Printed: 2/14/2020 3:47:13 PM 
Analysis List 
Page 1 of 2 
Analysis ID: W-PFAS-MS 
Perfluorinated alkyl substances in water matrices by HPLC/MS/MS 
Group ID: 
CHEMISTRY 
Charge Code: 
A 220.00 
Scheduler Matrix: 
Water 
Analysis Group: 
LC-Water 
Modified: 
28-JAN-2020 14:08 by WATTS_J 
Method: 
EPA 8321B 
Prep ID: 
3535A (PFAS) 
Removed: 
No 
Scheduler Group: 
Pesticides 
ADaPT Prep ID: 
3535 
Work Factor: 
1 
Scheduler Section: 
CHEMISTRY 
Prep Expires: 28 00:00:00.00 
Visible: 
T 
QC Group: 
QC_LC_WATER 
Expected Time: 30 00:00:00.00 
This analysis does not use % solid. 
Bottle Information 
Group: 
**NONE** - Bottle Group 'None' 
Preservative: 
ICE 
Container 1: 
P-125ML HDPE PFAS - 125ml HDPE bottle for PFAS (2-bagged) Volume: 
Bottle QC: 
QC used: Lower limit: 1; 
Analysis Volume: 
250 mL 
Container 2: 
Bottle is not shared. 
Hazard Text: 
Template ID: 
**Master List** -
Targ/Surr 
ADaPT 
Component 
Units 
MDL 
PQL 
Targ/Surr 
Assn 
Cas # 
Haz Level 
NELAP 
ADaPT Name 
ADaPT Units 
ADaPT Method 
T/D 
4:2 Fluorotelomer sulfonate (4:2 
ng/L 
2 
8 
T 
467 
757124-72 
N 
4:2 Fluorotelomer sulfonate 
ng/L 
EPA 8321 mod. 
T 
FTS) 
(4:2 FTS) 
6:2 Fluorotelomer sulfonate (6:2 
ng/L 
4 
16 
T 
467 
27619-97-2 
N 
6:2 Fluorotelomer sulfonate 
ng/L 
EPA 8321 mod. 
T 
FTS) 
(6:2 FTS) 
8:2 Fluorotelomer sulfonate (8:2 
ng/L 
2 
8 
T 
468 
39108-34-4 
N 
8:2 Fluorotelomer sulfonate 
ng/L 
EPA 8321 mod. 
T 
FTS) 
(8:2 FTS) 
Hexafluoropropylene oxide dimer 
ng/L 
1 
4 
T 
495 
13252-13-6 
N 
Hexafluoropropylene oxide 
ng/L 
EPA 8321 mod. 
T 
acid 
dimer acid 
Hexafluoropropylene oxide dimer 
ng/L 
1.6 
6.4 
S 
495 
DEP-SURR-108 
N 
Hexafluoropropylene oxide 
ng/L 
EPA 8321 mod. 
T 
acid-13C 
dimer acid-13C 
N-Et perfluorooctanesulfonamidoAc 
ng/L 
0.4 
1.6 
T 
468 
2991-50-6 
N 
N-Et 
ng/L 
EPA 8321 mod. 
T 
acid 
perfluorooctanesulfonamidoAc 
acid 
N-Me 
ng/L 
0.4 
1.6 
T 
468 
2355-31-9 
N 
N-Me 
ng/L 
EPA 8321 mod. 
T 
perfluorooctanesulfonamidoAc acid 
perfluorooctanesulfonamidoAc 
acid 
Perfluorobutanesulfonate-13C 
ng/L 
1.6 
6.4 
S 
467 
DEP-SURR-105 
N 
Perfluorobutanesulfonate-13C 
ng/L 
EPA 8321 mod. 
T 
Perfluorobutanesulfonic acid 
ng/L 
0.4 
1.6 
T 
467 
375-73-5 
N 
Perfluorobutanesulfonic acid 
ng/L 
EPA 8321 mod. 
T 
(PFBS) 
(PFBS) 
Perfluorodecanesulfonic acid 
ng/L 
0.4 
1.6 
T 
468 
335-77-3 
N 
Perfluorodecanesulfonic acid 
ng/L 
EPA 8321 mod. 
T 
(PFDS) 
(PFDS) 
Perfluorodecanoic acid (PFDA) 
ng/L 
1 
4 
T 
466 
335-76-2 
N 
Perfluorodecanoic acid 
ng/L 
EPA 8321 mod. 
T 
(PFDA) 
Perfluorodecanoic acid-13C 
ng/L 
1.6 
6.4 
S 
466 
DEP-SURR-104 
N 
Perfluorodecanoic acid-13C 
ng/L 
EPA 8321 mod. 
T 
Perfluorododecanoic acid (PFDoA) 
ng/L 
1 
4 
T 
466 
307-55-1 
N 
Perfluorododecanoic acid 
ng/L 
EPA 8321 mod. 
T 
(PFDoA) 
Perfluoroheptanesulfonic acid 
ng/L 
0.4 
1.6 
T 
468 
375-92-8 
N 
Perfluoroheptanesulfonic acid 
ng/L 
EPA 8321 mod. 
T 
(PFHpS) 
(PFHpS) 
Perfluoroheptanoic acid (PFHpA) 
ng/L 
0.4 
1.6 
T 
465 
375-85-9 
N 
Perfluoroheptanoic acid 
ng/L 
EPA 8321 mod. 
T 
(PFHpA) 
Perfluorohexanesulfonate-13C 
ng/L 
1.6 
6.4 
S 
468 
DEP-SURR-106 
N 
Perfluorohexanesulfonate-13C 
ng/L 
EPA 8321 mod. 
T 
Perfluorohexanesulfonic acid 
ng/L 
0.4 
1.6 
T 
468 
355-46-4 
N 
Perfluorohexanesulfonic acid 
ng/L 
EPA 8321 mod. 
T 
(PFHxS) 
(PFHxS) 
Perfluorohexanoic acid (PFHxA) 
ng/L 
1 
4 
T 
465 
307-24-4 
N 
Perfluorohexanoic acid 
ng/L 
EPA 8321 mod. 
T 
(PFHxA) 



Printed: 2/14/2020 3:47:13 PM 
Analysis List 
Page 2 of 2 
Component 
Units 
MDL 
PQL 
Targ/Surr 
Targ/Surr 
Assn 
Cas # 
Haz Level 
NELAP 
ADaPT Name 
ADaPT Units 
ADaPT Method 
ADaPT 
T/D 
Perfluorohexanoic acid-13C 
ng/L 
1.6 
6.4 
S 
465 
DEP-SURR-103 
N 
Perfluorohexanoic acid-13C 
ng/L 
EPA 8321 mod. 
T 
Perfluorononanesulfonic acid 
ng/L 
0.4 
1.6 
T 
468 
68259-12-1 
N 
Perfluorononanesulfonic acid 
ng/L 
EPA 8321 mod. 
T 
(PFNS) 
(PFNS) 
Perfluorononanoic acid (PFNA) 
ng/L 
1 
4 
T 
465 
375-95-1 
N 
Perfluorononanoic acid 
ng/L 
EPA 8321 mod. 
T 
(PFNA) 
Perfluorooctanesulfonic acid 
ng/L 
2 
8 
T 
468 
1763-23-1 
N 
Perfluorooctanesulfonic acid 
ng/L 
EPA 8321 mod. 
T 
(PFOS) 
(PFOS) 
Perfluorooctanoic acid (PFOA) 
ng/L 
1 
4 
T 
465 
335-67-1 
N 
Perfluorooctanoic acid (PFOA) 
ng/L 
EPA 8321 mod. 
T 
Perfluoropentanesulfonic acid 
ng/L 
0.4 
1.6 
T 
467 
2706-91-4 
N 
Perfluoropentanesulfonic acid 
ng/L 
EPA 8321 mod. 
T 
(PFPeS) 
(PFPeS) 
Perfluoropentanoic acid (PFPeA) 
ng/L 
4 
16 
T 
465 
2706-90-3 
N 
Perfluoropentanoic acid 
ng/L 
EPA 8321 mod. 
T 
(PFPeA) 
Perfluorotetradecanoic acid 
ng/L 
0.4 
1.6 
T 
466 
376-06-7 
N 
Perfluorotetradecanoic acid 
ng/L 
EPA 8321 mod. 
T 
(PFTeA) 
(PFTeA) 
Perfluorotridecanoic acid (PFTriA) 
ng/L 
0.4 
1.6 
T 
466 
72629-94-8 
N 
Perfluorotridecanoic acid 
ng/L 
EPA 8321 mod. 
T 
(PFTriA) 
Perfluoroundecanoic acid (PFUnA) 
ng/L 
1 
4 
T 
466 
2058-94-8 
N 
Perfluoroundecanoic acid 
ng/L 
EPA 8321 mod. 
T 
(PFUnA)