REQUEST_ID|JOB_ID|SAMPLE_ID|SAMPLE_SITE|FIELD_ID|SAMPLE_DATE|SAMPLE_TIME|ANALYSIS_DATE|ANALYSIS_TIME|PARAM_CODE|PARAM_NAME|RESULT|VALUE_QUAL|UOM|MDL|PQL|PREP_METHOD|PREP_DESC|PREP_DATE|PREP_TIME|ANALYSIS_METHOD|SAMPLER|LAB_COMMENTS
RQ-2024-03-04-66|TLH-2024-03-06-59|2473682|BLUE LAKE AT CENTER|G4SD0157|05-MAR-2024|11:40|08-MAR-2024|07:11||Total Alkalinity|17||mg CaCO3/L|0.65|2.5|||||SM 2320 B-2011|Nicole R, Emily A|
RQ-2024-03-04-66|TLH-2024-03-06-59|2473682|BLUE LAKE AT CENTER|G4SD0157|05-MAR-2024|11:40|06-MAR-2024|13:15|76|Turbidity|4.7|A|NTU|0.10|1.0|||||EPA 180.1 Rev. 2.0|Nicole R, Emily A|
RQ-2024-03-04-66|TLH-2024-03-06-59|2473682|BLUE LAKE AT CENTER|G4SD0157|05-MAR-2024|11:40|09-MAR-2024|09:19|940|Chloride|19||mg Cl/L|0.20|0.50|||||EPA 300.0 Rev. 2.1|Nicole R, Emily A|
RQ-2024-03-04-66|TLH-2024-03-06-59|2473682|BLUE LAKE AT CENTER|G4SD0157|05-MAR-2024|11:40|06-MAR-2024|14:31|80|Color (true)|13||PCU|2.5|6.0|||||DEP SOP: NU-094-1|Nicole R, Emily A|
RQ-2024-03-04-66|TLH-2024-03-06-59|2473682|BLUE LAKE AT CENTER|G4SD0157|05-MAR-2024|11:40|08-MAR-2024|07:11|951|Fluoride|0.025|U|mg F/L|0.025|0.10|||||SM 4500-F- C-2011|Nicole R, Emily A|
RQ-2024-03-04-66|TLH-2024-03-06-59|2473682|BLUE LAKE AT CENTER|G4SD0157|05-MAR-2024|11:40|09-MAR-2024|09:19|945|Sulfate|22||mg SO4/L|0.20|0.50|||||EPA 300.0 Rev. 2.1|Nicole R, Emily A|
RQ-2024-03-04-66|TLH-2024-03-06-59|2473682|BLUE LAKE AT CENTER|G4SD0157|05-MAR-2024|11:40|08-MAR-2024|13:20|70300|TDS|98||mg/L|15|25|||||SM 2540 C-2015|Nicole R, Emily A|
RQ-2024-03-04-66|TLH-2024-03-06-59|2473682|BLUE LAKE AT CENTER|G4SD0157|05-MAR-2024|11:40|08-MAR-2024|13:20|530|TSS|3|I|mg/L|2.0|10|||||SM 2540 D-2015|Nicole R, Emily A|Batch relative percent difference is unavailable because of low analyte concentration in the QC sample.
RQ-2024-03-04-66|TLH-2024-03-06-59|2473683|BLUE LAKE AT CENTER|G4SD0157|05-MAR-2024|11:40|08-MAR-2024|13:28|610|Ammonia-N|0.002|U|mg N/L|0.0020|0.0050|||||EPA 350.1 Rev. 2.0|Nicole R, Emily A|
RQ-2024-03-04-66|TLH-2024-03-06-59|2473683|BLUE LAKE AT CENTER|G4SD0157|05-MAR-2024|11:40|08-MAR-2024|15:03|630|NO2NO3-N|0.004|U|mg N/L|0.0040|0.010|||||EPA 353.2 Rev. 2.0|Nicole R, Emily A|
RQ-2024-03-04-66|TLH-2024-03-06-59|2473683|BLUE LAKE AT CENTER|G4SD0157|05-MAR-2024|11:40|14-MAR-2024|13:25|665|Total-P|0.026||mg P/L|0.0020|0.0050|365.1 (MARCH 1983)|Automated, ascorbic acid|08-MAR-2024|12:35|EPA 365.1 Rev. 2.0|Nicole R, Emily A|
RQ-2024-03-04-66|TLH-2024-03-06-59|2473683|BLUE LAKE AT CENTER|G4SD0157|05-MAR-2024|11:40|12-MAR-2024|10:34|625|Kjeldahl Nitrogen|0.80||mg N/L|0.080|0.20|351.2 (MARCH 1983)|Preparation of samples for total kjeldahl nitrogen analysis|08-MAR-2024|14:09|EPA 351.2 Rev. 2.0|Nicole R, Emily A|
RQ-2024-03-04-66|TLH-2024-03-06-59|2473683|BLUE LAKE AT CENTER|G4SD0157|05-MAR-2024|11:40|07-MAR-2024|16:43|680|Organic Carbon|7.5||mg C/L|0.50|1.0|||||SM 5310 B-2014|Nicole R, Emily A|
RQ-2024-03-04-66|TLH-2024-03-06-59|2473684|LAKEPLACIDOUTLETATSR70W|G4SD0213|05-MAR-2024|12:15|08-MAR-2024|07:23||Total Alkalinity|9.1||mg CaCO3/L|0.65|2.5|||||SM 2320 B-2011|Nicole R, Emily A|
RQ-2024-03-04-66|TLH-2024-03-06-59|2473684|LAKEPLACIDOUTLETATSR70W|G4SD0213|05-MAR-2024|12:15|06-MAR-2024|13:17|76|Turbidity|3.9||NTU|0.10|1.0|||||EPA 180.1 Rev. 2.0|Nicole R, Emily A|
RQ-2024-03-04-66|TLH-2024-03-06-59|2473684|LAKEPLACIDOUTLETATSR70W|G4SD0213|05-MAR-2024|12:15|09-MAR-2024|07:18|940|Chloride|15|A|mg Cl/L|0.20|0.50|||||EPA 300.0 Rev. 2.1|Nicole R, Emily A|
RQ-2024-03-04-66|TLH-2024-03-06-59|2473684|LAKEPLACIDOUTLETATSR70W|G4SD0213|05-MAR-2024|12:15|06-MAR-2024|14:46|80|Color (true)|360||PCU|7.5|18|||||DEP SOP: NU-094-1|Nicole R, Emily A|
RQ-2024-03-04-66|TLH-2024-03-06-59|2473684|LAKEPLACIDOUTLETATSR70W|G4SD0213|05-MAR-2024|12:15|08-MAR-2024|07:23|951|Fluoride|0.089|I|mg F/L|0.025|0.10|||||SM 4500-F- C-2011|Nicole R, Emily A|
RQ-2024-03-04-66|TLH-2024-03-06-59|2473684|LAKEPLACIDOUTLETATSR70W|G4SD0213|05-MAR-2024|12:15|09-MAR-2024|07:18|945|Sulfate|19|A|mg SO4/L|0.20|0.50|||||EPA 300.0 Rev. 2.1|Nicole R, Emily A|
RQ-2024-03-04-66|TLH-2024-03-06-59|2473684|LAKEPLACIDOUTLETATSR70W|G4SD0213|05-MAR-2024|12:15|08-MAR-2024|13:20|70300|TDS|146||mg/L|15|25|||||SM 2540 C-2015|Nicole R, Emily A|
RQ-2024-03-04-66|TLH-2024-03-06-59|2473684|LAKEPLACIDOUTLETATSR70W|G4SD0213|05-MAR-2024|12:15|08-MAR-2024|13:20|530|TSS|2|U|mg/L|2.0|10|||||SM 2540 D-2015|Nicole R, Emily A|Batch relative percent difference is unavailable because of low analyte concentration in the QC sample.
RQ-2024-03-04-66|TLH-2024-03-06-59|2473685|LAKEPLACIDOUTLETATSR70W|G4SD0213|05-MAR-2024|12:15|11-MAR-2024|11:38|610|Ammonia-N|0.023|Y|mg N/L|0.0020|0.0050|||||EPA 350.1 Rev. 2.0|Nicole R, Emily A|The sample was received unpreserved: pH > 2. Sample preserved in laboratory.
RQ-2024-03-04-66|TLH-2024-03-06-59|2473685|LAKEPLACIDOUTLETATSR70W|G4SD0213|05-MAR-2024|12:15|08-MAR-2024|15:09|630|NO2NO3-N|0.10|Y|mg N/L|0.0040|0.010|||||EPA 353.2 Rev. 2.0|Nicole R, Emily A|The sample was received unpreserved: pH > 2. Sample preserved in laboratory.
RQ-2024-03-04-66|TLH-2024-03-06-59|2473685|LAKEPLACIDOUTLETATSR70W|G4SD0213|05-MAR-2024|12:15|11-MAR-2024|12:34|665|Total-P|1.3|Y|mg P/L|0.050|0.25|365.1 (MARCH 1983)|Automated, ascorbic acid|08-MAR-2024|12:35|EPA 365.1 Rev. 2.0|Nicole R, Emily A|Total-P: The sample was received unpreserved: pH > 2. Sample preserved in laboratory.
RQ-2024-03-04-66|TLH-2024-03-06-59|2473685|LAKEPLACIDOUTLETATSR70W|G4SD0213|05-MAR-2024|12:15|12-MAR-2024|10:36|625|Kjeldahl Nitrogen|1.5|Y|mg N/L|0.080|0.20|351.2 (MARCH 1983)|Preparation of samples for total kjeldahl nitrogen analysis|08-MAR-2024|14:09|EPA 351.2 Rev. 2.0|Nicole R, Emily A|The sample was received unpreserved: pH > 2. Sample preserved in laboratory.
RQ-2024-03-04-66|TLH-2024-03-06-59|2473685|LAKEPLACIDOUTLETATSR70W|G4SD0213|05-MAR-2024|12:15|07-MAR-2024|16:58|680|Organic Carbon|31|Y|mg C/L|0.50|1.0|||||SM 5310 B-2014|Nicole R, Emily A|The sample was received unpreserved: pH > 2. Sample preserved in laboratory.
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|08-MAR-2024|19:13||AMPA|0.10|U|ug/L|0.10|0.40|LC-FILTER|Filtration of samples prior to analysis|08-MAR-2024|12:00|EPA 8321B|Nicole R, Emily A|
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|09-MAR-2024|07:00||Acesulfame K|0.10|U|ug/L|0.10|0.40|LC-FILTER|Filtration of samples prior to analysis|08-MAR-2024|12:00|EPA 8321B|Nicole R, Emily A|
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|08-MAR-2024|19:13||Endothall|0.25|U|ug/L|0.25|1.0|LC-FILTER|Filtration of samples prior to analysis|08-MAR-2024|12:00|EPA 8321B|Nicole R, Emily A|
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|08-MAR-2024|19:13||Glufosinate|0.10|U|ug/L|0.10|0.40|LC-FILTER|Filtration of samples prior to analysis|08-MAR-2024|12:00|EPA 8321B|Nicole R, Emily A|
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|08-MAR-2024|19:13||Glyphosate|0.10|U|ug/L|0.10|0.40|LC-FILTER|Filtration of samples prior to analysis|08-MAR-2024|12:00|EPA 8321B|Nicole R, Emily A|
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|09-MAR-2024|07:00||Sucralose|0.040|I|ug/L|0.010|0.040|LC-FILTER|Filtration of samples prior to analysis|08-MAR-2024|12:00|EPA 8321B|Nicole R, Emily A|
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|09-MAR-2024|07:16|39740|2,4,5-T|0.0040|U|ug/L|0.0040|0.016|3535A|Prep for herbicides and carbamates|08-MAR-2024|13:00|EPA 8321B|Nicole R, Emily A|MS accuracy for some analytes could not be assessed due to high concentration of parameter in the spiked sample.
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|09-MAR-2024|07:16|39730|2,4-D|0.0020|U|ug/L|0.0020|0.0080|3535A|Prep for herbicides and carbamates|08-MAR-2024|13:00|EPA 8321B|Nicole R, Emily A|MS accuracy for some analytes could not be assessed due to high concentration of parameter in the spiked sample.
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|09-MAR-2024|07:16||Acetaminophen|0.0080|U|ug/L|0.0080|0.032|3535A|Prep for herbicides and carbamates|08-MAR-2024|13:00|EPA 8321B|Nicole R, Emily A|MS accuracy for some analytes could not be assessed due to high concentration of parameter in the spiked sample.
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|09-MAR-2024|07:16||Acetamiprid|0.0020|U|ug/L|0.0020|0.0080|3535A|Prep for herbicides and carbamates|08-MAR-2024|13:00|EPA 8321B|Nicole R, Emily A|MS accuracy for some analytes could not be assessed due to high concentration of parameter in the spiked sample.
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|09-MAR-2024|07:16||Afidopyropen|0.0020|U|ug/L|0.0020|0.0080|3535A|Prep for herbicides and carbamates|08-MAR-2024|13:00|EPA 8321B|Nicole R, Emily A|MS accuracy for some analytes could not be assessed due to high concentration of parameter in the spiked sample.
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|09-MAR-2024|07:16||Bentazon|0.039||ug/L|8.0E-04|0.0032|3535A|Prep for herbicides and carbamates|08-MAR-2024|13:00|EPA 8321B|Nicole R, Emily A|MS accuracy for some analytes could not be assessed due to high concentration of parameter in the spiked sample.
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|09-MAR-2024|07:16||Benzovindiflupyr|0.0020|U|ug/L|0.0020|0.0080|3535A|Prep for herbicides and carbamates|08-MAR-2024|13:00|EPA 8321B|Nicole R, Emily A|MS accuracy for some analytes could not be assessed due to high concentration of parameter in the spiked sample.
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|09-MAR-2024|07:16||Carbamazepine|8.0E-04|U|ug/L|8.0E-04|0.0032|3535A|Prep for herbicides and carbamates|08-MAR-2024|13:00|EPA 8321B|Nicole R, Emily A|MS accuracy for some analytes could not be assessed due to high concentration of parameter in the spiked sample.
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|09-MAR-2024|07:16||Clothianidin|0.018||ug/L|0.0020|0.0080|3535A|Prep for herbicides and carbamates|08-MAR-2024|13:00|EPA 8321B|Nicole R, Emily A|MS accuracy for some analytes could not be assessed due to high concentration of parameter in the spiked sample.
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|09-MAR-2024|07:16||Dinotefuran|0.0020|U|ug/L|0.0020|0.0080|3535A|Prep for herbicides and carbamates|08-MAR-2024|13:00|EPA 8321B|Nicole R, Emily A|MS accuracy for some analytes could not be assessed due to high concentration of parameter in the spiked sample.
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|09-MAR-2024|07:16||Diuron|0.0020|U|ug/L|0.0020|0.0080|3535A|Prep for herbicides and carbamates|08-MAR-2024|13:00|EPA 8321B|Nicole R, Emily A|MS accuracy for some analytes could not be assessed due to high concentration of parameter in the spiked sample.
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|09-MAR-2024|07:16||Fenuron|0.032|U|ug/L|0.032|0.13|3535A|Prep for herbicides and carbamates|08-MAR-2024|13:00|EPA 8321B|Nicole R, Emily A|MS accuracy for some analytes could not be assessed due to high concentration of parameter in the spiked sample.
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|09-MAR-2024|07:16||Fluridone|8.0E-04|U|ug/L|8.0E-04|0.0032|3535A|Prep for herbicides and carbamates|08-MAR-2024|13:00|EPA 8321B|Nicole R, Emily A|MS accuracy for some analytes could not be assessed due to high concentration of parameter in the spiked sample.
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|09-MAR-2024|07:16||Hydrocodone|0.0020|U|ug/L|0.0020|0.0080|3535A|Prep for herbicides and carbamates|08-MAR-2024|13:00|EPA 8321B|Nicole R, Emily A|MS accuracy for some analytes could not be assessed due to high concentration of parameter in the spiked sample.
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|09-MAR-2024|07:16||Ibuprofen|0.080|U|ug/L|0.080|0.32|3535A|Prep for herbicides and carbamates|08-MAR-2024|13:00|EPA 8321B|Nicole R, Emily A|MS accuracy for some analytes could not be assessed due to high concentration of parameter in the spiked sample.
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|09-MAR-2024|07:16||Imazapyr|0.0040|U|ug/L|0.0040|0.016|3535A|Prep for herbicides and carbamates|08-MAR-2024|13:00|EPA 8321B|Nicole R, Emily A|MS accuracy for some analytes could not be assessed due to high concentration of parameter in the spiked sample.
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|09-MAR-2024|07:16||Imidacloprid|0.016||ug/L|0.0020|0.0080|3535A|Prep for herbicides and carbamates|08-MAR-2024|13:00|EPA 8321B|Nicole R, Emily A|MS accuracy for some analytes could not be assessed due to high concentration of parameter in the spiked sample.
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|09-MAR-2024|07:16||Linuron|0.0040|U|ug/L|0.0040|0.016|3535A|Prep for herbicides and carbamates|08-MAR-2024|13:00|EPA 8321B|Nicole R, Emily A|MS accuracy for some analytes could not be assessed due to high concentration of parameter in the spiked sample.
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|09-MAR-2024|07:16||MCPP|0.0020|U|ug/L|0.0020|0.0080|3535A|Prep for herbicides and carbamates|08-MAR-2024|13:00|EPA 8321B|Nicole R, Emily A|MS accuracy for some analytes could not be assessed due to high concentration of parameter in the spiked sample.
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|09-MAR-2024|07:16||Mandestrobin|0.0020|U|ug/L|0.0020|0.0080|3535A|Prep for herbicides and carbamates|08-MAR-2024|13:00|EPA 8321B|Nicole R, Emily A|MS accuracy for some analytes could not be assessed due to high concentration of parameter in the spiked sample.
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|09-MAR-2024|07:16||Naproxen|0.0080|U|ug/L|0.0080|0.032|3535A|Prep for herbicides and carbamates|08-MAR-2024|13:00|EPA 8321B|Nicole R, Emily A|MS accuracy for some analytes could not be assessed due to high concentration of parameter in the spiked sample.
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|09-MAR-2024|07:16||Primidone|0.0040|U|ug/L|0.0040|0.016|3535A|Prep for herbicides and carbamates|08-MAR-2024|13:00|EPA 8321B|Nicole R, Emily A|MS accuracy for some analytes could not be assessed due to high concentration of parameter in the spiked sample.
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|09-MAR-2024|07:16||Pyraclostrobin|0.0020|U|ug/L|0.0020|0.0080|3535A|Prep for herbicides and carbamates|08-MAR-2024|13:00|EPA 8321B|Nicole R, Emily A|MS accuracy for some analytes could not be assessed due to high concentration of parameter in the spiked sample.
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|09-MAR-2024|07:16|39760|Silvex|0.0040|U|ug/L|0.0040|0.016|3535A|Prep for herbicides and carbamates|08-MAR-2024|13:00|EPA 8321B|Nicole R, Emily A|MS accuracy for some analytes could not be assessed due to high concentration of parameter in the spiked sample.
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|09-MAR-2024|07:16||Thiamethoxam|0.078||ug/L|0.0020|0.0080|3535A|Prep for herbicides and carbamates|08-MAR-2024|13:00|EPA 8321B|Nicole R, Emily A|MS accuracy for some analytes could not be assessed due to high concentration of parameter in the spiked sample.
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|09-MAR-2024|07:16||Tolfenpyrad|0.0020|U|ug/L|0.0020|0.0080|3535A|Prep for herbicides and carbamates|08-MAR-2024|13:00|EPA 8321B|Nicole R, Emily A|MS accuracy for some analytes could not be assessed due to high concentration of parameter in the spiked sample.
RQ-2024-03-04-66|TLH-2024-03-06-63|2473692|BONNET CREEK AT SR 64|G4SD0107|05-MAR-2024|10:15|09-MAR-2024|07:16||Triclopyr|0.0040|U|ug/L|0.0040|0.016|3535A|Prep for herbicides and carbamates|08-MAR-2024|13:00|EPA 8321B|Nicole R, Emily A|MS accuracy for some analytes could not be assessed due to high concentration of parameter in the spiked sample.