.7 Rev. 4.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 MILLS CREEK AT US 301/US1 19020048 19020048 11-22-2021 12:10 2291034 1087 Vanadium 2.0 U 2.0 ug/L 8.0 Batch matrix spike recoveries for calcium are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-01-2021 17:34 EPA 200.7 Rev. 4.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 MILLS CREEK AT US 301/US1 19020048 19020048 11-22-2021 12:10 2291034 1092 Zinc 5.0 U 5.0 ug/L 20 Batch matrix spike recoveries for calcium are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-01-2021 17:34 EPA 200.7 Rev. 4.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 MILLS CREEK AT US 301/US1 19020048 19020048 11-22-2021 12:10 2291034 1105 Aluminum 449 5.0 ug/L 20 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-06-2021 14:38 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 MILLS CREEK AT US 301/US1 19020048 19020048 11-22-2021 12:10 2291034 1097 Antimony 0.050 U 0.050 ug/L 0.20 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-03-2021 17:29 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 MILLS CREEK AT US 301/US1 19020048 19020048 11-22-2021 12:10 2291034 1002 Arsenic 0.48 0.050 ug/L 0.20 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-03-2021 17:29 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 MILLS CREEK AT US 301/US1 19020048 19020048 11-22-2021 12:10 2291034 1007 Barium 18.8 0.20 ug/L 0.80 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-03-2021 17:29 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 MILLS CREEK AT US 301/US1 19020048 19020048 11-22-2021 12:10 2291034 1012 Beryllium 0.029 I 0.010 ug/L 0.040 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-03-2021 17:29 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 MILLS CREEK AT US 301/US1 19020048 19020048 11-22-2021 12:10 2291034 1022 Boron 20.1 2.0 ug/L 8.0 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-03-2021 17:29 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 MILLS CREEK AT US 301/US1 19020048 19020048 11-22-2021 12:10 2291034 1027 Cadmium 0.020 U 0.020 ug/L 0.080 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-03-2021 17:29 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 MILLS CREEK AT US 301/US1 19020048 19020048 11-22-2021 12:10 2291034 1034 Chromium 0.59 I 0.40 ug/L 1.6 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-03-2021 17:29 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 MILLS CREEK AT US 301/US1 19020048 19020048 11-22-2021 12:10 2291034 1037 Cobalt 0.349 0.020 ug/L 0.080 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-03-2021 17:29 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 MILLS CREEK AT US 301/US1 19020048 19020048 11-22-2021 12:10 2291034 1042 Copper 0.40 U 0.40 ug/L 0.80 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-03-2021 17:29 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 MILLS CREEK AT US 301/US1 19020048 19020048 11-22-2021 12:10 2291034 1051 Lead 0.48 0.20 ug/L 0.40 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-03-2021 17:29 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 MILLS CREEK AT US 301/US1 19020048 19020048 11-22-2021 12:10 2291034 1055 Manganese 25.2 0.10 ug/L 0.40 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-03-2021 17:29 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 MILLS CREEK AT US 301/US1 19020048 19020048 11-22-2021 12:10 2291034 1062 Molybdenum 0.15 U 0.15 ug/L 0.60 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-03-2021 17:29 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 MILLS CREEK AT US 301/US1 19020048 19020048 11-22-2021 12:10 2291034 1067 Nickel 0.55 I 0.50 ug/L 2.0 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-03-2021 17:29 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 MILLS CREEK AT US 301/US1 19020048 19020048 11-22-2021 12:10 2291034 1147 Selenium 0.20 U 0.20 ug/L 0.80 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-03-2021 17:29 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 MILLS CREEK AT US 301/US1 19020048 19020048 11-22-2021 12:10 2291034 1077 Silver 0.010 U 0.010 ug/L 0.040 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-03-2021 17:29 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger RQ-2021-11-22-07 MILLS CREEK AT US 301/US1 19020048 19020048 11-22-2021 12:10 2291034 1059 Thallium 0.10 U 0.10 ug/L 0.40 Batch matrix spike recoveries for molybdenum are unavailable for one of two spiked samples because of high analyte concentration in the QC sample. 11-30-2021 10:30 12-06-2021 14:38 EPA 200.8 Rev. 5.4 Kimberly Appleby, Katrin Villinger