SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 1 of 93 Chemical Analysis Report SIS-2009-08-06-01 Florida Department of Environmental Protection Florida Department of Environmental Protection Central Laboratory Innovation Park Laboratory 2600 Blair Stone Road 2051 E. Paul Dirac Dr. Tallahassee, FL 32399-2400 Tallahassee, FL 32310 DOH Accreditation E31780 DOH Accreditation E31640 Overflow Analyses Performed By: Florida Radiochemistry Services, Inc. 5456 Hoffner Ave., Suite 201 Orlando, FL 32812 DOH Accreditation E83033 Event Description: Acreage Sampling PBC Request ID: RQ-2009-08-03-46 Customer: SIS Project ID: SIS-INVEST Send Reports to: For additional information please contact FL Dept. of Environmental Protection Timothy W. Fitzpatrick 2600 Blair Stone Road Liang-Tsair Lin, Ph.D. Twin Towers Bldg. MS# 4515 Colin Wright, Ph.D. Tallahassee, FL 32399 Kathryn Brackett Attn: Bill Martin Andrew R. Tintle, QA Officer Phone (850) 245-8085 Certified by: Timothy Fitzpatrick, Program Administrator Date Certified: 31-AUG-2009 14:55 NON-CONFORMANCE REPORT INCLUDED SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 2 of 93 Abbreviations and data remark codes CERT # - NELAP (National Environmental Laboratory Accreditation Program) Certification Number of the laboratory that performed the analysis. LCS – Laboratory Control Sample; in the QC Failures column, this notation indicates a batch recovery failure. MS – Matrix Spike; in the QC Failures column, this notation indicates a batch recovery failure. RPD – Relative Percent Difference; in the QC Failures column, this notation indicates a batch failure for precision. CCV – Continuing Calibration Verification; in the QC Failures column, this notation indicates a failure of the calibration verification check sample. RSD – Relative Standard Deviation expressed as a percentage. SMP – Sample. * - Item was outside the QC Limits. ** - The laboratory is not NELAP certified for this analyte/method, or certification is not applicable. A - Value reported is the mean of two or more determinations B - Results based on colony counts outside the acceptable range. I - The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. J - Estimated value K - Actual value is known to be less than value given L - Actual value is known to be greater than value given N - Presumptive evidence of presence of material. O - Sampled, but analysis lost or not performed. Q - Sample held beyond normal holding time. T - Value reported is less than the criterion of detection. U - Material was analyzed for but not detected. The reported value is the method detection limit for the sample analyzed. V - Analyte was detected in both sample and method blank. X - Too few individuals to calculate SCI value. Y - The laboratory analysis was from an unpreserved or improperly preserved sample. The data may not be accurate Z - Colonies were too numerous to count (TNTC). Precision is reported as relative percent difference unless otherwise noted. Uncertainty associated with the analytical results contained in this report can be estimated from the reported quality assurance results and from published test performance acceptance criteria. Unless otherwise noted, analytical values for soil and sediment samples are reported on a dry weight basis, and analytical values for waste and tissue samples are reported on a wet weight basis. All sample collection performed by Bureau of Laboratories staff followed the field Standard Operating Procedures adopted by reference in Rule 62-160 FAC unless otherwise noted. Quality control information from overflow laboratories may not be included in this report. Please refer to the associated report from the overflow laboratory for additional information. Results for NELAP accredited tests contained in this report meet the requirements specified by the National Environmental Laboratory Accreditation Conference (NELAC). All samples received were in acceptable condition and met NELAC requirements unless otherwise noted. Results generated in this report pertain to the samples collected and submitted for analysis. Job: TLH-2009-08-06-28 Group: Overflow Job: TLH-2009-08-06-63 Group: Overflow Job: TLH-2009-08-06-64 Group: Priority Organic Pollutants Job: TLH-2009-08-06-65 Group: Pesticides Job: TLH-2009-08-06-68 Group: Priority Organic Pollutants Job: TLH-2009-08-06-71 Group: Pesticides Job: TLH-2009-08-06-75 Group: Metals Job: TLH-2009-08-06-76 Group: Nutrients SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 3 of 93 Sample Location: ACREAGE Collection Date/Time: 08/04/2009 03:20 PM Field ID: 1 Z-16441 87th LN N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 1206580 EPA 900.0 Alpha, Total 7.1 pCi/L E83033 Alpha-Counting Error 1.7 pCi/L 1206598 EPA 522 1,4-Dioxane** 0.43 I ug/L E31640 1206616 EPA 8260C Benzene 0.20 U ug/L Bromodichloromethane 0.20 U ug/L Bromoform 0.50 UJ LCS ug/L Bromomethane 0.50 UJ CCV,MS ug/L 2-Butanone 10 U ug/L Carbon tetrachloride 0.20 U ug/L Chlorobenzene 0.20 U ug/L Chloroethane 0.50 U MS ug/L Chloroform 0.20 U ug/L Chloromethane 0.50 U MS ug/L Dibromochloromethane 0.20 U ug/L 1,2-Dichlorobenzene 0.50 U ug/L 1,3-Dichlorobenzene 0.50 U ug/L 1,4-Dichlorobenzene 0.50 U ug/L 1,1-Dichloroethane 0.20 U ug/L 1,2-Dichloroethane 0.20 U ug/L 1,1-Dichloroethene 0.50 U ug/L cis-1,2-Dichloroethene 0.50 U ug/L trans-1,2-Dichloroethene 0.50 U ug/L 1,2-Dichloropropane 0.50 U ug/L cis-1,3-Dichloropropene 0.50 U MS ug/L trans-1,3-Dichloropropene 0.20 UJ LCS,MS ug/L Ethylbenzene 0.50 U ug/L Methylene chloride 0.50 U ug/L 1,1,2,2-Tetrachloroethane 0.50 UJ CCV ug/L Tetrachloroethene 0.50 U ug/L Toluene 0.50 U ug/L 1,1,1-Trichloroethane 0.20 U ug/L 1,1,2-Trichloroethane 0.20 U ug/L Trichloroethene 0.20 UJ CCV ug/L Trichlorofluoromethane 0.50 U ug/L Vinyl chloride 0.50 U ug/L Methyl-t-butyl ether 0.50 U ug/L o-Xylene 0.20 U ug/L m,p-Xylene 0.50 U ug/L 1206634 DEP SOP: LC-001-2 2,4-D 0.20 U ug/L E31780 2,4,5-T 0.20 U ug/L Acifluorfen 0.20 U ug/L Silvex 0.20 U ug/L 1206656 EPA 8270D Acenaphthene 0.97 U ug/L Acenaphthylene 0.97 U ug/L Acetophenone 0.97 U ug/L 2-Acetylaminofluorene 0.97 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 4 of 93 Field ID: 1 Z-16441 87th LN N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 4-Aminobiphenyl Aniline Anthracene Azobenzene/1,2-Diphenylhydrazine Benzidine Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(k)fluoranthene Benzo(g,h,i)perylene Benzyl alcohol Bis(2-chloroethoxy)methane Bis(2-chloroethyl)ether Bis(2-chloroisopropyl)ether Bis(2-ethylhexyl)phthalate Butyl benzyl phthalate 4-Bromophenyl phenyl ether 4-Chloroaniline 2-Chloronaphthalene 4-Chlorophenyl phenyl ether Chrysene m,p-Cresols o-Cresol Di-n-butyl phthalate Di-n-octyl phthalate Dibenzo(a,h)anthracene Dibenzofuran 3,3'-Dichlorobenzidine Diethyl phthalate Dimethyl phthalate Dimethylaminoazobenzene 7,12-Dimethylbenz(a)anthracene 3,3'-Dimethylbenzidine 1,3-Dinitrobenzene 2,4-Dinitrotoluene 2,6-Dinitrotoluene Dinoseb** Ethyl methanesulfonate Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Hexachloropropene Indeno(1,2,3-cd)pyrene Isophorone Isosafrole Methapyrilene 3.9 0.97 0.97 0.97 97 0.97 0.97 0.97 0.97 0.97 0.97 0.97 0.97 2.9 14 4.8 0.97 0.97 0.97 1.9 0.97 1.9 1.9 4.8 0.97 0.97 0.97 39 0.97 9.7 0.97 0.97 19 1.9 0.97 0.97 3.9 0.97 0.97 0.97 0.97 2.9 2.9 2.9 1.9 0.97 0.97 0.97 3.9 U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U UJ CCV,LCS ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 5 of 93 Field ID: 1 Z-16441 87th LN N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 3-Methylcholanthrene 0.97 U ug/L Methyl methanesulfonate 0.97 UJ CCV ug/L 2-Methylnaphthalene 0.97 U ug/L Naphthalene 0.97 U ug/L 1-Naphthylamine 9.7 U ug/L 2-Naphthylamine 9.7 U MS ug/L 1,4-Naphthoquinone 19 UJ CCV ug/L 2-Nitroaniline 0.97 U ug/L 3-Nitroaniline 0.97 U ug/L 4-Nitroaniline 0.97 UJ CCV ug/L Nitrobenzene 1.9 U ug/L Nitroquinoline-1-oxide 19 U ug/L 5-Nitro-o-toluidine 0.97 U ug/L N-Nitrosodiethylamine 0.97 U ug/L N-Nitrosodimethylamine 1.9 U ug/L N-Nitrosodi-n-propylamine 1.9 U ug/L N-Nitrosomethylethylamine 1.9 U ug/L N-Nitrosomorpholine 0.97 U ug/L N-Nitrosopiperidine 0.97 U ug/L N-Nitrosopyrrolidine 1.9 U ug/L Pentachlorobenzene 0.97 U ug/L Pentachloroethane** 48 U ug/L Pentachloronitrobenzene 0.97 U ug/L Phenacetin 3.9 U ug/L Phenanthrene 0.97 U ug/L 2-Picoline 0.97 U ug/L Pyrene 0.97 U ug/L Pyridine 3.9 U ug/L Safrole 0.97 U ug/L 1,2,4,5-Tetrachlorobenzene 0.97 U ug/L o-Toluidine 0.97 U ug/L 1,2,4-Trichlorobenzene 0.97 U ug/L 1,3,5-Trinitrobenzene 3.9 U ug/L 4-Chloro-3-methylphenol 0.97 U ug/L 2-Chlorophenol 0.97 U ug/L 2,4-Dichlorophenol 0.97 U ug/L 2,6-Dichlorophenol 0.97 U ug/L 2,4-Dimethylphenol 9.7 U ug/L 2,4-Dinitrophenol 14 U ug/L 2-Methyl-4,6-dinitrophenol 2.9 U ug/L 2-Nitrophenol 0.97 U ug/L 4-Nitrophenol 14 U ug/L Pentachlorophenol 2.9 U ug/L Phenol 0.97 U ug/L 2,3,4,6-Tetrachlorophenol 1.9 U ug/L 2,4,5-Trichlorophenol 0.97 U ug/L 2,4,6-Trichlorophenol 0.97 U ug/L N-Nitrosodiphenylamine/ Diphenylamine 2.9 U ug/L 1206674 FL-PRO TRPH 0.24 U mg/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 6 of 93 Field ID: 1 Z-16441 87th LN N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 1206702 EPA 504 1,2-Dibromoethane 0.010 U ug/L 1206720 DEP SOP: GC-011-5 (based on EPA Methods 608, 617, 1656) Aldrin Alpha-BHC 0.0098 0.0098 U U ug/L ug/L Beta-BHC 0.0098 U ug/L Delta-BHC 0.0098 U ug/L Gamma-BHC 0.0098 U ug/L Chlordane 0.20 U ug/L DDD-p,p' 0.020 U ug/L DDE-p,p' 0.020 U ug/L DDT-p,p' 0.029 U ug/L Dieldrin 0.020 U ug/L Endosulfan I 0.020 U ug/L Endosulfan II 0.020 U ug/L Endosulfan Sulfate 0.020 U ug/L Endrin 0.049 U ug/L Endrin Aldehyde 0.020 U ug/L Heptachlor 0.0098 U ug/L Heptachlor Epoxide 0.020 U ug/L Methoxychlor 0.049 U ug/L Toxaphene 0.73 U ug/L PCB-1016 0.20 U ug/L PCB-1221 0.20 U ug/L PCB-1232 0.20 U ug/L PCB-1242 0.29 U ug/L PCB-1248 0.20 U ug/L PCB-1254 0.29 U ug/L PCB-1260 0.20 U ug/L DEP SOP: GC-012-3 (based on EPA 614, 619, 622, 633 and 507) Alachlor Ametryn 0.59 0.049 UJ U CCV ug/L ug/L Atrazine 0.049 U ug/L Azinphos Methyl 0.20 UJ CCV ug/L Bromacil 0.20 U ug/L Butylate 0.20 UJ CCV ug/L Chlorpyrifos Ethyl 0.049 U ug/L Chlorpyrifos Methyl 0.098 U ug/L Diazinon 0.049 U ug/L Ethion 0.049 U ug/L Ethoprop 0.098 U ug/L Fenamiphos 0.20 U ug/L Fonofos 0.098 U ug/L Hexazinone 0.098 UJ CCV ug/L Malathion 0.15 U ug/L Metalaxyl 0.24 UJ CCV ug/L Metolachlor 0.49 UJ CCV ug/L Metribuzin 0.098 U ug/L Mevinphos 0.20 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 7 of 93 Field ID: 1 Z-16441 87th LN N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Naled 0.78 U ug/L Norflurazon 0.15 UJ CCV ug/L Parathion Ethyl 0.15 U ug/L Parathion Methyl 0.098 U ug/L Phorate 0.049 U ug/L Prometon 0.20 U ug/L Prometryn 0.15 U ug/L Simazine 0.049 U ug/L 1206756 EPA 6010C Strontium 622 ug/L Titanium 0.50 I ug/L EPA 6020A Aluminum 58 ug/L Arsenic 0.25 U ug/L Barium 13.8 ug/L Cadmium 0.030 U ug/L Chromium 0.42 I ug/L Copper 0.50 U ug/L Lead 0.20 U ug/L Selenium 0.20 U ug/L Silver 0.025 U ug/L EPA 7470A Mercury 0.12 U MS ug/L 1206774 EPA 353.2 Rev. 2.0 NO2NO3-N 0.004 I mg N/L Ref. Method and Comment: EPA 8260C QC failure(s) observed. EPA 8270D QC failure(s) observed. FL-PRO Insufficient sample to perform matrix spikes. DEP SOP: GC-011-5 (based on EPA Methods 608, 617, 1656) Insufficient sample to perform MS duplicate due to loss of sample in sample preparation. DEP SOP: GC-012-3 (based on EPA 614, 619, 622, 633 and 507) Insufficient sample to perform MS duplicate due to loss of sample in sample preparation. QC failure(s) observed. Sample Location: ACREAGE Collection Date/Time: 08/04/2009 03:05 PM Field ID: 1 Z-17895 80th St. N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 1206579 EPA 900.0 Alpha, Total 2.9 pCi/L E83033 Alpha-Counting Error 1.8 pCi/L 1206597 EPA 522 1,4-Dioxane** 0.20 U ug/L E31640 1206615 EPA 8260C Benzene 0.20 U ug/L Bromodichloromethane 0.20 U ug/L Bromoform 0.50 UJ LCS ug/L Bromomethane 0.50 UJ CCV,MS ug/L 2-Butanone 10 U ug/L Carbon tetrachloride 0.20 U ug/L Chlorobenzene 0.20 U ug/L Chloroethane 0.50 U MS ug/L Chloroform 0.20 U ug/L Chloromethane 0.50 U MS ug/L Dibromochloromethane 0.20 U ug/L 1,2-Dichlorobenzene 0.50 U ug/L 1,3-Dichlorobenzene 0.50 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 8 of 93 Field ID: 1 Z-17895 80th St. N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 1,4-Dichlorobenzene 0.50 U ug/L 1,1-Dichloroethane 0.20 U ug/L 1,2-Dichloroethane 0.20 U ug/L 1,1-Dichloroethene 0.50 U ug/L cis-1,2-Dichloroethene 0.50 U ug/L trans-1,2-Dichloroethene 0.50 U ug/L 1,2-Dichloropropane 0.50 U ug/L cis-1,3-Dichloropropene 0.50 U MS ug/L trans-1,3-Dichloropropene 0.20 UJ LCS,MS ug/L Ethylbenzene 0.50 U ug/L Methylene chloride 0.50 U ug/L 1,1,2,2-Tetrachloroethane 0.50 UJ CCV ug/L Tetrachloroethene 0.50 U ug/L Toluene 0.50 U ug/L 1,1,1-Trichloroethane 0.20 U ug/L 1,1,2-Trichloroethane 0.20 U ug/L Trichloroethene 0.20 UJ CCV ug/L Trichlorofluoromethane 0.50 U ug/L Vinyl chloride 0.50 U ug/L Methyl-t-butyl ether 0.50 U ug/L o-Xylene 0.20 U ug/L m,p-Xylene 0.50 U ug/L 1206633 DEP SOP: LC-001-2 2,4-D 0.21 U ug/L E31780 2,4,5-T 0.21 U ug/L Acifluorfen 0.21 U ug/L Silvex 0.21 U ug/L 1206655 EPA 8270D Acenaphthene 0.97 U ug/L Acenaphthylene 0.97 U ug/L Acetophenone 0.97 U ug/L 2-Acetylaminofluorene 0.97 U ug/L 4-Aminobiphenyl 3.9 U MS ug/L Aniline 0.97 U ug/L Anthracene 0.97 U ug/L Azobenzene/1,2-Diphenylhydrazine 0.97 U ug/L Benzidine 97 U ug/L Benzo(a)anthracene 0.97 U ug/L Benzo(a)pyrene 0.97 U ug/L Benzo(b)fluoranthene 0.97 U ug/L Benzo(k)fluoranthene 0.97 U ug/L Benzo(g,h,i)perylene 0.97 U ug/L Benzyl alcohol 0.97 U ug/L Bis(2-chloroethoxy)methane 0.97 U ug/L Bis(2-chloroethyl)ether 0.97 U ug/L Bis(2-chloroisopropyl)ether 2.9 U ug/L Bis(2-ethylhexyl)phthalate 15 U ug/L Butyl benzyl phthalate 4.9 U ug/L 4-Bromophenyl phenyl ether 0.97 U ug/L 4-Chloroaniline 0.97 U ug/L 2-Chloronaphthalene 0.97 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 9 of 93 Field ID: 1 Z-17895 80th St. N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 4-Chlorophenyl phenyl ether Chrysene m,p-Cresols o-Cresol Di-n-butyl phthalate Di-n-octyl phthalate Dibenzo(a,h)anthracene Dibenzofuran 3,3'-Dichlorobenzidine Diethyl phthalate Dimethyl phthalate Dimethylaminoazobenzene 7,12-Dimethylbenz(a)anthracene 3,3'-Dimethylbenzidine 1,3-Dinitrobenzene 2,4-Dinitrotoluene 2,6-Dinitrotoluene Dinoseb** Ethyl methanesulfonate Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Hexachloropropene Indeno(1,2,3-cd)pyrene Isophorone Isosafrole Methapyrilene 3-Methylcholanthrene Methyl methanesulfonate 2-Methylnaphthalene Naphthalene 1-Naphthylamine 2-Naphthylamine 1,4-Naphthoquinone 2-Nitroaniline 3-Nitroaniline 4-Nitroaniline Nitrobenzene Nitroquinoline-1-oxide 5-Nitro-o-toluidine N-Nitrosodiethylamine N-Nitrosodimethylamine N-Nitrosodi-n-propylamine N-Nitrosomethylethylamine N-Nitrosomorpholine N-Nitrosopiperidine 1.9 0.97 1.9 1.9 4.9 0.97 0.97 0.97 39 0.97 9.7 0.97 0.97 19 1.9 0.97 0.97 3.9 0.97 0.97 0.97 0.97 2.9 2.9 2.9 1.9 0.97 0.97 0.97 3.9 0.97 0.97 0.97 0.97 9.7 9.7 19 0.97 0.97 0.97 1.9 19 0.97 0.97 1.9 1.9 1.9 0.97 0.97 U U U U U UJ U U U U U U U U U U U U U U U U U U U U U U U UJ U UJ U U U U UJ U U UJ U U U U U U U U U CCV LCS CCV MS MS CCV,MS CCV MS,RPD ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 10 of 93 SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 10 of 93 Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # N-Nitrosopyrrolidine 1.9 U ug/L Pentachlorobenzene 0.97 U ug/L Pentachloroethane** 49 U ug/L Pentachloronitrobenzene 0.97 U ug/L Phenacetin 3.9 U ug/L Phenanthrene 0.97 U ug/L 2-Picoline 0.97 U ug/L Pyrene 0.97 U ug/L Pyridine 3.9 U ug/L Safrole 0.97 U ug/L 1,2,4,5-Tetrachlorobenzene 0.97 U ug/L o-Toluidine 0.97 U ug/L 1,2,4-Trichlorobenzene 0.97 U ug/L 1,3,5-Trinitrobenzene 3.9 U ug/L 4-Chloro-3-methylphenol 0.97 U ug/L 2-Chlorophenol 0.97 U ug/L 2,4-Dichlorophenol 0.97 U ug/L 2,6-Dichlorophenol 0.97 U ug/L 2,4-Dimethylphenol 9.7 U ug/L 2,4-Dinitrophenol 15 U ug/L 2-Methyl-4,6-dinitrophenol 2.9 U ug/L 2-Nitrophenol 0.97 U ug/L 4-Nitrophenol 15 U ug/L Pentachlorophenol 2.9 U ug/L Phenol 0.97 U ug/L 2,3,4,6-Tetrachlorophenol 1.9 U ug/L 2,4,5-Trichlorophenol 0.97 U ug/L 2,4,6-Trichlorophenol 0.97 U ug/L N-Nitrosodiphenylamine/ Diphenylamine 2.9 U ug/L 1206673 FL-PRO TRPH 0.25 U mg/L 1206701 EPA 504 1,2-Dibromoethane 0.010 U ug/L 1206719 DEP SOP: GC-011-5 (based Aldrin 0.0096 U ug/L on EPA Methods 608, 617, 1656) Alpha-BHC 0.0096 U ug/L Beta-BHC 0.0096 U ug/L Delta-BHC 0.0096 U ug/L Gamma-BHC 0.0096 U ug/L Chlordane 0.19 U ug/L DDD-p,p' 0.019 U ug/L DDE-p,p' 0.019 U ug/L DDT-p,p' 0.029 U ug/L Dieldrin 0.019 U ug/L Endosulfan I 0.019 U ug/L Endosulfan II 0.019 U ug/L Endosulfan Sulfate 0.019 U ug/L Endrin 0.048 U ug/L Endrin Aldehyde 0.019 U ug/L Heptachlor 0.0096 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 11 of 93 Field ID: 1 Z-17895 80th St. N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Heptachlor Epoxide 0.019 U ug/L Methoxychlor 0.048 U ug/L Toxaphene 0.72 U ug/L PCB-1016 0.19 U ug/L PCB-1221 0.19 U ug/L PCB-1232 0.19 U ug/L PCB-1242 0.29 U ug/L PCB-1248 0.19 U ug/L PCB-1254 0.29 U ug/L PCB-1260 0.19 U ug/L DEP SOP: GC-012-3 (based Alachlor 0.58 UJ CCV ug/L on EPA 614, 619, 622, 633 and 507) Ametryn 0.048 U ug/L Atrazine 0.048 U ug/L Azinphos Methyl 0.19 UJ CCV ug/L Bromacil 0.19 U ug/L Butylate 0.19 UJ CCV ug/L Chlorpyrifos Ethyl 0.048 U ug/L Chlorpyrifos Methyl 0.096 U ug/L Diazinon 0.048 U ug/L Ethion 0.048 U ug/L Ethoprop 0.096 U ug/L Fenamiphos 0.19 U ug/L Fonofos 0.096 U ug/L Hexazinone 0.096 UJ CCV ug/L Malathion 0.14 U ug/L Metalaxyl 0.24 UJ CCV ug/L Metolachlor 0.48 UJ CCV ug/L Metribuzin 0.096 U ug/L Mevinphos 0.19 U ug/L Naled 0.77 U ug/L Norflurazon 0.14 UJ CCV ug/L Parathion Ethyl 0.14 U ug/L Parathion Methyl 0.096 U ug/L Phorate 0.048 U ug/L Prometon 0.19 U ug/L Prometryn 0.14 U ug/L Simazine 0.048 U ug/L 1206755 EPA 6010C Strontium 917 ug/L Titanium 0.50 U ug/L EPA 6020A Aluminum 5.0 U ug/L Arsenic 0.79 I ug/L Barium 31.0 ug/L Cadmium 0.030 U ug/L Chromium 0.30 U ug/L Copper 0.89 ug/L Lead 0.20 U ug/L Selenium 0.20 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 12 of 93 Field ID: 1 Z-17895 80th St. N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Silver 0.025 U ug/L EPA 7470A Mercury 0.12 U ug/L 1206773 EPA 353.2 Rev. 2.0 NO2NO3-N 0.004 U mg N/L Ref. Method and Comment: EPA 8260C QC failure(s) observed. EPA 8270D QC failure(s) observed. FL-PRO Insufficient sample to perform matrix spikes. DEP SOP: GC-011-5 (based on EPA Methods 608, 617, 1656) Insufficient sample to perform MS duplicate due to loss of sample in sample preparation. DEP SOP: GC-012-3 (based on EPA 614, 619, 622, 633 and 507) Insufficient sample to perform MS duplicate due to loss of sample in sample preparation. QC failure(s) observed. Sample Location: ACREAGE Collection Date/Time: 08/05/2009 11:40 AM Field ID: 2 Z-14072 78th PL N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 1206586 EPA 900.0 Alpha, Total 2.3 pCi/L E83033 Alpha-Counting Error 1.2 pCi/L 1206604 EPA 522 1,4-Dioxane** 0.20 U ug/L E31640 1206622 EPA 8260C Benzene 0.20 U ug/L Bromodichloromethane 0.20 U ug/L Bromoform 0.50 UJ LCS ug/L Bromomethane 0.50 UJ CCV,MS ug/L 2-Butanone 10 U ug/L Carbon tetrachloride 0.20 U ug/L Chlorobenzene 0.20 U ug/L Chloroethane 0.50 U MS ug/L Chloroform 0.20 U ug/L Chloromethane 0.50 U MS ug/L Dibromochloromethane 0.20 U ug/L 1,2-Dichlorobenzene 0.50 U ug/L 1,3-Dichlorobenzene 0.50 U ug/L 1,4-Dichlorobenzene 0.50 U ug/L 1,1-Dichloroethane 0.20 U ug/L 1,2-Dichloroethane 0.20 U ug/L 1,1-Dichloroethene 0.50 U ug/L cis-1,2-Dichloroethene 0.50 U ug/L trans-1,2-Dichloroethene 0.50 U ug/L 1,2-Dichloropropane 0.50 U ug/L cis-1,3-Dichloropropene 0.50 U MS ug/L trans-1,3-Dichloropropene 0.20 UJ LCS,MS ug/L Ethylbenzene 0.50 U ug/L Methylene chloride 0.50 U ug/L 1,1,2,2-Tetrachloroethane 0.50 UJ CCV ug/L Tetrachloroethene 0.50 U ug/L Toluene 0.50 U ug/L 1,1,1-Trichloroethane 0.20 U ug/L 1,1,2-Trichloroethane 0.20 U ug/L Trichloroethene 0.20 UJ CCV ug/L Trichlorofluoromethane 0.50 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 13 of 93 Field ID: 2 Z-14072 78th PL N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Vinyl chloride 0.50 U ug/L Methyl-t-butyl ether 0.50 U ug/L o-Xylene 0.20 U ug/L m,p-Xylene 0.50 U ug/L 1206640 DEP SOP: LC-001-2 2,4-D 0.20 U ug/L E31780 2,4,5-T 0.20 U ug/L Acifluorfen 0.20 U ug/L Silvex 0.20 U ug/L 1206662 EPA 8270D Acenaphthene 1.0 U ug/L Acenaphthylene 1.0 U ug/L Acetophenone 1.0 U ug/L 2-Acetylaminofluorene 1.0 U ug/L 4-Aminobiphenyl 4.1 U ug/L Aniline 1.0 U ug/L Anthracene 1.0 U ug/L Azobenzene/1,2-Diphenylhydrazine 1.0 U ug/L Benzidine 100 U ug/L Benzo(a)anthracene 1.0 U ug/L Benzo(a)pyrene 1.0 U ug/L Benzo(b)fluoranthene 1.0 U ug/L Benzo(k)fluoranthene 1.0 U ug/L Benzo(g,h,i)perylene 1.0 U ug/L Benzyl alcohol 1.0 U ug/L Bis(2-chloroethoxy)methane 1.0 U ug/L Bis(2-chloroethyl)ether 1.0 U ug/L Bis(2-chloroisopropyl)ether 3.1 U ug/L Bis(2-ethylhexyl)phthalate 15 U ug/L Butyl benzyl phthalate 5.1 U ug/L 4-Bromophenyl phenyl ether 1.0 U ug/L 4-Chloroaniline 1.0 U ug/L 2-Chloronaphthalene 1.0 U ug/L 4-Chlorophenyl phenyl ether 2.0 U ug/L Chrysene 1.0 U ug/L m,p-Cresols 2.0 U ug/L o-Cresol 2.0 U ug/L Di-n-butyl phthalate 5.1 U ug/L Di-n-octyl phthalate 1.0 U ug/L Dibenzo(a,h)anthracene 1.0 U ug/L Dibenzofuran 1.0 U ug/L 3,3'-Dichlorobenzidine 41 U ug/L Diethyl phthalate 1.0 U ug/L Dimethyl phthalate 10 U ug/L Dimethylaminoazobenzene 1.0 UJ CCV ug/L 7,12-Dimethylbenz(a)anthracene 1.0 U ug/L 3,3'-Dimethylbenzidine 20 U ug/L 1,3-Dinitrobenzene 2.0 U ug/L 2,4-Dinitrotoluene 1.0 U ug/L 2,6-Dinitrotoluene 1.0 U ug/L Dinoseb** 4.1 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 14 of 93 Field ID: 2 Z-14072 78th PL N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Ethyl methanesulfonate 1.0 U ug/L Fluoranthene 1.0 U ug/L Fluorene 1.0 U ug/L Hexachlorobenzene 1.0 U ug/L Hexachlorobutadiene 3.1 U ug/L Hexachlorocyclopentadiene 3.1 U ug/L Hexachloroethane 3.1 U ug/L Hexachloropropene 2.0 U ug/L Indeno(1,2,3-cd)pyrene 1.0 U ug/L Isophorone 1.0 U ug/L Isosafrole 1.0 U ug/L Methapyrilene 4.1 UJ CCV,LCS ug/L 3-Methylcholanthrene 1.0 U ug/L Methyl methanesulfonate 1.0 UJ CCV ug/L 2-Methylnaphthalene 1.0 U ug/L Naphthalene 1.0 U ug/L 1-Naphthylamine 10 U ug/L 2-Naphthylamine 1,4-Naphthoquinone 10 20 UJ UJ LCS,MS,RP D CCV,MS ug/L ug/L 2-Nitroaniline 1.0 U ug/L 3-Nitroaniline 1.0 U ug/L 4-Nitroaniline 1.0 UJ CCV ug/L Nitrobenzene 2.0 U ug/L Nitroquinoline-1-oxide 20 UJ LCS,MS ug/L 5-Nitro-o-toluidine 1.0 U ug/L N-Nitrosodiethylamine 1.0 U ug/L N-Nitrosodimethylamine 2.0 U ug/L N-Nitrosodi-n-propylamine 2.0 U ug/L N-Nitrosomethylethylamine 2.0 U ug/L N-Nitrosomorpholine 1.0 U ug/L N-Nitrosopiperidine 1.0 U ug/L N-Nitrosopyrrolidine 2.0 U ug/L Pentachlorobenzene 1.0 U ug/L Pentachloroethane** 51 U ug/L Pentachloronitrobenzene 1.0 U ug/L Phenacetin 4.1 U ug/L Phenanthrene 1.0 U ug/L 2-Picoline 1.0 U ug/L Pyrene 1.0 U ug/L Pyridine 4.1 U ug/L Safrole 1.0 U ug/L 1,2,4,5-Tetrachlorobenzene 1.0 U ug/L o-Toluidine 1.0 U ug/L 1,2,4-Trichlorobenzene 1.0 U ug/L 1,3,5-Trinitrobenzene 4.1 U ug/L 4-Chloro-3-methylphenol 1.0 U ug/L 2-Chlorophenol 1.0 U ug/L 2,4-Dichlorophenol 1.0 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 15 of 93 Field ID: 2 Z-14072 78th PL N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 2,6-Dichlorophenol 1.0 U ug/L 2,4-Dimethylphenol 10 U ug/L 2,4-Dinitrophenol 15 U ug/L 2-Methyl-4,6-dinitrophenol 3.1 U ug/L 2-Nitrophenol 1.0 U ug/L 4-Nitrophenol 15 U ug/L Pentachlorophenol 3.1 U ug/L Phenol 1.0 U ug/L 2,3,4,6-Tetrachlorophenol 2.0 U ug/L 2,4,5-Trichlorophenol 1.0 U ug/L 2,4,6-Trichlorophenol 1.0 UJ CCV ug/L N-Nitrosodiphenylamine/ Diphenylamine 3.1 U ug/L 1206680 FL-PRO TRPH 0.26 U mg/L 1206708 EPA 504 1,2-Dibromoethane 0.011 U ug/L 1206726 DEP SOP: GC-011-5 (based Aldrin 0.010 U ug/L on EPA Methods 608, 617, 1656) Alpha-BHC 0.010 U ug/L Beta-BHC 0.010 U ug/L Delta-BHC 0.010 U ug/L Gamma-BHC 0.010 U ug/L Chlordane 0.20 U ug/L DDD-p,p' 0.020 U ug/L DDE-p,p' 0.020 U ug/L DDT-p,p' 0.030 U ug/L Dieldrin 0.020 U ug/L Endosulfan I 0.020 U ug/L Endosulfan II 0.020 U ug/L Endosulfan Sulfate 0.020 U ug/L Endrin 0.050 U ug/L Endrin Aldehyde 0.020 U ug/L Heptachlor 0.010 U ug/L Heptachlor Epoxide 0.020 U ug/L Methoxychlor 0.050 U ug/L Toxaphene 0.75 U ug/L PCB-1016 0.20 U ug/L PCB-1221 0.20 U ug/L PCB-1232 0.20 U ug/L PCB-1242 0.30 U ug/L PCB-1248 0.20 U ug/L PCB-1254 0.30 U ug/L PCB-1260 0.20 U ug/L DEP SOP: GC-012-3 (based Alachlor 0.60 UJ CCV ug/L on EPA 614, 619, 622, 633 and 507) Ametryn 0.050 U ug/L Atrazine 0.050 U ug/L Azinphos Methyl 0.20 UJ CCV ug/L Bromacil 0.20 U ug/L Butylate 0.20 UJ CCV ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 16 of 93 Field ID: 2 Z-14072 78th PL N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Chlorpyrifos Ethyl 0.050 U ug/L Chlorpyrifos Methyl 0.10 U ug/L Diazinon 0.050 U ug/L Ethion 0.050 U ug/L Ethoprop 0.10 U ug/L Fenamiphos 0.20 U ug/L Fonofos 0.10 U ug/L Hexazinone 0.10 UJ CCV ug/L Malathion 0.15 U ug/L Metalaxyl 0.25 UJ CCV ug/L Metolachlor 0.50 UJ CCV ug/L Metribuzin 0.10 UJ CCV ug/L Mevinphos 0.20 U ug/L Naled 0.80 U ug/L Norflurazon 0.15 UJ CCV ug/L Parathion Ethyl 0.15 U ug/L Parathion Methyl 0.10 U ug/L Phorate 0.050 U ug/L Prometon 0.20 U ug/L Prometryn 0.15 U ug/L Simazine 0.050 UJ CCV ug/L 1206762 EPA 6010C Strontium 589 ug/L Titanium 0.50 U ug/L EPA 6020A Aluminum 5.0 U ug/L Arsenic 0.25 U ug/L Barium 29.1 ug/L Cadmium 0.030 U ug/L Chromium 0.34 I ug/L Copper 0.50 U ug/L Lead 0.20 U ug/L Selenium 0.20 U ug/L Silver 0.025 U ug/L EPA 7470A Mercury 0.12 U MS ug/L 1206780 EPA 353.2 Rev. 2.0 NO2NO3-N 0.005 I mg N/L Ref. Method and Comment: EPA 8260C QC failure(s) observed. EPA 8270D QC failure(s) observed. FL-PRO Insufficient sample to perform matrix spikes. DEP SOP: GC-011-5 (based on EPA Methods 608, 617, 1656) Insufficient sample to perform MS duplicate due to loss of sample in sample preparation. DEP SOP: GC-012-3 (based on EPA 614, 619, 622, 633 and 507) Insufficient sample to perform MS duplicate due to loss of sample in sample preparation. QC failure(s) observed. Sample Location: ACREAGE Collection Date/Time: 08/05/2009 10:45 AM Field ID: 2 Z-14390 ORANGE BLVD Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 1206389 EPA 903.1 and Ra-05 Radium 226 1.0 pCi/L E83033 Radium 226-Counting Error 0.3 pCi/L Radium 228 1.0 U pCi/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 17 of 93 Field ID: 2 Z-14390 ORANGE BLVD Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Radium 228-Counting Error 0.6 pCi/L 1206395 EPA 900.0 Alpha, Total 1.6 pCi/L Alpha-Counting Error 1.1 pCi/L 1206603 EPA 522 1,4-Dioxane** 0.20 U ug/L E31640 1206621 EPA 8260C Benzene 0.20 U ug/L Bromodichloromethane 0.20 U ug/L Bromoform 0.50 UJ LCS ug/L Bromomethane 0.50 UJ CCV,MS ug/L 2-Butanone 10 U ug/L Carbon tetrachloride 0.20 U ug/L Chlorobenzene 0.20 U ug/L Chloroethane 0.50 U MS ug/L Chloroform 0.20 U ug/L Chloromethane 0.50 U MS ug/L Dibromochloromethane 0.20 U ug/L 1,2-Dichlorobenzene 0.50 U ug/L 1,3-Dichlorobenzene 0.50 U ug/L 1,4-Dichlorobenzene 0.50 U ug/L 1,1-Dichloroethane 0.20 U ug/L 1,2-Dichloroethane 0.20 U ug/L 1,1-Dichloroethene 0.50 U ug/L cis-1,2-Dichloroethene 0.50 U ug/L trans-1,2-Dichloroethene 0.50 U ug/L 1,2-Dichloropropane 0.50 U ug/L cis-1,3-Dichloropropene 0.50 U MS ug/L trans-1,3-Dichloropropene 0.20 UJ LCS,MS ug/L Ethylbenzene 0.50 U ug/L Methylene chloride 0.50 U ug/L 1,1,2,2-Tetrachloroethane 0.50 UJ CCV ug/L Tetrachloroethene 0.50 U ug/L Toluene 0.50 U ug/L 1,1,1-Trichloroethane 0.20 U ug/L 1,1,2-Trichloroethane 0.20 U ug/L Trichloroethene 0.20 UJ CCV ug/L Trichlorofluoromethane 0.50 U ug/L Vinyl chloride 0.50 U ug/L Methyl-t-butyl ether 0.50 U ug/L o-Xylene 0.20 U ug/L m,p-Xylene 0.50 U ug/L 1206639 DEP SOP: LC-001-2 2,4-D 0.20 U ug/L E31780 2,4,5-T 0.20 U ug/L Acifluorfen 0.20 U ug/L Silvex 0.20 U ug/L 1206661 EPA 8270D Acenaphthene 0.96 U ug/L Acenaphthylene 0.96 U ug/L Acetophenone 0.96 U ug/L 2-Acetylaminofluorene 0.96 U ug/L 4-Aminobiphenyl 3.9 U ug/L Aniline 0.96 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 18 of 93 Field ID: 2 Z-14390 ORANGE BLVD Matrix: W-GROUND Sample ID Ref. Method Component Anthracene Azobenzene/1,2-Diphenylhydrazine Benzidine Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(k)fluoranthene Benzo(g,h,i)perylene Benzyl alcohol Bis(2-chloroethoxy)methane Bis(2-chloroethyl)ether Bis(2-chloroisopropyl)ether Bis(2-ethylhexyl)phthalate Butyl benzyl phthalate 4-Bromophenyl phenyl ether 4-Chloroaniline 2-Chloronaphthalene 4-Chlorophenyl phenyl ether Chrysene m,p-Cresols o-Cresol Di-n-butyl phthalate Di-n-octyl phthalate Dibenzo(a,h)anthracene Dibenzofuran 3,3'-Dichlorobenzidine Diethyl phthalate Dimethyl phthalate Dimethylaminoazobenzene 7,12-Dimethylbenz(a)anthracene 3,3'-Dimethylbenzidine 1,3-Dinitrobenzene 2,4-Dinitrotoluene 2,6-Dinitrotoluene Dinoseb** Ethyl methanesulfonate Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Hexachloropropene Indeno(1,2,3-cd)pyrene Isophorone Isosafrole Methapyrilene 3-Methylcholanthrene Methyl methanesulfonate Result 0.96 0.96 96 0.96 0.96 0.96 0.96 0.96 0.96 0.96 0.96 2.9 14 4.8 0.96 0.96 0.96 1.9 0.96 1.9 1.9 4.8 0.96 0.96 0.96 39 0.96 9.6 0.96 0.96 19 1.9 0.96 0.96 3.9 0.96 0.96 0.96 0.96 2.9 2.9 2.9 1.9 0.96 0.96 0.96 3.9 0.96 0.96 Code QC Failures Units Cert # U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L UJ CCV ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L UJ CCV,LCS ug/L U ug/L UJ CCV ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 19 of 93 Field ID: 2 Z-14390 ORANGE BLVD Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 2-Methylnaphthalene 0.96 U ug/L Naphthalene 0.96 U ug/L 1-Naphthylamine 9.6 U ug/L 2-Naphthylamine 9.6 UJ LCS,MS,RP ug/L D 1,4-Naphthoquinone 19 UJ CCV,MS ug/L 2-Nitroaniline 0.96 U ug/L 3-Nitroaniline 0.96 U ug/L 4-Nitroaniline 0.96 UJ CCV ug/L Nitrobenzene 1.9 U ug/L Nitroquinoline-1-oxide 19 UJ LCS,MS ug/L 5-Nitro-o-toluidine 0.96 U ug/L N-Nitrosodiethylamine 0.96 U ug/L N-Nitrosodimethylamine 1.9 U ug/L N-Nitrosodi-n-propylamine 1.9 U ug/L N-Nitrosomethylethylamine 1.9 U ug/L N-Nitrosomorpholine 0.96 U ug/L N-Nitrosopiperidine 0.96 U ug/L N-Nitrosopyrrolidine 1.9 U ug/L Pentachlorobenzene 0.96 U ug/L Pentachloroethane** 48 U ug/L Pentachloronitrobenzene 0.96 U ug/L Phenacetin 3.9 U ug/L Phenanthrene 0.96 U ug/L 2-Picoline 0.96 U ug/L Pyrene 0.96 U ug/L Pyridine 3.9 U ug/L Safrole 0.96 U ug/L 1,2,4,5-Tetrachlorobenzene 0.96 U ug/L o-Toluidine 0.96 U ug/L 1,2,4-Trichlorobenzene 0.96 U ug/L 1,3,5-Trinitrobenzene 3.9 U ug/L 4-Chloro-3-methylphenol 0.96 U ug/L 2-Chlorophenol 0.96 U ug/L 2,4-Dichlorophenol 0.96 U ug/L 2,6-Dichlorophenol 0.96 U ug/L 2,4-Dimethylphenol 9.6 U ug/L 2,4-Dinitrophenol 14 U ug/L 2-Methyl-4,6-dinitrophenol 2.9 U ug/L 2-Nitrophenol 0.96 U ug/L 4-Nitrophenol 14 U ug/L Pentachlorophenol 2.9 U ug/L Phenol 0.96 U ug/L 2,3,4,6-Tetrachlorophenol 1.9 U ug/L 2,4,5-Trichlorophenol 0.96 U ug/L 2,4,6-Trichlorophenol 0.96 UJ CCV ug/L N-Nitrosodiphenylamine/ Diphenylamine 2.9 U ug/L 1206679 FL-PRO TRPH 0.25 U mg/L 1206707 EPA 504 1,2-Dibromoethane 0.010 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 20 of 93 Field ID: 2 Z-14390 ORANGE BLVD Matrix: W-GROUND Sample ID Ref. Method Component 1206725 DEP SOP: GC-011-5 (based Aldrin on EPA Methods 608, 617, 1656) Alpha-BHC Beta-BHC Delta-BHC Gamma-BHC Chlordane DDD-p,p' DDE-p,p' DDT-p,p' Dieldrin Endosulfan I Endosulfan II Endosulfan Sulfate Endrin Endrin Aldehyde Heptachlor Heptachlor Epoxide Methoxychlor Toxaphene PCB-1016 PCB-1221 PCB-1232 PCB-1242 PCB-1248 PCB-1254 PCB-1260 DEP SOP: GC-012-3 (based Alachlor on EPA 614, 619, 622, 633 and 507) Ametryn Atrazine Azinphos Methyl Bromacil Butylate Chlorpyrifos Ethyl Chlorpyrifos Methyl Diazinon Ethion Ethoprop Fenamiphos Fonofos Hexazinone Malathion Metalaxyl Metolachlor Metribuzin Mevinphos Naled Result 0.010 0.010 0.010 0.010 0.010 0.20 0.020 0.020 0.030 0.020 0.020 0.020 0.020 0.051 0.020 0.010 0.020 0.051 0.76 0.20 0.20 0.20 0.30 0.20 0.30 0.20 0.61 0.051 0.051 0.20 0.20 0.20 0.051 0.10 0.051 0.051 0.10 0.20 0.10 0.10 0.15 0.25 0.51 0.10 0.20 0.81 Code QC Failures Units Cert # U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L UJ CCV ug/L U ug/L U ug/L UJ CCV ug/L U ug/L UJ CCV ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L UJ CCV ug/L U ug/L UJ CCV ug/L UJ CCV ug/L U ug/L U ug/L U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 21 of 93 Field ID: 2 Z-14390 ORANGE BLVD Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Norflurazon 0.15 UJ CCV ug/L Parathion Ethyl 0.15 U ug/L Parathion Methyl 0.10 U ug/L Phorate 0.051 U ug/L Prometon 0.20 U ug/L Prometryn 0.15 U ug/L Simazine 0.051 U ug/L 1206761 EPA 6010C Strontium 391 ug/L Titanium 0.50 U ug/L EPA 6020A Aluminum 5.0 U ug/L Arsenic 0.25 U ug/L Barium 20.8 ug/L Cadmium 0.030 U ug/L Chromium 0.30 U ug/L Copper 0.50 U ug/L Lead 0.20 U ug/L Selenium 0.20 U ug/L Silver 0.025 U ug/L EPA 7470A Mercury 0.12 U MS ug/L 1206779 EPA 353.2 Rev. 2.0 NO2NO3-N 0.040 U mg N/L Ref. Method and Comment: EPA 8260C QC failure(s) observed. EPA 8270D QC failure(s) observed. FL-PRO Insufficient sample to perform matrix spikes. DEP SOP: GC-011-5 (based on EPA Methods 608, 617, 1656) Insufficient sample to perform MS duplicate due to loss of sample in sample preparation. DEP SOP: GC-012-3 (based on EPA 614, 619, 622, 633 and 507) Insufficient sample to perform MS duplicate due to loss of sample in sample preparation. QC failure(s) observed. EPA 353.2 Rev. 2.0 The MDL was elevated due to sample matrix interference. Sample Location: ACREAGE Collection Date/Time: 08/04/2009 03:50 PM Field ID: 2 Z-14692 TANGERINE BLVD Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 1206820 EPA 504 1,2-Dibromoethane 0.010 U ug/L E31780 1206823 EPA 353.2 Rev. 2.0 NO2NO3-N 0.006 I mg N/L 1206825 DEP SOP: LC-001-2 2,4-D 0.21 U ug/L 2,4,5-T 0.21 U ug/L Acifluorfen 0.21 U ug/L Silvex 0.21 U ug/L 1206827 EPA 8270D Acenaphthene 1.0 U ug/L Acenaphthylene 1.0 U ug/L Acetophenone 1.0 U ug/L 2-Acetylaminofluorene 1.0 U ug/L 4-Aminobiphenyl 4.1 U ug/L Aniline 1.0 U ug/L Anthracene 1.0 U ug/L Azobenzene/1,2-Diphenylhydrazine 1.0 U ug/L Benzidine 100 U ug/L Benzo(a)anthracene 1.0 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 22 of 93 Field ID: 2 Z-14692 TANGERINE BLVD Matrix: W-GROUND Sample ID Ref. Method Component Benzo(a)pyrene Benzo(b)fluoranthene Benzo(k)fluoranthene Benzo(g,h,i)perylene Benzyl alcohol Bis(2-chloroethoxy)methane Bis(2-chloroethyl)ether Bis(2-chloroisopropyl)ether Bis(2-ethylhexyl)phthalate Butyl benzyl phthalate 4-Bromophenyl phenyl ether 4-Chloroaniline 2-Chloronaphthalene 4-Chlorophenyl phenyl ether Chrysene m,p-Cresols o-Cresol Di-n-butyl phthalate Di-n-octyl phthalate Dibenzo(a,h)anthracene Dibenzofuran 3,3'-Dichlorobenzidine Diethyl phthalate Dimethyl phthalate Dimethylaminoazobenzene 7,12-Dimethylbenz(a)anthracene 3,3'-Dimethylbenzidine 1,3-Dinitrobenzene 2,4-Dinitrotoluene 2,6-Dinitrotoluene Dinoseb** Ethyl methanesulfonate Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Hexachloropropene Indeno(1,2,3-cd)pyrene Isophorone Isosafrole Methapyrilene 3-Methylcholanthrene Methyl methanesulfonate 2-Methylnaphthalene Naphthalene 1-Naphthylamine 2-Naphthylamine Result 1.0 1.0 1.0 1.0 1.0 1.0 1.0 3.0 15 5.1 1.0 1.0 1.0 2.0 1.0 2.0 2.0 5.1 1.0 1.0 1.0 41 1.0 10 1.0 1.0 20 2.0 1.0 1.0 4.1 1.0 1.0 1.0 1.0 3.0 3.0 3.0 2.0 1.0 1.0 1.0 4.1 1.0 1.0 1.0 1.0 10 10 Code QC Failures Units Cert # U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L UJ CCV,LCS ug/L U ug/L UJ CCV ug/L U ug/L U ug/L U ug/L U MS ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 23 of 93 Field ID: 2 Z-14692 TANGERINE BLVD Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 1,4-Naphthoquinone 20 UJ CCV ug/L 2-Nitroaniline 1.0 U ug/L 3-Nitroaniline 1.0 U ug/L 4-Nitroaniline 1.0 UJ CCV ug/L Nitrobenzene 2.0 U ug/L Nitroquinoline-1-oxide 20 U ug/L 5-Nitro-o-toluidine 1.0 U ug/L N-Nitrosodiethylamine 1.0 U ug/L N-Nitrosodimethylamine 2.0 U ug/L N-Nitrosodi-n-propylamine 2.0 U ug/L N-Nitrosomethylethylamine 2.0 U ug/L N-Nitrosomorpholine 1.0 U ug/L N-Nitrosopiperidine 1.0 U ug/L N-Nitrosopyrrolidine 2.0 U ug/L Pentachlorobenzene 1.0 U ug/L Pentachloroethane** 51 U ug/L Pentachloronitrobenzene 1.0 U ug/L Phenacetin 4.1 U ug/L Phenanthrene 1.0 U ug/L 2-Picoline 1.0 U ug/L Pyrene 1.0 U ug/L Pyridine 4.1 U ug/L Safrole 1.0 U ug/L 1,2,4,5-Tetrachlorobenzene 1.0 U ug/L o-Toluidine 1.0 U ug/L 1,2,4-Trichlorobenzene 1.0 U ug/L 1,3,5-Trinitrobenzene 4.1 U ug/L 4-Chloro-3-methylphenol 1.0 U ug/L 2-Chlorophenol 1.0 U ug/L 2,4-Dichlorophenol 1.0 U ug/L 2,6-Dichlorophenol 1.0 U ug/L 2,4-Dimethylphenol 10 U ug/L 2,4-Dinitrophenol 15 U ug/L 2-Methyl-4,6-dinitrophenol 3.0 U ug/L 2-Nitrophenol 1.0 U ug/L 4-Nitrophenol 15 U ug/L Pentachlorophenol 3.0 U ug/L Phenol 1.0 U ug/L 2,3,4,6-Tetrachlorophenol 2.0 U ug/L 2,4,5-Trichlorophenol 1.0 U ug/L 2,4,6-Trichlorophenol 1.0 U ug/L N-Nitrosodiphenylamine/ Diphenylamine 3.0 U ug/L 1206829 FL-PRO TRPH 0.25 U mg/L 1206832 DEP SOP: GC-011-5 (based Aldrin 0.0098 U ug/L on EPA Methods 608, 617, 1656) Alpha-BHC 0.0098 U ug/L Beta-BHC 0.0098 UJ CCV ug/L Delta-BHC 0.0098 UJ CCV ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 24 of 93 Field ID: 2 Z-14692 TANGERINE BLVD Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Gamma-BHC 0.0098 U ug/L Chlordane 0.20 U ug/L DDD-p,p' 0.020 UJ CCV ug/L DDE-p,p' 0.020 UJ CCV ug/L DDT-p,p' 0.029 U ug/L Dieldrin 0.020 U ug/L Endosulfan I 0.020 U ug/L Endosulfan II 0.020 U ug/L Endosulfan Sulfate 0.020 U ug/L Endrin 0.049 U ug/L Endrin Aldehyde 0.020 U ug/L Heptachlor 0.0098 U ug/L Heptachlor Epoxide 0.020 U ug/L Methoxychlor 0.049 UJ CCV ug/L Toxaphene 0.74 U ug/L PCB-1016 0.20 U ug/L PCB-1221 0.20 U ug/L PCB-1232 0.20 U ug/L PCB-1242 0.29 U ug/L PCB-1248 0.20 U ug/L PCB-1254 0.29 U ug/L PCB-1260 0.20 U ug/L DEP SOP: GC-012-3 (based Alachlor 0.59 UJ CCV ug/L on EPA 614, 619, 622, 633 and 507) Ametryn 0.049 U ug/L Atrazine 0.049 U ug/L Azinphos Methyl 0.20 UJ CCV ug/L Bromacil 0.20 U ug/L Butylate 0.20 UJ CCV ug/L Chlorpyrifos Ethyl 0.049 U ug/L Chlorpyrifos Methyl 0.098 U ug/L Diazinon 0.049 U ug/L Ethion 0.049 U ug/L Ethoprop 0.098 U ug/L Fenamiphos 0.20 U ug/L Fonofos 0.098 U ug/L Hexazinone 0.098 UJ CCV ug/L Malathion 0.15 U ug/L Metalaxyl 0.25 UJ CCV ug/L Metolachlor 0.49 UJ CCV ug/L Metribuzin 0.098 UJ CCV ug/L Mevinphos 0.20 U ug/L Naled 0.79 U ug/L Norflurazon 0.15 UJ CCV ug/L Parathion Ethyl 0.15 U ug/L Parathion Methyl 0.098 U ug/L Phorate 0.049 U ug/L Prometon 0.20 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 25 of 93 Field ID: 2 Z-14692 TANGERINE BLVD Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Prometryn 0.15 U ug/L Simazine 0.049 UJ CCV ug/L 1206834 EPA 522 1,4-Dioxane** 0.20 U ug/L E31640 1206835 EPA 8260C Benzene 0.20 U ug/L Bromodichloromethane 0.20 U ug/L Bromoform 0.50 UJ LCS ug/L Bromomethane 0.50 UJ CCV,MS ug/L 2-Butanone 10 U ug/L Carbon tetrachloride 0.20 U ug/L Chlorobenzene 0.20 U ug/L Chloroethane 0.50 U MS ug/L Chloroform 0.20 U ug/L Chloromethane 0.50 U MS ug/L Dibromochloromethane 0.20 U ug/L 1,2-Dichlorobenzene 0.50 U ug/L 1,3-Dichlorobenzene 0.50 U ug/L 1,4-Dichlorobenzene 0.50 U ug/L 1,1-Dichloroethane 0.20 U ug/L 1,2-Dichloroethane 0.20 U ug/L 1,1-Dichloroethene 0.50 U ug/L cis-1,2-Dichloroethene 0.50 U ug/L trans-1,2-Dichloroethene 0.50 U ug/L 1,2-Dichloropropane 0.50 U ug/L cis-1,3-Dichloropropene 0.50 U MS ug/L trans-1,3-Dichloropropene 0.20 UJ CCV,LCS, ug/L MS Ethylbenzene 0.50 U ug/L Methylene chloride 0.50 U ug/L 1,1,2,2-Tetrachloroethane 0.50 UJ CCV ug/L Tetrachloroethene 0.50 U ug/L Toluene 0.50 U ug/L 1,1,1-Trichloroethane 0.20 U ug/L 1,1,2-Trichloroethane 0.20 U ug/L Trichloroethene 0.20 UJ CCV ug/L Trichlorofluoromethane 0.50 U ug/L Vinyl chloride 0.50 U ug/L Methyl-t-butyl ether 0.50 U ug/L o-Xylene 0.20 U ug/L m,p-Xylene 0.50 U ug/L 1206839 EPA 900.0 Alpha, Total 15.6 U pCi/L E83033 Alpha-Counting Error 4.8 pCi/L 1206847 EPA 6010C Strontium 528 ug/L E31780 Titanium 0.50 U ug/L EPA 6020A Aluminum 5.0 U ug/L Arsenic 1.01 ug/L Barium 65.1 ug/L Cadmium 0.030 U ug/L Chromium 0.30 I ug/L Copper 1.02 ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 26 of 93 Field ID: 2 Z-14692 TANGERINE BLVD Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Lead 0.20 U ug/L Selenium 0.20 U ug/L Silver 0.025 U ug/L EPA 7470A Mercury 0.12 U ug/L Ref. Method and Comment: EPA 8270D QC failure(s) observed. DEP SOP: GC-011-5 (based on EPA Methods 608, 617, 1656) Insufficient sample to perform MS duplicate due to loss of sample in sample preparation. QC failure(s) observed. DEP SOP: GC-012-3 (based on EPA 614, 619, 622, 633 and 507) Insufficient sample to perform MS duplicate due to loss of sample in sample preparation. QC failure(s) observed. EPA 8260C QC failure(s) observed. Sample Location: ACREAGE Collection Date/Time: 08/05/2009 10:27 AM Field ID: 2 Z-14741 77th PL N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 1206582 EPA 900.0 Alpha, Total 1.8 U pCi/L E83033 Alpha-Counting Error 1.0 pCi/L 1206600 EPA 522 1,4-Dioxane** 0.20 U ug/L E31640 1206619 EPA 8260C Benzene 0.20 U ug/L Bromodichloromethane 0.20 U ug/L Bromoform 0.50 UJ LCS ug/L Bromomethane 0.50 UJ CCV,MS ug/L 2-Butanone 10 U ug/L Carbon tetrachloride 0.20 U ug/L Chlorobenzene 0.20 U ug/L Chloroethane 0.50 UJ MS ug/L Chloroform 0.20 U ug/L Chloromethane 0.50 UJ MS ug/L Dibromochloromethane 0.20 U ug/L 1,2-Dichlorobenzene 0.50 U ug/L 1,3-Dichlorobenzene 0.50 U ug/L 1,4-Dichlorobenzene 0.50 U ug/L 1,1-Dichloroethane 0.20 U ug/L 1,2-Dichloroethane 0.20 U ug/L 1,1-Dichloroethene 0.50 U ug/L cis-1,2-Dichloroethene 0.50 U ug/L trans-1,2-Dichloroethene 0.50 U ug/L 1,2-Dichloropropane 0.50 U ug/L cis-1,3-Dichloropropene 0.50 UJ MS ug/L trans-1,3-Dichloropropene 0.20 UJ LCS,MS ug/L Ethylbenzene 0.50 U ug/L Methylene chloride 0.50 U ug/L 1,1,2,2-Tetrachloroethane 0.50 UJ CCV ug/L Tetrachloroethene 0.50 U ug/L Toluene 0.50 U ug/L 1,1,1-Trichloroethane 0.20 U ug/L 1,1,2-Trichloroethane 0.20 U ug/L Trichloroethene 0.20 UJ CCV ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 27 of 93 Field ID: 2 Z-14741 77th PL N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Trichlorofluoromethane 0.50 U ug/L Vinyl chloride 0.50 U ug/L Methyl-t-butyl ether 0.50 U ug/L o-Xylene 0.20 U ug/L m,p-Xylene 0.50 U ug/L 1206636 DEP SOP: LC-001-2 2,4-D 0.21 U ug/L E31780 2,4,5-T 0.21 U ug/L Acifluorfen 0.21 U ug/L Silvex 0.21 U ug/L 1206658 EPA 8270D Acenaphthene 1.0 U ug/L Acenaphthylene 1.0 U ug/L Acetophenone 1.0 U ug/L 2-Acetylaminofluorene 1.0 U ug/L 4-Aminobiphenyl 4.0 U ug/L Aniline 1.0 U ug/L Anthracene 1.0 U ug/L Azobenzene/1,2-Diphenylhydrazine 1.0 U ug/L Benzidine 100 U ug/L Benzo(a)anthracene 1.0 U ug/L Benzo(a)pyrene 1.0 U ug/L Benzo(b)fluoranthene 1.0 U ug/L Benzo(k)fluoranthene 1.0 U ug/L Benzo(g,h,i)perylene 1.0 U ug/L Benzyl alcohol 1.0 U ug/L Bis(2-chloroethoxy)methane 1.0 U ug/L Bis(2-chloroethyl)ether 1.0 U ug/L Bis(2-chloroisopropyl)ether 3.0 U ug/L Bis(2-ethylhexyl)phthalate 15 U ug/L Butyl benzyl phthalate 5.0 U ug/L 4-Bromophenyl phenyl ether 1.0 U ug/L 4-Chloroaniline 1.0 U ug/L 2-Chloronaphthalene 1.0 U ug/L 4-Chlorophenyl phenyl ether 2.0 U ug/L Chrysene 1.0 U ug/L m,p-Cresols 2.0 U ug/L o-Cresol 2.0 U ug/L Di-n-butyl phthalate 5.0 U ug/L Di-n-octyl phthalate 1.0 U ug/L Dibenzo(a,h)anthracene 1.0 U ug/L Dibenzofuran 1.0 U ug/L 3,3'-Dichlorobenzidine 40 U ug/L Diethyl phthalate 1.0 U ug/L Dimethyl phthalate 10 U ug/L Dimethylaminoazobenzene 1.0 UJ CCV ug/L 7,12-Dimethylbenz(a)anthracene 1.0 U ug/L 3,3'-Dimethylbenzidine 20 U ug/L 1,3-Dinitrobenzene 2.0 U ug/L 2,4-Dinitrotoluene 1.0 U ug/L 2,6-Dinitrotoluene 1.0 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 28 of 93 Field ID: 2 Z-14741 77th PL N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Dinoseb** 4.0 U ug/L Ethyl methanesulfonate 1.0 U ug/L Fluoranthene 1.0 U ug/L Fluorene 1.0 U ug/L Hexachlorobenzene 1.0 U ug/L Hexachlorobutadiene 3.0 U ug/L Hexachlorocyclopentadiene 3.0 U ug/L Hexachloroethane 3.0 U ug/L Hexachloropropene 2.0 U ug/L Indeno(1,2,3-cd)pyrene 1.0 U ug/L Isophorone 1.0 U ug/L Isosafrole 1.0 U ug/L Methapyrilene 4.0 UJ CCV,LCS ug/L 3-Methylcholanthrene 1.0 U ug/L Methyl methanesulfonate 1.0 UJ CCV ug/L 2-Methylnaphthalene 1.0 U ug/L Naphthalene 1.0 U ug/L 1-Naphthylamine 10 U ug/L 2-Naphthylamine 1,4-Naphthoquinone 10 20 UJ UJ LCS,MS,RP D CCV,MS ug/L ug/L 2-Nitroaniline 1.0 U ug/L 3-Nitroaniline 1.0 U ug/L 4-Nitroaniline 1.0 UJ CCV ug/L Nitrobenzene 2.0 U ug/L Nitroquinoline-1-oxide 20 UJ LCS,MS ug/L 5-Nitro-o-toluidine 1.0 U ug/L N-Nitrosodiethylamine 1.0 U ug/L N-Nitrosodimethylamine 2.0 U ug/L N-Nitrosodi-n-propylamine 2.0 U ug/L N-Nitrosomethylethylamine 2.0 U ug/L N-Nitrosomorpholine 1.0 U ug/L N-Nitrosopiperidine 1.0 U ug/L N-Nitrosopyrrolidine 2.0 U ug/L Pentachlorobenzene 1.0 U ug/L Pentachloroethane** 50 U ug/L Pentachloronitrobenzene 1.0 U ug/L Phenacetin 4.0 U ug/L Phenanthrene 1.0 U ug/L 2-Picoline 1.0 U ug/L Pyrene 1.0 U ug/L Pyridine 4.0 U ug/L Safrole 1.0 U ug/L 1,2,4,5-Tetrachlorobenzene 1.0 U ug/L o-Toluidine 1.0 U ug/L 1,2,4-Trichlorobenzene 1.0 U ug/L 1,3,5-Trinitrobenzene 4.0 U ug/L 4-Chloro-3-methylphenol 1.0 U ug/L 2-Chlorophenol 1.0 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 29 of 93 Field ID: 2 Z-14741 77th PL N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 2,4-Dichlorophenol 1.0 U ug/L 2,6-Dichlorophenol 1.0 U ug/L 2,4-Dimethylphenol 10 U ug/L 2,4-Dinitrophenol 15 U ug/L 2-Methyl-4,6-dinitrophenol 3.0 U ug/L 2-Nitrophenol 1.0 U ug/L 4-Nitrophenol 15 U ug/L Pentachlorophenol 3.0 U ug/L Phenol 1.0 U ug/L 2,3,4,6-Tetrachlorophenol 2.0 U ug/L 2,4,5-Trichlorophenol 1.0 U ug/L 2,4,6-Trichlorophenol 1.0 UJ CCV ug/L N-Nitrosodiphenylamine/ Diphenylamine 3.0 U ug/L 1206676 FL-PRO TRPH 0.26 U mg/L 1206704 EPA 504 1,2-Dibromoethane 0.010 U ug/L 1206722 DEP SOP: GC-011-5 (based Aldrin 0.010 U ug/L on EPA Methods 608, 617, 1656) Alpha-BHC 0.010 U ug/L Beta-BHC 0.010 U ug/L Delta-BHC 0.010 U ug/L Gamma-BHC 0.010 U ug/L Chlordane 0.20 U ug/L DDD-p,p' 0.020 U ug/L DDE-p,p' 0.020 U ug/L DDT-p,p' 0.030 U ug/L Dieldrin 0.020 U ug/L Endosulfan I 0.020 U ug/L Endosulfan II 0.020 U ug/L Endosulfan Sulfate 0.020 U ug/L Endrin 0.050 U ug/L Endrin Aldehyde 0.020 U ug/L Heptachlor 0.010 U ug/L Heptachlor Epoxide 0.020 U ug/L Methoxychlor 0.050 U ug/L Toxaphene 0.75 U ug/L PCB-1016 0.20 U ug/L PCB-1221 0.20 U ug/L PCB-1232 0.20 U ug/L PCB-1242 0.30 U ug/L PCB-1248 0.20 U ug/L PCB-1254 0.30 U ug/L PCB-1260 0.20 U ug/L DEP SOP: GC-012-3 (based Alachlor 0.60 UJ CCV ug/L on EPA 614, 619, 622, 633 and 507) Ametryn 0.050 U ug/L Atrazine 0.050 U ug/L Azinphos Methyl 0.20 UJ CCV ug/L Bromacil 0.20 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 30 of 93 Field ID: 2 Z-14741 77th PL N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Butylate 0.20 UJ CCV ug/L Chlorpyrifos Ethyl 0.050 U ug/L Chlorpyrifos Methyl 0.10 U ug/L Diazinon 0.050 U ug/L Ethion 0.050 U ug/L Ethoprop 0.10 U ug/L Fenamiphos 0.20 U ug/L Fonofos 0.10 U ug/L Hexazinone 0.10 UJ CCV ug/L Malathion 0.15 U ug/L Metalaxyl 0.25 UJ CCV ug/L Metolachlor 0.50 UJ CCV ug/L Metribuzin 0.10 U ug/L Mevinphos 0.20 U ug/L Naled 0.80 U ug/L Norflurazon 0.15 UJ CCV ug/L Parathion Ethyl 0.15 U ug/L Parathion Methyl 0.10 U ug/L Phorate 0.050 U ug/L Prometon 0.20 U ug/L Prometryn 0.15 U ug/L Simazine 0.050 U ug/L 1206758 EPA 6010C Strontium 1.08E+03 ug/L Titanium 0.50 U ug/L EPA 6020A Aluminum 5.0 U ug/L Arsenic 0.25 U ug/L Barium 8.77 ug/L Cadmium 0.030 U ug/L Chromium 0.30 U ug/L Copper 0.50 U ug/L Lead 0.20 U ug/L Selenium 0.20 U ug/L Silver 0.025 U ug/L EPA 7470A Mercury 0.12 U MS ug/L Ref. Method and Comment: EPA 8260C QC failure(s) observed. EPA 8270D QC failure(s) observed. FL-PRO Insufficient sample to perform matrix spikes. DEP SOP: GC-011-5 (based on EPA Methods 608, 617, 1656) Insufficient sample to perform MS duplicate due to loss of sample in sample preparation. DEP SOP: GC-012-3 (based on EPA 614, 619, 622, 633 and 507) Insufficient sample to perform MS duplicate due to loss of sample in sample preparation. QC failure(s) observed. Sample Location: ACREAGE Collection Date/Time: 08/05/2009 08:55 AM Field ID: 2 Z-15163 82nd Ln N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 1206581 EPA 900.0 Alpha, Total 2.0 U pCi/L E83033 Alpha-Counting Error 1.3 pCi/L 1206599 EPA 522 1,4-Dioxane** 0.20 U ug/L E31640 SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 31 of 93 Field ID: 2 Z-15163 82nd Ln N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 1206617 EPA 8260C Benzene 0.20 U ug/L Bromodichloromethane 0.20 U ug/L Bromoform 0.50 UJ LCS ug/L Bromomethane 0.50 UJ CCV,MS ug/L 2-Butanone 10 U ug/L Carbon tetrachloride 0.20 U ug/L Chlorobenzene 0.20 U ug/L Chloroethane 0.50 U MS ug/L Chloroform 0.20 U ug/L Chloromethane 0.50 U MS ug/L Dibromochloromethane 0.20 U ug/L 1,2-Dichlorobenzene 0.50 U ug/L 1,3-Dichlorobenzene 0.50 U ug/L 1,4-Dichlorobenzene 0.50 U ug/L 1,1-Dichloroethane 0.20 U ug/L 1,2-Dichloroethane 0.20 U ug/L 1,1-Dichloroethene 0.50 U ug/L cis-1,2-Dichloroethene 0.50 U ug/L trans-1,2-Dichloroethene 0.50 U ug/L 1,2-Dichloropropane 0.50 U ug/L cis-1,3-Dichloropropene 0.50 U MS ug/L trans-1,3-Dichloropropene 0.20 UJ LCS,MS ug/L Ethylbenzene 0.50 U ug/L Methylene chloride 0.50 U ug/L 1,1,2,2-Tetrachloroethane 0.50 UJ CCV ug/L Tetrachloroethene 0.50 U ug/L Toluene 0.50 U ug/L 1,1,1-Trichloroethane 0.20 U ug/L 1,1,2-Trichloroethane 0.20 U ug/L Trichloroethene 0.20 UJ CCV ug/L Trichlorofluoromethane 0.50 U ug/L Vinyl chloride 0.50 U ug/L Methyl-t-butyl ether 0.50 U ug/L o-Xylene 0.20 U ug/L m,p-Xylene 0.50 U ug/L 1206635 DEP SOP: LC-001-2 2,4-D 0.20 U ug/L E31780 2,4,5-T 0.20 U ug/L Acifluorfen 0.20 U ug/L Silvex 0.20 U ug/L 1206657 EPA 8270D Acenaphthene 0.98 U ug/L Acenaphthylene 0.98 U ug/L Acetophenone 0.98 U ug/L 2-Acetylaminofluorene 0.98 U ug/L 4-Aminobiphenyl 3.9 U ug/L Aniline 0.98 U ug/L Anthracene 0.98 U ug/L Azobenzene/1,2-Diphenylhydrazine 0.98 U ug/L Benzidine 98 U ug/L Benzo(a)anthracene 0.98 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 32 of 93 Field ID: 2 Z-15163 82nd Ln N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Benzo(a)pyrene Benzo(b)fluoranthene Benzo(k)fluoranthene Benzo(g,h,i)perylene Benzyl alcohol Bis(2-chloroethoxy)methane Bis(2-chloroethyl)ether Bis(2-chloroisopropyl)ether Bis(2-ethylhexyl)phthalate Butyl benzyl phthalate 4-Bromophenyl phenyl ether 4-Chloroaniline 2-Chloronaphthalene 4-Chlorophenyl phenyl ether Chrysene m,p-Cresols o-Cresol Di-n-butyl phthalate Di-n-octyl phthalate Dibenzo(a,h)anthracene Dibenzofuran 3,3'-Dichlorobenzidine Diethyl phthalate Dimethyl phthalate Dimethylaminoazobenzene 7,12-Dimethylbenz(a)anthracene 3,3'-Dimethylbenzidine 1,3-Dinitrobenzene 2,4-Dinitrotoluene 2,6-Dinitrotoluene Dinoseb** Ethyl methanesulfonate Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Hexachloropropene Indeno(1,2,3-cd)pyrene Isophorone Isosafrole Methapyrilene 3-Methylcholanthrene Methyl methanesulfonate 2-Methylnaphthalene Naphthalene 1-Naphthylamine 2-Naphthylamine 0.98 0.98 0.98 0.98 0.98 0.98 0.98 2.9 15 4.9 0.98 0.98 0.98 2.0 0.98 2.0 2.0 4.9 0.98 0.98 0.98 39 0.98 9.8 0.98 0.98 20 2.0 0.98 0.98 3.9 0.98 0.98 0.98 0.98 2.9 2.9 2.9 2.0 0.98 0.98 0.98 3.9 0.98 0.98 0.98 0.98 9.8 9.8 U U U U U U U U U U U U U U U U U U UJ U U U U U U U U U U U U U U U U U U U U U U U UJ U UJ U U U U CCV LCS CCV MS ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 33 of 93 Field ID: 2 Z-15163 82nd Ln N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 1,4-Naphthoquinone 20 UJ CCV ug/L 2-Nitroaniline 0.98 U ug/L 3-Nitroaniline 0.98 U ug/L 4-Nitroaniline 0.98 UJ CCV ug/L Nitrobenzene 2.0 U ug/L Nitroquinoline-1-oxide 20 U ug/L 5-Nitro-o-toluidine 0.98 U ug/L N-Nitrosodiethylamine 0.98 U ug/L N-Nitrosodimethylamine 2.0 U ug/L N-Nitrosodi-n-propylamine 2.0 U ug/L N-Nitrosomethylethylamine 2.0 U ug/L N-Nitrosomorpholine 0.98 U ug/L N-Nitrosopiperidine 0.98 U ug/L N-Nitrosopyrrolidine 2.0 U ug/L Pentachlorobenzene 0.98 U ug/L Pentachloroethane** 49 U ug/L Pentachloronitrobenzene 0.98 U ug/L Phenacetin 3.9 U ug/L Phenanthrene 0.98 U ug/L 2-Picoline 0.98 U ug/L Pyrene 0.98 U ug/L Pyridine 3.9 U ug/L Safrole 0.98 U ug/L 1,2,4,5-Tetrachlorobenzene 0.98 U ug/L o-Toluidine 0.98 U ug/L 1,2,4-Trichlorobenzene 0.98 U ug/L 1,3,5-Trinitrobenzene 3.9 U ug/L 4-Chloro-3-methylphenol 0.98 U ug/L 2-Chlorophenol 0.98 U ug/L 2,4-Dichlorophenol 0.98 U ug/L 2,6-Dichlorophenol 0.98 U ug/L 2,4-Dimethylphenol 9.8 U ug/L 2,4-Dinitrophenol 15 U ug/L 2-Methyl-4,6-dinitrophenol 2.9 U ug/L 2-Nitrophenol 0.98 U ug/L 4-Nitrophenol 15 U ug/L Pentachlorophenol 2.9 U ug/L Phenol 0.98 U ug/L 2,3,4,6-Tetrachlorophenol 2.0 U ug/L 2,4,5-Trichlorophenol 0.98 U ug/L 2,4,6-Trichlorophenol 0.98 U ug/L N-Nitrosodiphenylamine/ Diphenylamine 2.9 U ug/L 1206675 FL-PRO TRPH 0.24 U mg/L 1206703 EPA 504 1,2-Dibromoethane 0.010 U ug/L 1206721 DEP SOP: GC-011-5 (based Aldrin 0.010 U ug/L on EPA Methods 608, 617, 1656) Alpha-BHC 0.010 U ug/L Beta-BHC 0.010 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 34 of 93 Field ID: 2 Z-15163 82nd Ln N Sample ID Ref. Method DEP SOP: GC-012-3 (based on EPA 614, 619, 622, 633 and 507) Matrix: W-GROUND Component Result Code QC Failures Units Cert # Delta-BHC 0.010 U ug/L Gamma-BHC 0.010 U ug/L Chlordane 0.20 U ug/L DDD-p,p' 0.020 U ug/L DDE-p,p' 0.020 U ug/L DDT-p,p' 0.030 U ug/L Dieldrin 0.020 U ug/L Endosulfan I 0.020 U ug/L Endosulfan II 0.020 U ug/L Endosulfan Sulfate 0.020 U ug/L Endrin 0.050 U ug/L Endrin Aldehyde 0.020 U ug/L Heptachlor 0.010 U ug/L Heptachlor Epoxide 0.020 U ug/L Methoxychlor 0.050 U ug/L Toxaphene 0.75 U ug/L PCB-1016 0.20 U ug/L PCB-1221 0.20 U ug/L PCB-1232 0.20 U ug/L PCB-1242 0.30 U ug/L PCB-1248 0.20 U ug/L PCB-1254 0.30 U ug/L PCB-1260 0.20 U ug/L Alachlor 0.60 UJ CCV ug/L Ametryn 0.050 U ug/L Atrazine 0.050 U ug/L Azinphos Methyl 0.20 UJ CCV ug/L Bromacil 0.20 U ug/L Butylate 0.20 UJ CCV ug/L Chlorpyrifos Ethyl 0.050 U ug/L Chlorpyrifos Methyl 0.10 U ug/L Diazinon 0.050 U ug/L Ethion 0.050 U ug/L Ethoprop 0.10 U ug/L Fenamiphos 0.20 U ug/L Fonofos 0.10 U ug/L Hexazinone 0.10 UJ CCV ug/L Malathion 0.15 U ug/L Metalaxyl 0.25 UJ CCV ug/L Metolachlor 0.50 UJ CCV ug/L Metribuzin 0.10 U ug/L Mevinphos 0.20 U ug/L Naled 0.80 U ug/L Norflurazon 0.15 UJ CCV ug/L Parathion Ethyl 0.15 U ug/L Parathion Methyl 0.10 U ug/L Phorate 0.050 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 35 of 93 Field ID: 2 Z-15163 82nd Ln N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Prometon 0.20 U ug/L Prometryn 0.15 U ug/L Simazine 0.050 U ug/L 1206757 EPA 6010C Strontium 795 ug/L Titanium 0.50 U ug/L EPA 6020A Aluminum 5.0 U ug/L Arsenic 0.25 U ug/L Barium 14.9 ug/L Cadmium 0.030 U ug/L Chromium 0.30 U ug/L Copper 0.52 ug/L Lead 0.20 U ug/L Selenium 0.20 U ug/L Silver 0.025 U ug/L EPA 7470A Mercury 0.12 U MS ug/L 1206775 EPA 353.2 Rev. 2.0 NO2NO3-N 0.004 I mg N/L Ref. Method and Comment: EPA 8260C QC failure(s) observed. EPA 8270D QC failure(s) observed. FL-PRO Insufficient sample to perform matrix spikes. DEP SOP: GC-011-5 (based on EPA Methods 608, 617, 1656) Insufficient sample to perform MS duplicate due to loss of sample in sample preparation. DEP SOP: GC-012-3 (based on EPA 614, 619, 622, 633 and 507) Insufficient sample to perform MS duplicate due to loss of sample in sample preparation. QC failure(s) observed. Sample Location: ACREAGE Collection Date/Time: 08/05/2009 12:00 PM Field ID: 3 Z-11546 60th St. N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 1206840 EPA 900.0 Alpha, Total 2.2 U pCi/L E83033 Alpha-Counting Error 1.8 pCi/L 1206848 EPA 6010C Strontium 393 ug/L E31780 Titanium 0.50 U ug/L EPA 6020A Aluminum 5.0 U ug/L Arsenic 0.36 I ug/L Barium 27.7 ug/L Cadmium 0.030 U ug/L Chromium 0.47 I ug/L Copper 0.50 U ug/L Lead 0.20 U ug/L Selenium 0.20 U ug/L Silver 0.025 U ug/L EPA 7470A Mercury 0.12 U ug/L Page 36 of 93 SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Matrix: W-GROUND Result Code UnitsComponent Field ID: 3 Z-11546 60th St. N Sample ID Ref. Method Cert #QC Failures Collection Date/Time: 08/04/2009 03:45 PMSample Location: ACREAGE Field ID: 3 Z-11855 KESWICK WAY Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 1206391 EPA 903.1 and Ra-05 Radium 226 0.3 pCi/L E83033 Radium 226-Counting Error 0.2 pCi/L Radium 228 0.9 U pCi/L Radium 228-Counting Error 0.6 pCi/L 1206397 EPA 900.0 Alpha, Total 2.3 pCi/L Alpha-Counting Error 1.2 pCi/L 1206611 EPA 522 1,4-Dioxane** 0.20 U ug/L E31640 1206629 EPA 8260C Benzene 0.20 U ug/L Bromodichloromethane 0.20 U ug/L Bromoform 0.50 UJ LCS ug/L Bromomethane 0.50 UJ CCV,MS ug/L 2-Butanone 10 U ug/L Carbon tetrachloride 0.20 U ug/L Chlorobenzene 0.20 U ug/L Chloroethane 0.50 U MS ug/L Chloroform 0.20 U ug/L Chloromethane 0.50 U MS ug/L Dibromochloromethane 0.20 U ug/L 1,2-Dichlorobenzene 0.50 U ug/L 1,3-Dichlorobenzene 0.50 U ug/L 1,4-Dichlorobenzene 0.50 U ug/L 1,1-Dichloroethane 0.20 U ug/L 1,2-Dichloroethane 0.20 U ug/L 1,1-Dichloroethene 0.50 U ug/L cis-1,2-Dichloroethene 0.50 U ug/L trans-1,2-Dichloroethene 0.50 U ug/L 1,2-Dichloropropane 0.50 U ug/L cis-1,3-Dichloropropene 0.50 U MS ug/L trans-1,3-Dichloropropene 0.20 UJ CCV,LCS, ug/L MS Ethylbenzene 0.50 U ug/L Methylene chloride 0.50 U ug/L 1,1,2,2-Tetrachloroethane 0.50 UJ CCV ug/L Tetrachloroethene 0.50 U ug/L Toluene 0.50 U ug/L 1,1,1-Trichloroethane 0.20 U ug/L 1,1,2-Trichloroethane 0.20 U ug/L Trichloroethene 0.20 UJ CCV ug/L Trichlorofluoromethane 0.50 U ug/L Vinyl chloride 0.50 U ug/L Methyl-t-butyl ether 0.50 U ug/L o-Xylene 0.20 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 37 of 93 Field ID: 3 Z-11855 KESWICK WAY Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # m,p-Xylene 0.50 U ug/L 1206647 DEP SOP: LC-001-2 2,4-D 0.21 U ug/L E31780 2,4,5-T 0.21 U ug/L Acifluorfen 0.21 U ug/L Silvex 0.21 U ug/L 1206669 EPA 8270D Acenaphthene 0.99 U ug/L Acenaphthylene 0.99 U ug/L Acetophenone 0.99 U ug/L 2-Acetylaminofluorene 0.99 U ug/L 4-Aminobiphenyl 4.0 U ug/L Aniline 0.99 U ug/L Anthracene 0.99 U ug/L Azobenzene/1,2-Diphenylhydrazine 0.99 U ug/L Benzidine 99 U ug/L Benzo(a)anthracene 0.99 U ug/L Benzo(a)pyrene 0.99 U ug/L Benzo(b)fluoranthene 0.99 U ug/L Benzo(k)fluoranthene 0.99 U ug/L Benzo(g,h,i)perylene 0.99 U ug/L Benzyl alcohol 0.99 U ug/L Bis(2-chloroethoxy)methane 0.99 U ug/L Bis(2-chloroethyl)ether 0.99 U ug/L Bis(2-chloroisopropyl)ether 3.0 U ug/L Bis(2-ethylhexyl)phthalate 15 U ug/L Butyl benzyl phthalate 4.9 U ug/L 4-Bromophenyl phenyl ether 0.99 U ug/L 4-Chloroaniline 0.99 U ug/L 2-Chloronaphthalene 0.99 U ug/L 4-Chlorophenyl phenyl ether 2.0 U ug/L Chrysene 0.99 U ug/L m,p-Cresols 2.0 U ug/L o-Cresol 2.0 U ug/L Di-n-butyl phthalate 4.9 U ug/L Di-n-octyl phthalate 0.99 U ug/L Dibenzo(a,h)anthracene 0.99 U ug/L Dibenzofuran 0.99 U ug/L 3,3'-Dichlorobenzidine 40 U ug/L Diethyl phthalate 0.99 U ug/L Dimethyl phthalate 9.9 U ug/L Dimethylaminoazobenzene 0.99 U ug/L 7,12-Dimethylbenz(a)anthracene 0.99 U ug/L 3,3'-Dimethylbenzidine 20 U ug/L 1,3-Dinitrobenzene 2.0 U ug/L 2,4-Dinitrotoluene 0.99 U ug/L 2,6-Dinitrotoluene 0.99 U ug/L Dinoseb** 4.0 U ug/L Ethyl methanesulfonate 0.99 U ug/L Fluoranthene 0.99 U ug/L Fluorene 0.99 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 38 of 93 Field ID: 3 Z-11855 KESWICK WAY Matrix: W-GROUND Sample ID Ref. Method Component Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Hexachloropropene Indeno(1,2,3-cd)pyrene Isophorone Isosafrole Methapyrilene 3-Methylcholanthrene Methyl methanesulfonate 2-Methylnaphthalene Naphthalene 1-Naphthylamine 2-Naphthylamine 1,4-Naphthoquinone 2-Nitroaniline 3-Nitroaniline 4-Nitroaniline Nitrobenzene Nitroquinoline-1-oxide 5-Nitro-o-toluidine N-Nitrosodiethylamine N-Nitrosodimethylamine N-Nitrosodi-n-propylamine N-Nitrosomethylethylamine N-Nitrosomorpholine N-Nitrosopiperidine N-Nitrosopyrrolidine Pentachlorobenzene Pentachloroethane** Pentachloronitrobenzene Phenacetin Phenanthrene 2-Picoline Pyrene Pyridine Safrole 1,2,4,5-Tetrachlorobenzene o-Toluidine 1,2,4-Trichlorobenzene 1,3,5-Trinitrobenzene 4-Chloro-3-methylphenol 2-Chlorophenol 2,4-Dichlorophenol 2,6-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrophenol 2-Methyl-4,6-dinitrophenol Result 0.99 3.0 3.0 3.0 2.0 0.99 0.99 0.99 4.0 0.99 0.99 0.99 0.99 9.9 9.9 20 0.99 0.99 0.99 2.0 20 0.99 0.99 2.0 2.0 2.0 0.99 0.99 2.0 0.99 49 0.99 4.0 0.99 0.99 0.99 4.0 0.99 0.99 0.99 0.99 4.0 0.99 0.99 0.99 0.99 9.9 15 3.0 Code QC Failures Units Cert # U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L UJ CCV,LCS ug/L U ug/L UJ CCV ug/L U ug/L U ug/L U ug/L U MS ug/L UJ CCV ug/L U ug/L U ug/L UJ CCV ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 39 of 93 Field ID: 3 Z-11855 KESWICK WAY Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 2-Nitrophenol 0.99 U ug/L 4-Nitrophenol 15 U ug/L Pentachlorophenol 3.0 U ug/L Phenol 0.99 U ug/L 2,3,4,6-Tetrachlorophenol 2.0 U ug/L 2,4,5-Trichlorophenol 0.99 U ug/L 2,4,6-Trichlorophenol 0.99 U ug/L N-Nitrosodiphenylamine/ Diphenylamine 3.0 U ug/L 1206687 FL-PRO TRPH 0.25 U mg/L 1206715 EPA 504 1,2-Dibromoethane 0.010 U ug/L 1206733 DEP SOP: GC-011-5 (based Aldrin 0.010 U ug/L on EPA Methods 608, 617, 1656) Alpha-BHC 0.010 U ug/L Beta-BHC 0.010 UJ CCV ug/L Delta-BHC 0.010 UJ CCV ug/L Gamma-BHC 0.010 U ug/L Chlordane 0.20 U ug/L DDD-p,p' 0.020 UJ CCV ug/L DDE-p,p' 0.020 UJ CCV ug/L DDT-p,p' 0.030 U ug/L Dieldrin 0.020 U ug/L Endosulfan I 0.020 U ug/L Endosulfan II 0.020 U ug/L Endosulfan Sulfate 0.020 U ug/L Endrin 0.050 U ug/L Endrin Aldehyde 0.020 U ug/L Heptachlor 0.010 U ug/L Heptachlor Epoxide 0.020 U ug/L Methoxychlor 0.050 UJ CCV ug/L Toxaphene 0.75 U ug/L PCB-1016 0.20 U ug/L PCB-1221 0.20 U ug/L PCB-1232 0.20 U ug/L PCB-1242 0.30 U ug/L PCB-1248 0.20 U ug/L PCB-1254 0.30 U ug/L PCB-1260 0.20 U ug/L DEP SOP: GC-012-3 (based Alachlor 0.60 UJ CCV ug/L on EPA 614, 619, 622, 633 and 507) Ametryn 0.050 U ug/L Atrazine 0.050 U ug/L Azinphos Methyl 0.20 UJ CCV ug/L Bromacil 0.20 U ug/L Butylate 0.20 UJ CCV ug/L Chlorpyrifos Ethyl 0.050 U ug/L Chlorpyrifos Methyl 0.10 U ug/L Diazinon 0.050 U ug/L Ethion 0.050 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 40 of 93 Field ID: 3 Z-11855 KESWICK WAY Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Ethoprop 0.10 U ug/L Fenamiphos 0.20 U ug/L Fonofos 0.10 U ug/L Hexazinone 0.10 UJ CCV ug/L Malathion 0.15 U ug/L Metalaxyl 0.25 UJ CCV ug/L Metolachlor 0.50 UJ CCV ug/L Metribuzin 0.10 UJ CCV ug/L Mevinphos 0.20 U ug/L Naled 0.80 U ug/L Norflurazon 0.15 UJ CCV ug/L Parathion Ethyl 0.15 U ug/L Parathion Methyl 0.10 U ug/L Phorate 0.050 U ug/L Prometon 0.20 U ug/L Prometryn 0.15 U ug/L Simazine 0.050 UJ CCV ug/L 1206769 EPA 6010C Strontium 730 ug/L Titanium 0.50 U ug/L EPA 6020A Aluminum 5.0 U ug/L Arsenic 0.25 U ug/L Barium 16.4 ug/L Cadmium 0.030 U ug/L Chromium 0.73 I ug/L Copper 1.01 ug/L Lead 0.20 U ug/L Selenium 0.20 U ug/L Silver 0.025 U ug/L EPA 7470A Mercury 0.12 U MS ug/L 1206787 EPA 353.2 Rev. 2.0 NO2NO3-N 0.006 I mg N/L Ref. Method and Comment: EPA 8260C QC failure(s) observed. EPA 8270D QC failure(s) observed. DEP SOP: GC-011-5 (based on EPA Methods 608, 617, 1656) Insufficient sample to perform MS duplicate due to loss of sample in sample preparation. QC failure(s) observed. DEP SOP: GC-012-3 (based on EPA 614, 619, 622, 633 and 507) Insufficient sample to perform MS duplicate due to loss of sample in sample preparation. QC failure(s) observed. Sample Location: ACREAGE Collection Date/Time: 08/05/2009 09:08 AM Field ID: 3 Z-12325 87th St. N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 1206588 EPA 900.0 Alpha, Total 1.4 pCi/L E83033 Alpha-Counting Error 0.9 pCi/L 1206606 EPA 522 1,4-Dioxane** 0.20 U ug/L E31640 1206624 EPA 8260C Benzene 0.20 U ug/L Bromodichloromethane 0.20 U ug/L Bromoform 0.50 UJ LCS ug/L Bromomethane 0.50 UJ CCV,MS ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 41 of 93 Field ID: 3 Z-12325 87th St. N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 2-Butanone 10 U ug/L Carbon tetrachloride 0.20 U ug/L Chlorobenzene 0.20 U ug/L Chloroethane 0.50 U MS ug/L Chloroform 0.20 U ug/L Chloromethane 0.50 U MS ug/L Dibromochloromethane 0.20 U ug/L 1,2-Dichlorobenzene 0.50 U ug/L 1,3-Dichlorobenzene 0.50 U ug/L 1,4-Dichlorobenzene 0.50 U ug/L 1,1-Dichloroethane 0.20 U ug/L 1,2-Dichloroethane 0.20 U ug/L 1,1-Dichloroethene 0.50 U ug/L cis-1,2-Dichloroethene 0.50 U ug/L trans-1,2-Dichloroethene 0.50 U ug/L 1,2-Dichloropropane 0.50 U ug/L cis-1,3-Dichloropropene 0.50 U MS ug/L trans-1,3-Dichloropropene 0.20 UJ LCS,MS ug/L Ethylbenzene 0.50 U ug/L Methylene chloride 0.50 U ug/L 1,1,2,2-Tetrachloroethane 0.50 UJ CCV ug/L Tetrachloroethene 0.50 U ug/L Toluene 0.50 U ug/L 1,1,1-Trichloroethane 0.20 U ug/L 1,1,2-Trichloroethane 0.20 U ug/L Trichloroethene 0.20 UJ CCV ug/L Trichlorofluoromethane 0.50 U ug/L Vinyl chloride 0.50 U ug/L Methyl-t-butyl ether 0.50 U ug/L o-Xylene 0.20 U ug/L m,p-Xylene 0.50 U ug/L 1206642 DEP SOP: LC-001-2 2,4-D 0.21 U ug/L E31780 2,4,5-T 0.21 U ug/L Acifluorfen 0.21 U ug/L Silvex 0.21 U ug/L 1206664 EPA 8270D Acenaphthene 0.98 U ug/L Acenaphthylene 0.98 U ug/L Acetophenone 0.98 U ug/L 2-Acetylaminofluorene 0.98 U ug/L 4-Aminobiphenyl 3.9 U ug/L Aniline 0.98 U ug/L Anthracene 0.98 U ug/L Azobenzene/1,2-Diphenylhydrazine 0.98 U ug/L Benzidine 98 U ug/L Benzo(a)anthracene 0.98 U ug/L Benzo(a)pyrene 0.98 U ug/L Benzo(b)fluoranthene 0.98 U ug/L Benzo(k)fluoranthene 0.98 U ug/L Benzo(g,h,i)perylene 0.98 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 42 of 93 Field ID: 3 Z-12325 87th St. N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Benzyl alcohol 0.98 U ug/L Bis(2-chloroethoxy)methane 0.98 U ug/L Bis(2-chloroethyl)ether 0.98 U ug/L Bis(2-chloroisopropyl)ether 2.9 U ug/L Bis(2-ethylhexyl)phthalate 15 U ug/L Butyl benzyl phthalate 4.9 U ug/L 4-Bromophenyl phenyl ether 0.98 U ug/L 4-Chloroaniline 0.98 U ug/L 2-Chloronaphthalene 0.98 U ug/L 4-Chlorophenyl phenyl ether 2.0 U ug/L Chrysene 0.98 U ug/L m,p-Cresols 2.0 U ug/L o-Cresol 2.0 U ug/L Di-n-butyl phthalate 4.9 U ug/L Di-n-octyl phthalate 0.98 U ug/L Dibenzo(a,h)anthracene 0.98 U ug/L Dibenzofuran 0.98 U ug/L 3,3'-Dichlorobenzidine 39 U ug/L Diethyl phthalate 0.98 U ug/L Dimethyl phthalate 9.8 U ug/L Dimethylaminoazobenzene 0.98 UJ CCV ug/L 7,12-Dimethylbenz(a)anthracene 0.98 U ug/L 3,3'-Dimethylbenzidine 20 U ug/L 1,3-Dinitrobenzene 2.0 U ug/L 2,4-Dinitrotoluene 0.98 U ug/L 2,6-Dinitrotoluene 0.98 U ug/L Dinoseb** 3.9 U ug/L Ethyl methanesulfonate 0.98 U ug/L Fluoranthene 0.98 U ug/L Fluorene 0.98 U ug/L Hexachlorobenzene 0.98 U ug/L Hexachlorobutadiene 2.9 U ug/L Hexachlorocyclopentadiene 2.9 U ug/L Hexachloroethane 2.9 U ug/L Hexachloropropene 2.0 U ug/L Indeno(1,2,3-cd)pyrene 0.98 U ug/L Isophorone 0.98 U ug/L Isosafrole 0.98 U ug/L Methapyrilene 3.9 UJ CCV,LCS ug/L 3-Methylcholanthrene 0.98 U ug/L Methyl methanesulfonate 0.98 UJ CCV ug/L 2-Methylnaphthalene 0.98 U ug/L Naphthalene 0.98 U ug/L 1-Naphthylamine 9.8 U ug/L 2-Naphthylamine 1,4-Naphthoquinone 9.8 20 UJ UJ LCS,MS,RP D CCV,MS ug/L ug/L 2-Nitroaniline 0.98 U ug/L 3-Nitroaniline 0.98 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 43 of 93 Field ID: 3 Z-12325 87th St. N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 4-Nitroaniline 0.98 UJ CCV ug/L Nitrobenzene 2.0 U ug/L Nitroquinoline-1-oxide 20 UJ LCS,MS ug/L 5-Nitro-o-toluidine 0.98 U ug/L N-Nitrosodiethylamine 0.98 U ug/L N-Nitrosodimethylamine 2.0 U ug/L N-Nitrosodi-n-propylamine 2.0 U ug/L N-Nitrosomethylethylamine 2.0 U ug/L N-Nitrosomorpholine 0.98 U ug/L N-Nitrosopiperidine 0.98 U ug/L N-Nitrosopyrrolidine 2.0 U ug/L Pentachlorobenzene 0.98 U ug/L Pentachloroethane** 49 U ug/L Pentachloronitrobenzene 0.98 U ug/L Phenacetin 3.9 U ug/L Phenanthrene 0.98 U ug/L 2-Picoline 0.98 U ug/L Pyrene 0.98 U ug/L Pyridine 3.9 U ug/L Safrole 0.98 U ug/L 1,2,4,5-Tetrachlorobenzene 0.98 U ug/L o-Toluidine 0.98 U ug/L 1,2,4-Trichlorobenzene 0.98 U ug/L 1,3,5-Trinitrobenzene 3.9 U ug/L 4-Chloro-3-methylphenol 0.98 U ug/L 2-Chlorophenol 0.98 U ug/L 2,4-Dichlorophenol 0.98 U ug/L 2,6-Dichlorophenol 0.98 U ug/L 2,4-Dimethylphenol 9.8 U ug/L 2,4-Dinitrophenol 15 U ug/L 2-Methyl-4,6-dinitrophenol 2.9 U ug/L 2-Nitrophenol 0.98 U ug/L 4-Nitrophenol 15 U ug/L Pentachlorophenol 2.9 U ug/L Phenol 0.98 U ug/L 2,3,4,6-Tetrachlorophenol 2.0 U ug/L 2,4,5-Trichlorophenol 0.98 U ug/L 2,4,6-Trichlorophenol 0.98 UJ CCV ug/L N-Nitrosodiphenylamine/ Diphenylamine 2.9 U ug/L 1206682 FL-PRO TRPH 0.25 U mg/L 1206710 EPA 504 1,2-Dibromoethane 0.010 U ug/L 1206728 DEP SOP: GC-011-5 (based Aldrin 0.0099 U ug/L on EPA Methods 608, 617, 1656) Alpha-BHC 0.0099 U ug/L Beta-BHC 0.0099 U ug/L Delta-BHC 0.0099 U ug/L Gamma-BHC 0.0099 U ug/L Chlordane 0.20 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 44 of 93 Field ID: 3 Z-12325 87th St. N Sample ID Ref. Method DEP SOP: GC-012-3 (based on EPA 614, 619, 622, 633 and 507) Matrix: W-GROUND Component Result Code QC Failures Units Cert # DDD-p,p' 0.020 U ug/L DDE-p,p' 0.020 U ug/L DDT-p,p' 0.030 U ug/L Dieldrin 0.020 U ug/L Endosulfan I 0.020 U ug/L Endosulfan II 0.020 U ug/L Endosulfan Sulfate 0.020 U ug/L Endrin 0.049 U ug/L Endrin Aldehyde 0.020 U ug/L Heptachlor 0.0099 U ug/L Heptachlor Epoxide 0.020 U ug/L Methoxychlor 0.049 U ug/L Toxaphene 0.74 U ug/L PCB-1016 0.20 U ug/L PCB-1221 0.20 U ug/L PCB-1232 0.20 U ug/L PCB-1242 0.30 U ug/L PCB-1248 0.20 U ug/L PCB-1254 0.30 U ug/L PCB-1260 0.20 U ug/L Alachlor 0.59 UJ CCV ug/L Ametryn 0.049 U ug/L Atrazine 0.049 U ug/L Azinphos Methyl 0.20 UJ CCV ug/L Bromacil 0.20 U ug/L Butylate 0.20 UJ CCV ug/L Chlorpyrifos Ethyl 0.049 U ug/L Chlorpyrifos Methyl 0.099 U ug/L Diazinon 0.049 U ug/L Ethion 0.049 U ug/L Ethoprop 0.099 U ug/L Fenamiphos 0.20 U ug/L Fonofos 0.099 U ug/L Hexazinone 0.099 UJ CCV ug/L Malathion 0.15 U ug/L Metalaxyl 0.25 UJ CCV ug/L Metolachlor 0.49 UJ CCV ug/L Metribuzin 0.099 UJ CCV ug/L Mevinphos 0.20 U ug/L Naled 0.79 U ug/L Norflurazon 0.15 UJ CCV ug/L Parathion Ethyl 0.15 U ug/L Parathion Methyl 0.099 U ug/L Phorate 0.049 U ug/L Prometon 0.20 U ug/L Prometryn 0.15 U ug/L Simazine 0.049 UJ CCV ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 45 of 93 Field ID: 3 Z-12325 87th St. N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 1206764 EPA 6010C Strontium 436 ug/L Titanium 0.50 U ug/L EPA 6020A Aluminum 31 ug/L Arsenic 0.25 U ug/L Barium 14.9 ug/L Cadmium 0.030 U ug/L Chromium 0.73 I ug/L Copper 2.09 ug/L Lead 0.38 I ug/L Selenium 0.20 U ug/L Silver 0.025 U ug/L EPA 7470A Mercury 0.12 U MS ug/L 1206782 EPA 353.2 Rev. 2.0 NO2NO3-N 0.004 U mg N/L Ref. Method and Comment: EPA 8260C QC failure(s) observed. EPA 8270D QC failure(s) observed. DEP SOP: GC-011-5 (based on EPA Methods 608, 617, 1656) Insufficient sample to perform MS duplicate due to loss of sample in sample preparation. DEP SOP: GC-012-3 (based on EPA 614, 619, 622, 633 and 507) Insufficient sample to perform MS duplicate due to loss of sample in sample preparation. QC failure(s) observed. Sample Location: ACREAGE Collection Date/Time: 08/05/2009 09:08 AM Field ID: 3 Z-12325 87th St. N DUP Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 1206589 EPA 900.0 Alpha, Total 1.9 U pCi/L E83033 Alpha-Counting Error 1.2 pCi/L 1206607 EPA 522 1,4-Dioxane** 0.20 U ug/L E31640 1206625 EPA 8260C Benzene 0.20 U ug/L Bromodichloromethane 0.20 U ug/L Bromoform 0.50 UJ LCS ug/L Bromomethane 0.50 UJ CCV,MS ug/L 2-Butanone 10 U ug/L Carbon tetrachloride 0.20 U ug/L Chlorobenzene 0.20 U ug/L Chloroethane 0.50 U MS ug/L Chloroform 0.20 U ug/L Chloromethane 0.50 U MS ug/L Dibromochloromethane 0.20 U ug/L 1,2-Dichlorobenzene 0.50 U ug/L 1,3-Dichlorobenzene 0.50 U ug/L 1,4-Dichlorobenzene 0.50 U ug/L 1,1-Dichloroethane 0.20 U ug/L 1,2-Dichloroethane 0.20 U ug/L 1,1-Dichloroethene 0.50 U ug/L cis-1,2-Dichloroethene 0.50 U ug/L trans-1,2-Dichloroethene 0.50 U ug/L 1,2-Dichloropropane 0.50 U ug/L cis-1,3-Dichloropropene 0.50 U MS ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 46 of 93 Field ID: 3 Z-12325 87th St. N DUP Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # trans-1,3-Dichloropropene 0.20 UJ LCS,MS ug/L Ethylbenzene 0.50 U ug/L Methylene chloride 0.50 U ug/L 1,1,2,2-Tetrachloroethane 0.50 UJ CCV ug/L Tetrachloroethene 0.50 U ug/L Toluene 0.50 U ug/L 1,1,1-Trichloroethane 0.20 U ug/L 1,1,2-Trichloroethane 0.20 U ug/L Trichloroethene 0.20 UJ CCV ug/L Trichlorofluoromethane 0.50 U ug/L Vinyl chloride 0.50 U ug/L Methyl-t-butyl ether 0.50 U ug/L o-Xylene 0.20 U ug/L m,p-Xylene 0.50 U ug/L 1206643 DEP SOP: LC-001-2 2,4-D 0.21 U ug/L E31780 2,4,5-T 0.21 U ug/L Acifluorfen 0.21 U ug/L Silvex 0.21 U ug/L 1206665 EPA 8270D Acenaphthene 0.98 U ug/L Acenaphthylene 0.98 U ug/L Acetophenone 0.98 U ug/L 2-Acetylaminofluorene 0.98 U ug/L 4-Aminobiphenyl 3.9 U ug/L Aniline 0.98 U ug/L Anthracene 0.98 U ug/L Azobenzene/1,2-Diphenylhydrazine 0.98 U ug/L Benzidine 98 U ug/L Benzo(a)anthracene 0.98 U ug/L Benzo(a)pyrene 0.98 U ug/L Benzo(b)fluoranthene 0.98 U ug/L Benzo(k)fluoranthene 0.98 U ug/L Benzo(g,h,i)perylene 0.98 U ug/L Benzyl alcohol 0.98 U ug/L Bis(2-chloroethoxy)methane 0.98 U ug/L Bis(2-chloroethyl)ether 0.98 U ug/L Bis(2-chloroisopropyl)ether 2.9 U ug/L Bis(2-ethylhexyl)phthalate 15 U ug/L Butyl benzyl phthalate 4.9 U ug/L 4-Bromophenyl phenyl ether 0.98 U ug/L 4-Chloroaniline 0.98 U ug/L 2-Chloronaphthalene 0.98 U ug/L 4-Chlorophenyl phenyl ether 2.0 U ug/L Chrysene 0.98 U ug/L m,p-Cresols 2.0 U ug/L o-Cresol 2.0 U ug/L Di-n-butyl phthalate 4.9 U ug/L Di-n-octyl phthalate 0.98 U ug/L Dibenzo(a,h)anthracene 0.98 U ug/L Dibenzofuran 0.98 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 47 of 93 Field ID: 3 Z-12325 87th St. N DUP Matrix: W-GROUND Sample ID Ref. Method Component 3,3'-Dichlorobenzidine Diethyl phthalate Dimethyl phthalate Dimethylaminoazobenzene 7,12-Dimethylbenz(a)anthracene 3,3'-Dimethylbenzidine 1,3-Dinitrobenzene 2,4-Dinitrotoluene 2,6-Dinitrotoluene Dinoseb** Ethyl methanesulfonate Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Hexachloropropene Indeno(1,2,3-cd)pyrene Isophorone Isosafrole Methapyrilene 3-Methylcholanthrene Methyl methanesulfonate 2-Methylnaphthalene Naphthalene 1-Naphthylamine 2-Naphthylamine 1,4-Naphthoquinone 2-Nitroaniline 3-Nitroaniline 4-Nitroaniline Nitrobenzene Nitroquinoline-1-oxide 5-Nitro-o-toluidine N-Nitrosodiethylamine N-Nitrosodimethylamine N-Nitrosodi-n-propylamine N-Nitrosomethylethylamine N-Nitrosomorpholine N-Nitrosopiperidine N-Nitrosopyrrolidine Pentachlorobenzene Pentachloroethane** Pentachloronitrobenzene Phenacetin Phenanthrene 2-Picoline Result 39 0.98 9.8 0.98 0.98 20 2.0 0.98 0.98 3.9 0.98 0.98 0.98 0.98 2.9 2.9 2.9 2.0 0.98 0.98 0.98 3.9 0.98 0.98 0.98 0.98 9.8 9.8 20 0.98 0.98 0.98 2.0 20 0.98 0.98 2.0 2.0 2.0 0.98 0.98 2.0 0.98 49 0.98 3.9 0.98 0.98 Code QC Failures Units Cert # U ug/L U ug/L U ug/L UJ CCV ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L UJ CCV,LCS ug/L U ug/L UJ CCV ug/L U ug/L U ug/L U ug/L UJ LCS,MS,RP ug/L D UJ CCV,MS ug/L U ug/L U ug/L UJ CCV ug/L U ug/L UJ LCS,MS ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 48 of 93 Field ID: 3 Z-12325 87th St. N DUP Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Pyrene 0.98 U ug/L Pyridine 3.9 U ug/L Safrole 0.98 U ug/L 1,2,4,5-Tetrachlorobenzene 0.98 U ug/L o-Toluidine 0.98 U ug/L 1,2,4-Trichlorobenzene 0.98 U ug/L 1,3,5-Trinitrobenzene 3.9 U ug/L 4-Chloro-3-methylphenol 0.98 U ug/L 2-Chlorophenol 0.98 U ug/L 2,4-Dichlorophenol 0.98 U ug/L 2,6-Dichlorophenol 0.98 U ug/L 2,4-Dimethylphenol 9.8 U ug/L 2,4-Dinitrophenol 15 U ug/L 2-Methyl-4,6-dinitrophenol 2.9 U ug/L 2-Nitrophenol 0.98 U ug/L 4-Nitrophenol 15 U ug/L Pentachlorophenol 2.9 U ug/L Phenol 0.98 U ug/L 2,3,4,6-Tetrachlorophenol 2.0 U ug/L 2,4,5-Trichlorophenol 0.98 U ug/L 2,4,6-Trichlorophenol 0.98 UJ CCV ug/L N-Nitrosodiphenylamine/ Diphenylamine 2.9 U ug/L 1206683 FL-PRO TRPH 0.24 U mg/L 1206711 EPA 504 1,2-Dibromoethane 0.011 U ug/L 1206729 DEP SOP: GC-011-5 (based Aldrin 0.0098 U ug/L on EPA Methods 608, 617, 1656) Alpha-BHC 0.0098 U ug/L Beta-BHC 0.0098 U ug/L Delta-BHC 0.0098 U ug/L Gamma-BHC 0.0098 U ug/L Chlordane 0.20 U ug/L DDD-p,p' 0.020 U ug/L DDE-p,p' 0.020 U ug/L DDT-p,p' 0.030 U ug/L Dieldrin 0.020 U ug/L Endosulfan I 0.020 U ug/L Endosulfan II 0.020 U ug/L Endosulfan Sulfate 0.020 U ug/L Endrin 0.049 U ug/L Endrin Aldehyde 0.020 U ug/L Heptachlor 0.0098 U ug/L Heptachlor Epoxide 0.020 U ug/L Methoxychlor 0.049 U ug/L Toxaphene 0.74 U ug/L PCB-1016 0.20 U ug/L PCB-1221 0.20 U ug/L PCB-1232 0.20 U ug/L PCB-1242 0.30 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 49 of 93 Field ID: 3 Z-12325 87th St. N DUP Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # PCB-1248 0.20 U ug/L PCB-1254 0.30 U ug/L PCB-1260 0.20 U ug/L DEP SOP: GC-012-3 (based Alachlor 0.59 UJ CCV ug/L on EPA 614, 619, 622, 633 and 507) Ametryn 0.049 U ug/L Atrazine 0.049 U ug/L Azinphos Methyl 0.20 UJ CCV ug/L Bromacil 0.20 U ug/L Butylate 0.20 UJ CCV ug/L Chlorpyrifos Ethyl 0.049 U ug/L Chlorpyrifos Methyl 0.098 U ug/L Diazinon 0.049 U ug/L Ethion 0.049 U ug/L Ethoprop 0.098 U ug/L Fenamiphos 0.20 U ug/L Fonofos 0.098 U ug/L Hexazinone 0.098 UJ CCV ug/L Malathion 0.15 U ug/L Metalaxyl 0.25 UJ CCV ug/L Metolachlor 0.49 UJ CCV ug/L Metribuzin 0.098 UJ CCV ug/L Mevinphos 0.20 U ug/L Naled 0.79 U ug/L Norflurazon 0.15 UJ CCV ug/L Parathion Ethyl 0.15 U ug/L Parathion Methyl 0.098 U ug/L Phorate 0.049 U ug/L Prometon 0.20 U ug/L Prometryn 0.15 U ug/L Simazine 0.049 UJ CCV ug/L 1206765 EPA 6010C Strontium 438 ug/L Titanium 0.50 I ug/L EPA 6020A Aluminum 39 ug/L Arsenic 0.25 U ug/L Barium 15.2 ug/L Cadmium 0.030 U ug/L Chromium 0.76 I ug/L Copper 3.70 ug/L Lead 0.63 I ug/L Selenium 0.20 U ug/L Silver 0.025 U ug/L EPA 7470A Mercury 0.12 U MS ug/L 1206783 EPA 353.2 Rev. 2.0 NO2NO3-N 0.004 U mg N/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 50 of 93 Field ID: 3 Z-12325 87th St. N DUP Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Ref. Method and Comment: EPA 8260C QC failure(s) observed. EPA 8270D QC failure(s) observed. DEP SOP: GC-011-5 (based on EPA Methods 608, 617, 1656) preparation. DEP SOP: GC-012-3 (based on EPA 614, 619, 622, 633 and 507) preparation. QC failure(s) observed. Insufficient sample to perform MS duplicate due to loss of sample in sample Insufficient sample to perform MS duplicate due to loss of sample in sample Sample Location: ACREAGE Collection Date/Time: 08/05/2009 09:05 AM Field ID: 3 Z-13048 82nd St N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 1206587 EPA 900.0 Alpha, Total 2.7 U pCi/L E83033 Alpha-Counting Error 1.9 pCi/L 1206605 EPA 522 1,4-Dioxane** 0.20 U ug/L E31640 1206623 EPA 8260C Benzene 0.20 U ug/L Bromodichloromethane 0.20 U ug/L Bromoform 0.50 UJ LCS ug/L Bromomethane 0.50 UJ CCV,MS ug/L 2-Butanone 10 U ug/L Carbon tetrachloride 0.20 U ug/L Chlorobenzene 0.20 U ug/L Chloroethane 0.50 U MS ug/L Chloroform 0.20 U ug/L Chloromethane 0.50 U MS ug/L Dibromochloromethane 0.20 U ug/L 1,2-Dichlorobenzene 0.50 U ug/L 1,3-Dichlorobenzene 0.50 U ug/L 1,4-Dichlorobenzene 0.50 U ug/L 1,1-Dichloroethane 0.20 U ug/L 1,2-Dichloroethane 0.20 U ug/L 1,1-Dichloroethene 0.50 U ug/L cis-1,2-Dichloroethene 0.50 U ug/L trans-1,2-Dichloroethene 0.50 U ug/L 1,2-Dichloropropane 0.50 U ug/L cis-1,3-Dichloropropene 0.50 U MS ug/L trans-1,3-Dichloropropene 0.20 UJ LCS,MS ug/L Ethylbenzene 0.50 U ug/L Methylene chloride 0.50 U ug/L 1,1,2,2-Tetrachloroethane 0.50 UJ CCV ug/L Tetrachloroethene 0.50 U ug/L Toluene 0.50 U ug/L 1,1,1-Trichloroethane 0.20 U ug/L 1,1,2-Trichloroethane 0.20 U ug/L Trichloroethene 0.20 UJ CCV ug/L Trichlorofluoromethane 0.50 U ug/L Vinyl chloride 0.50 U ug/L Methyl-t-butyl ether 0.50 U ug/L o-Xylene 0.20 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 51 of 93 Field ID: 3 Z-13048 82nd St N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # m,p-Xylene 0.50 U ug/L 1206641 DEP SOP: LC-001-2 2,4-D 0.21 U ug/L E31780 2,4,5-T 0.21 U ug/L Acifluorfen 0.21 U ug/L Silvex 0.21 U ug/L 1206663 EPA 8270D Acenaphthene 0.96 U ug/L Acenaphthylene 0.96 U ug/L Acetophenone 0.96 U ug/L 2-Acetylaminofluorene 0.96 U ug/L 4-Aminobiphenyl 3.9 U ug/L Aniline 0.96 U ug/L Anthracene 0.96 U ug/L Azobenzene/1,2-Diphenylhydrazine 0.96 U ug/L Benzidine 96 U ug/L Benzo(a)anthracene 0.96 U ug/L Benzo(a)pyrene 0.96 U ug/L Benzo(b)fluoranthene 0.96 U ug/L Benzo(k)fluoranthene 0.96 U ug/L Benzo(g,h,i)perylene 0.96 U ug/L Benzyl alcohol 0.96 U ug/L Bis(2-chloroethoxy)methane 0.96 U ug/L Bis(2-chloroethyl)ether 0.96 U ug/L Bis(2-chloroisopropyl)ether 2.9 U ug/L Bis(2-ethylhexyl)phthalate 14 U ug/L Butyl benzyl phthalate 4.8 U ug/L 4-Bromophenyl phenyl ether 0.96 U ug/L 4-Chloroaniline 0.96 U ug/L 2-Chloronaphthalene 0.96 U ug/L 4-Chlorophenyl phenyl ether 1.9 U ug/L Chrysene 0.96 U ug/L m,p-Cresols 1.9 U ug/L o-Cresol 1.9 U ug/L Di-n-butyl phthalate 4.8 U ug/L Di-n-octyl phthalate 0.96 U ug/L Dibenzo(a,h)anthracene 0.96 U ug/L Dibenzofuran 0.96 U ug/L 3,3'-Dichlorobenzidine 39 U ug/L Diethyl phthalate 0.96 U ug/L Dimethyl phthalate 9.6 U ug/L Dimethylaminoazobenzene 0.96 UJ CCV ug/L 7,12-Dimethylbenz(a)anthracene 0.96 U ug/L 3,3'-Dimethylbenzidine 19 U ug/L 1,3-Dinitrobenzene 1.9 U ug/L 2,4-Dinitrotoluene 0.96 U ug/L 2,6-Dinitrotoluene 0.96 U ug/L Dinoseb** 3.9 U ug/L Ethyl methanesulfonate 0.96 U ug/L Fluoranthene 0.96 U ug/L Fluorene 0.96 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 52 of 93 Field ID: 3 Z-13048 82nd St N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Hexachlorobenzene 0.96 U ug/L Hexachlorobutadiene 2.9 U ug/L Hexachlorocyclopentadiene 2.9 U ug/L Hexachloroethane 2.9 U ug/L Hexachloropropene 1.9 U ug/L Indeno(1,2,3-cd)pyrene 0.96 U ug/L Isophorone 0.96 U ug/L Isosafrole 0.96 U ug/L Methapyrilene 3.9 UJ CCV,LCS ug/L 3-Methylcholanthrene 0.96 U ug/L Methyl methanesulfonate 0.96 UJ CCV ug/L 2-Methylnaphthalene 0.96 U ug/L Naphthalene 0.96 U ug/L 1-Naphthylamine 9.6 U ug/L 2-Naphthylamine 1,4-Naphthoquinone 9.6 19 UJ UJ LCS,MS,RP D CCV,MS ug/L ug/L 2-Nitroaniline 0.96 U ug/L 3-Nitroaniline 0.96 U ug/L 4-Nitroaniline 0.96 UJ CCV ug/L Nitrobenzene 1.9 U ug/L Nitroquinoline-1-oxide 19 UJ LCS,MS ug/L 5-Nitro-o-toluidine 0.96 U ug/L N-Nitrosodiethylamine 0.96 U ug/L N-Nitrosodimethylamine 1.9 U ug/L N-Nitrosodi-n-propylamine 1.9 U ug/L N-Nitrosomethylethylamine 1.9 U ug/L N-Nitrosomorpholine 0.96 U ug/L N-Nitrosopiperidine 0.96 U ug/L N-Nitrosopyrrolidine 1.9 U ug/L Pentachlorobenzene 0.96 U ug/L Pentachloroethane** 48 U ug/L Pentachloronitrobenzene 0.96 U ug/L Phenacetin 3.9 U ug/L Phenanthrene 0.96 U ug/L 2-Picoline 0.96 U ug/L Pyrene 0.96 U ug/L Pyridine 3.9 U ug/L Safrole 0.96 U ug/L 1,2,4,5-Tetrachlorobenzene 0.96 U ug/L o-Toluidine 0.96 U ug/L 1,2,4-Trichlorobenzene 0.96 U ug/L 1,3,5-Trinitrobenzene 3.9 U ug/L 4-Chloro-3-methylphenol 0.96 U ug/L 2-Chlorophenol 0.96 U ug/L 2,4-Dichlorophenol 0.96 U ug/L 2,6-Dichlorophenol 0.96 U ug/L 2,4-Dimethylphenol 9.6 U ug/L 2,4-Dinitrophenol 14 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 53 of 93 Field ID: 3 Z-13048 82nd St N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 2-Methyl-4,6-dinitrophenol 2.9 U ug/L 2-Nitrophenol 0.96 U ug/L 4-Nitrophenol 14 U ug/L Pentachlorophenol 2.9 U ug/L Phenol 0.96 U ug/L 2,3,4,6-Tetrachlorophenol 1.9 U ug/L 2,4,5-Trichlorophenol 0.96 U ug/L 2,4,6-Trichlorophenol 0.96 UJ CCV ug/L N-Nitrosodiphenylamine/ Diphenylamine 2.9 U ug/L 1206681 FL-PRO TRPH 0.24 U mg/L 1206709 EPA 504 1,2-Dibromoethane 0.010 U ug/L 1206727 DEP SOP: GC-011-5 (based Aldrin 0.0096 U ug/L on EPA Methods 608, 617, 1656) Alpha-BHC 0.0096 U ug/L Beta-BHC 0.0096 U ug/L Delta-BHC 0.0096 U ug/L Gamma-BHC 0.0096 U ug/L Chlordane 0.19 U ug/L DDD-p,p' 0.019 U ug/L DDE-p,p' 0.019 U ug/L DDT-p,p' 0.029 U ug/L Dieldrin 0.019 U ug/L Endosulfan I 0.019 U ug/L Endosulfan II 0.019 U ug/L Endosulfan Sulfate 0.019 U ug/L Endrin 0.048 U ug/L Endrin Aldehyde 0.019 U ug/L Heptachlor 0.0096 U ug/L Heptachlor Epoxide 0.019 U ug/L Methoxychlor 0.048 U ug/L Toxaphene 0.72 U ug/L PCB-1016 0.19 U ug/L PCB-1221 0.19 U ug/L PCB-1232 0.19 U ug/L PCB-1242 0.29 U ug/L PCB-1248 0.19 U ug/L PCB-1254 0.29 U ug/L PCB-1260 0.19 U ug/L DEP SOP: GC-012-3 (based Alachlor 0.57 UJ CCV ug/L on EPA 614, 619, 622, 633 and 507) Ametryn 0.048 U ug/L Atrazine 0.048 U ug/L Azinphos Methyl 0.19 UJ CCV ug/L Bromacil 0.19 U ug/L Butylate 0.19 UJ CCV ug/L Chlorpyrifos Ethyl 0.048 U ug/L Chlorpyrifos Methyl 0.096 U ug/L Diazinon 0.048 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 54 of 93 Field ID: 3 Z-13048 82nd St N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Ethion 0.048 U ug/L Ethoprop 0.096 U ug/L Fenamiphos 0.19 U ug/L Fonofos 0.096 U ug/L Hexazinone 0.096 UJ CCV ug/L Malathion 0.14 U ug/L Metalaxyl 0.24 UJ CCV ug/L Metolachlor 0.48 UJ CCV ug/L Metribuzin 0.096 UJ CCV ug/L Mevinphos 0.19 U ug/L Naled 0.76 U ug/L Norflurazon 0.14 UJ CCV ug/L Parathion Ethyl 0.14 U ug/L Parathion Methyl 0.096 U ug/L Phorate 0.048 U ug/L Prometon 0.19 U ug/L Prometryn 0.14 U ug/L Simazine 0.048 UJ CCV ug/L 1206763 EPA 6010C Strontium 889 ug/L Titanium 0.50 U ug/L EPA 6020A Aluminum 5.0 U ug/L Arsenic 0.25 U ug/L Barium 10.4 ug/L Cadmium 0.030 U ug/L Chromium 0.40 I ug/L Copper 8.48 ug/L Lead 0.41 I ug/L Selenium 0.20 U ug/L Silver 0.025 U ug/L EPA 7470A Mercury 0.12 U MS ug/L 1206781 EPA 353.2 Rev. 2.0 NO2NO3-N 0.004 U mg N/L Ref. Method and Comment: EPA 8260C QC failure(s) observed. EPA 8270D QC failure(s) observed. FL-PRO Insufficient sample to perform matrix spikes. DEP SOP: GC-011-5 (based on EPA Methods 608, 617, 1656) Insufficient sample to perform MS duplicate due to loss of sample in sample preparation. DEP SOP: GC-012-3 (based on EPA 614, 619, 622, 633 and 507) Insufficient sample to perform MS duplicate due to loss of sample in sample preparation. QC failure(s) observed. Sample Location: ACREAGE Collection Date/Time: 08/05/2009 10:50 AM Field ID: 3 Z-13678 82nd St. N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 1206592 EPA 900.0 Alpha, Total 1.3 U pCi/L E83033 Alpha-Counting Error 0.9 pCi/L 1206610 EPA 522 1,4-Dioxane** 0.20 U ug/L E31640 1206628 EPA 8260C Benzene 0.20 U ug/L Bromodichloromethane 0.20 U ug/L Bromoform 0.50 UJ LCS ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 55 of 93 Field ID: 3 Z-13678 82nd St. N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Bromomethane 0.50 UJ CCV,MS ug/L 2-Butanone 10 U ug/L Carbon tetrachloride 0.20 U ug/L Chlorobenzene 0.20 U ug/L Chloroethane 0.50 U MS ug/L Chloroform 0.20 U ug/L Chloromethane 0.50 U MS ug/L Dibromochloromethane 0.20 U ug/L 1,2-Dichlorobenzene 0.50 U ug/L 1,3-Dichlorobenzene 0.50 U ug/L 1,4-Dichlorobenzene 0.50 U ug/L 1,1-Dichloroethane 0.20 U ug/L 1,2-Dichloroethane 0.20 U ug/L 1,1-Dichloroethene 0.50 U ug/L cis-1,2-Dichloroethene 0.50 U ug/L trans-1,2-Dichloroethene 0.50 U ug/L 1,2-Dichloropropane 0.50 U ug/L cis-1,3-Dichloropropene 0.50 U MS ug/L trans-1,3-Dichloropropene 0.20 UJ CCV,LCS, ug/L MS Ethylbenzene 0.50 U ug/L Methylene chloride 0.50 U ug/L 1,1,2,2-Tetrachloroethane 0.50 UJ CCV ug/L Tetrachloroethene 0.50 U ug/L Toluene 0.50 U ug/L 1,1,1-Trichloroethane 0.20 U ug/L 1,1,2-Trichloroethane 0.20 U ug/L Trichloroethene 0.20 UJ CCV ug/L Trichlorofluoromethane 0.50 U ug/L Vinyl chloride 0.50 U ug/L Methyl-t-butyl ether 0.50 U ug/L o-Xylene 0.20 U ug/L m,p-Xylene 0.50 U ug/L 1206646 DEP SOP: LC-001-2 2,4-D 0.20 U ug/L E31780 2,4,5-T 0.20 U ug/L Acifluorfen 0.20 U ug/L Silvex 0.20 U ug/L 1206668 EPA 8270D Acenaphthene 0.95 U ug/L Acenaphthylene 0.95 U ug/L Acetophenone 0.95 U ug/L 2-Acetylaminofluorene 0.95 U ug/L 4-Aminobiphenyl 3.8 U MS ug/L Aniline 0.95 U ug/L Anthracene 0.95 U ug/L Azobenzene/1,2-Diphenylhydrazine 0.95 U ug/L Benzidine 95 U ug/L Benzo(a)anthracene 0.95 U ug/L Benzo(a)pyrene 0.95 U ug/L Benzo(b)fluoranthene 0.95 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 56 of 93 Field ID: 3 Z-13678 82nd St. N Sample ID Ref. Method Component Result Code Matrix: W-GROUND Units Cert #QC Failures Benzo(k)fluoranthene Benzo(g,h,i)perylene Benzyl alcohol Bis(2-chloroethoxy)methane Bis(2-chloroethyl)ether Bis(2-chloroisopropyl)ether Bis(2-ethylhexyl)phthalate Butyl benzyl phthalate 4-Bromophenyl phenyl ether 4-Chloroaniline 2-Chloronaphthalene 4-Chlorophenyl phenyl ether Chrysene m,p-Cresols o-Cresol Di-n-butyl phthalate Di-n-octyl phthalate Dibenzo(a,h)anthracene Dibenzofuran 3,3'-Dichlorobenzidine Diethyl phthalate Dimethyl phthalate Dimethylaminoazobenzene 7,12-Dimethylbenz(a)anthracene 3,3'-Dimethylbenzidine 1,3-Dinitrobenzene 2,4-Dinitrotoluene 2,6-Dinitrotoluene Dinoseb** Ethyl methanesulfonate Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Hexachloropropene Indeno(1,2,3-cd)pyrene Isophorone Isosafrole Methapyrilene 3-Methylcholanthrene Methyl methanesulfonate 2-Methylnaphthalene Naphthalene 1-Naphthylamine 2-Naphthylamine 1,4-Naphthoquinone 2-Nitroaniline 0.95 0.95 0.95 0.95 0.95 2.9 14 4.8 0.95 0.95 0.95 1.9 0.95 1.9 1.9 4.8 0.95 0.95 0.95 38 0.95 9.5 0.95 0.95 19 1.9 0.95 0.95 3.8 0.95 0.95 0.95 0.95 2.9 2.9 2.9 1.9 0.95 0.95 0.95 3.8 0.95 0.95 0.95 0.95 9.5 9.5 19 0.95 U U U U U U U U U U U U U U U U UJ U U U U U U U U U U U U U U U U U U U U U U U UJ U UJ U U U U UJ U ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/LCCV ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/LLCS ug/L ug/LCCV ug/L ug/L ug/LMS ug/LMS ug/LCCV,MS ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 57 of 93 Field ID: 3 Z-13678 82nd St. N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 3-Nitroaniline 0.95 U ug/L 4-Nitroaniline 0.95 UJ CCV ug/L Nitrobenzene 1.9 U ug/L Nitroquinoline-1-oxide 19 U MS,RPD ug/L 5-Nitro-o-toluidine 0.95 U ug/L N-Nitrosodiethylamine 0.95 U ug/L N-Nitrosodimethylamine 1.9 U ug/L N-Nitrosodi-n-propylamine 1.9 U ug/L N-Nitrosomethylethylamine 1.9 U ug/L N-Nitrosomorpholine 0.95 U ug/L N-Nitrosopiperidine 0.95 U ug/L N-Nitrosopyrrolidine 1.9 U ug/L Pentachlorobenzene 0.95 U ug/L Pentachloroethane** 48 U ug/L Pentachloronitrobenzene 0.95 U ug/L Phenacetin 3.8 U ug/L Phenanthrene 0.95 U ug/L 2-Picoline 0.95 U ug/L Pyrene 0.95 U ug/L Pyridine 3.8 U ug/L Safrole 0.95 U ug/L 1,2,4,5-Tetrachlorobenzene 0.95 U ug/L o-Toluidine 0.95 U ug/L 1,2,4-Trichlorobenzene 0.95 U ug/L 1,3,5-Trinitrobenzene 3.8 U ug/L 4-Chloro-3-methylphenol 0.95 U ug/L 2-Chlorophenol 0.95 U ug/L 2,4-Dichlorophenol 0.95 U ug/L 2,6-Dichlorophenol 0.95 U ug/L 2,4-Dimethylphenol 9.5 U ug/L 2,4-Dinitrophenol 14 U ug/L 2-Methyl-4,6-dinitrophenol 2.9 U ug/L 2-Nitrophenol 0.95 U ug/L 4-Nitrophenol 14 U ug/L Pentachlorophenol 2.9 U ug/L Phenol 0.95 U ug/L 2,3,4,6-Tetrachlorophenol 1.9 U ug/L 2,4,5-Trichlorophenol 0.95 U ug/L 2,4,6-Trichlorophenol 0.95 U ug/L N-Nitrosodiphenylamine/ Diphenylamine 2.9 U ug/L 1206686 FL-PRO TRPH 0.24 U mg/L 1206714 EPA 504 1,2-Dibromoethane 0.010 U ug/L 1206732 DEP SOP: GC-011-5 (based Aldrin 0.0096 U ug/L on EPA Methods 608, 617, 1656) Alpha-BHC 0.0096 U ug/L Beta-BHC 0.0096 UJ CCV ug/L Delta-BHC 0.0096 UJ CCV ug/L Gamma-BHC 0.0096 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 58 of 93 Field ID: 3 Z-13678 82nd St. N Sample ID Ref. Method DEP SOP: GC-012-3 (based on EPA 614, 619, 622, 633 and 507) Matrix: W-GROUND Component Result Code QC Failures Units Cert # Chlordane 0.19 U ug/L DDD-p,p' 0.019 UJ CCV ug/L DDE-p,p' 0.019 UJ CCV ug/L DDT-p,p' 0.029 U ug/L Dieldrin 0.019 U ug/L Endosulfan I 0.019 U ug/L Endosulfan II 0.019 U ug/L Endosulfan Sulfate 0.019 U ug/L Endrin 0.048 U ug/L Endrin Aldehyde 0.019 U ug/L Heptachlor 0.0096 U ug/L Heptachlor Epoxide 0.019 U ug/L Methoxychlor 0.048 UJ CCV ug/L Toxaphene 0.72 U ug/L PCB-1016 0.19 U ug/L PCB-1221 0.19 U ug/L PCB-1232 0.19 U ug/L PCB-1242 0.29 U ug/L PCB-1248 0.19 U ug/L PCB-1254 0.29 U ug/L PCB-1260 0.19 U ug/L Alachlor 0.58 UJ CCV ug/L Ametryn 0.048 U ug/L Atrazine 0.048 U ug/L Azinphos Methyl 0.19 UJ CCV ug/L Bromacil 0.19 U ug/L Butylate 0.19 UJ CCV ug/L Chlorpyrifos Ethyl 0.048 U ug/L Chlorpyrifos Methyl 0.096 U ug/L Diazinon 0.048 U ug/L Ethion 0.048 U ug/L Ethoprop 0.096 U ug/L Fenamiphos 0.19 U ug/L Fonofos 0.096 U ug/L Hexazinone 0.096 UJ CCV ug/L Malathion 0.14 U ug/L Metalaxyl 0.24 UJ CCV ug/L Metolachlor 0.48 UJ CCV ug/L Metribuzin 0.096 UJ CCV ug/L Mevinphos 0.19 U ug/L Naled 0.77 U ug/L Norflurazon 0.14 UJ CCV ug/L Parathion Ethyl 0.14 U ug/L Parathion Methyl 0.096 U ug/L Phorate 0.048 U ug/L Prometon 0.19 U ug/L Prometryn 0.14 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 59 of 93 Field ID: 3 Z-13678 82nd St. N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Simazine 0.048 UJ CCV ug/L 1206768 EPA 6010C Strontium 466 ug/L Titanium 0.50 U ug/L EPA 6020A Aluminum 5.0 U ug/L Arsenic 0.25 U ug/L Barium 10.2 ug/L Cadmium 0.030 U ug/L Chromium 0.52 I ug/L Copper 0.56 ug/L Lead 0.20 I ug/L Selenium 0.20 U ug/L Silver 0.025 U ug/L EPA 7470A Mercury 0.12 U MS ug/L 1206786 EPA 353.2 Rev. 2.0 NO2NO3-N 0.007 I mg N/L Ref. Method and Comment: EPA 8260C QC failure(s) observed. EPA 8270D QC failure(s) observed. DEP SOP: GC-011-5 (based on EPA Methods 608, 617, 1656) Insufficient sample to perform MS duplicate due to loss of sample in sample preparation. QC failure(s) observed. DEP SOP: GC-012-3 (based on EPA 614, 619, 622, 633 and 507) Insufficient sample to perform MS duplicate due to loss of sample in sample preparation. QC failure(s) observed. Sample Location: ACREAGE Collection Date/Time: 08/05/2009 09:55 AM Field ID: 3 Z-13756 73rd St N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 1206591 EPA 900.0 Alpha, Total 2.2 pCi/L E83033 Alpha-Counting Error 1.3 pCi/L 1206609 EPA 522 1,4-Dioxane** 0.20 U ug/L E31640 1206627 EPA 8260C Benzene 0.20 U ug/L Bromodichloromethane 0.20 U ug/L Bromoform 0.50 UJ LCS ug/L Bromomethane 0.50 UJ CCV,MS ug/L 2-Butanone 10 U ug/L Carbon tetrachloride 0.20 U ug/L Chlorobenzene 0.20 U ug/L Chloroethane 0.50 U MS ug/L Chloroform 0.20 U ug/L Chloromethane 0.50 U MS ug/L Dibromochloromethane 0.20 U ug/L 1,2-Dichlorobenzene 0.50 U ug/L 1,3-Dichlorobenzene 0.50 U ug/L 1,4-Dichlorobenzene 0.50 U ug/L 1,1-Dichloroethane 0.20 U ug/L 1,2-Dichloroethane 0.21 I ug/L 1,1-Dichloroethene 0.50 U ug/L cis-1,2-Dichloroethene 0.50 U ug/L trans-1,2-Dichloroethene 0.50 U ug/L 1,2-Dichloropropane 0.50 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 60 of 93 Field ID: 3 Z-13756 73rd St N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # cis-1,3-Dichloropropene 0.50 U MS ug/L trans-1,3-Dichloropropene 0.20 UJ CCV,LCS, ug/L MS Ethylbenzene 0.50 U ug/L Methylene chloride 0.50 U ug/L 1,1,2,2-Tetrachloroethane 0.50 UJ CCV ug/L Tetrachloroethene 0.50 U ug/L Toluene 0.50 U ug/L 1,1,1-Trichloroethane 0.20 U ug/L 1,1,2-Trichloroethane 0.22 I ug/L Trichloroethene 0.20 UJ CCV ug/L Trichlorofluoromethane 0.50 U ug/L Vinyl chloride 0.50 U ug/L Methyl-t-butyl ether 0.50 U ug/L o-Xylene 0.20 U ug/L m,p-Xylene 0.50 U ug/L 1206645 DEP SOP: LC-001-2 2,4-D 0.20 U ug/L E31780 2,4,5-T 0.20 U ug/L Acifluorfen 0.20 U ug/L Silvex 0.20 U ug/L 1206667 EPA 8270D Acenaphthene 0.98 U ug/L Acenaphthylene 0.98 U ug/L Acetophenone 0.98 U ug/L 2-Acetylaminofluorene 0.98 U ug/L 4-Aminobiphenyl 3.9 U MS ug/L Aniline 0.98 U ug/L Anthracene 0.98 U ug/L Azobenzene/1,2-Diphenylhydrazine 0.98 U ug/L Benzidine 98 U ug/L Benzo(a)anthracene 0.98 U ug/L Benzo(a)pyrene 0.98 U ug/L Benzo(b)fluoranthene 0.98 U ug/L Benzo(k)fluoranthene 0.98 U ug/L Benzo(g,h,i)perylene 0.98 U ug/L Benzyl alcohol 0.98 U ug/L Bis(2-chloroethoxy)methane 0.98 U ug/L Bis(2-chloroethyl)ether 0.98 U ug/L Bis(2-chloroisopropyl)ether 2.9 U ug/L Bis(2-ethylhexyl)phthalate 15 U ug/L Butyl benzyl phthalate 4.9 U ug/L 4-Bromophenyl phenyl ether 0.98 U ug/L 4-Chloroaniline 0.98 U ug/L 2-Chloronaphthalene 0.98 U ug/L 4-Chlorophenyl phenyl ether 2.0 U ug/L Chrysene 0.98 U ug/L m,p-Cresols 2.0 U ug/L o-Cresol 2.0 U ug/L Di-n-butyl phthalate 4.9 U ug/L Di-n-octyl phthalate 0.98 UJ CCV ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 61 of 93 Field ID: 3 Z-13756 73rd St N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Dibenzo(a,h)anthracene Dibenzofuran 3,3'-Dichlorobenzidine Diethyl phthalate Dimethyl phthalate Dimethylaminoazobenzene 7,12-Dimethylbenz(a)anthracene 3,3'-Dimethylbenzidine 1,3-Dinitrobenzene 2,4-Dinitrotoluene 2,6-Dinitrotoluene Dinoseb** Ethyl methanesulfonate Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Hexachloropropene Indeno(1,2,3-cd)pyrene Isophorone Isosafrole Methapyrilene 3-Methylcholanthrene Methyl methanesulfonate 2-Methylnaphthalene Naphthalene 1-Naphthylamine 2-Naphthylamine 1,4-Naphthoquinone 2-Nitroaniline 3-Nitroaniline 4-Nitroaniline Nitrobenzene Nitroquinoline-1-oxide 5-Nitro-o-toluidine N-Nitrosodiethylamine N-Nitrosodimethylamine N-Nitrosodi-n-propylamine N-Nitrosomethylethylamine N-Nitrosomorpholine N-Nitrosopiperidine N-Nitrosopyrrolidine Pentachlorobenzene Pentachloroethane** Pentachloronitrobenzene Phenacetin Phenanthrene 0.98 0.98 39 0.98 9.8 0.98 0.98 20 2.0 0.98 0.98 3.9 0.98 0.98 0.98 0.98 2.9 2.9 2.9 2.0 0.98 0.98 0.98 3.9 0.98 0.98 0.98 0.98 9.8 9.8 20 0.98 0.98 0.98 2.0 20 0.98 0.98 2.0 2.0 2.0 0.98 0.98 2.0 0.98 49 0.98 3.9 0.98 U U U U U U U U U U U U U U U U U U U U U U U UJ U UJ U U U U UJ U U UJ U U U U U U U U U U U U U U U LCS CCV MS MS CCV,MS CCV MS,RPD ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 62 of 93 Field ID: 3 Z-13756 73rd St N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 2-Picoline 0.98 U ug/L Pyrene 0.98 U ug/L Pyridine 3.9 U ug/L Safrole 0.98 U ug/L 1,2,4,5-Tetrachlorobenzene 0.98 U ug/L o-Toluidine 0.98 U ug/L 1,2,4-Trichlorobenzene 0.98 U ug/L 1,3,5-Trinitrobenzene 3.9 U ug/L 4-Chloro-3-methylphenol 0.98 U ug/L 2-Chlorophenol 0.98 U ug/L 2,4-Dichlorophenol 0.98 U ug/L 2,6-Dichlorophenol 0.98 U ug/L 2,4-Dimethylphenol 9.8 U ug/L 2,4-Dinitrophenol 15 U ug/L 2-Methyl-4,6-dinitrophenol 2.9 U ug/L 2-Nitrophenol 0.98 U ug/L 4-Nitrophenol 15 U ug/L Pentachlorophenol 2.9 U ug/L Phenol 0.98 U ug/L 2,3,4,6-Tetrachlorophenol 2.0 U ug/L 2,4,5-Trichlorophenol 0.98 U ug/L 2,4,6-Trichlorophenol 0.98 U ug/L N-Nitrosodiphenylamine/ Diphenylamine 2.9 U ug/L 1206685 FL-PRO TRPH 0.25 U mg/L 1206713 EPA 504 1,2-Dibromoethane 0.010 U ug/L 1206731 DEP SOP: GC-011-5 (based Aldrin 0.0095 U ug/L on EPA Methods 608, 617, 1656) Alpha-BHC 0.0095 U ug/L Beta-BHC 0.0095 UJ CCV ug/L Delta-BHC 0.0095 UJ CCV ug/L Gamma-BHC 0.0095 U ug/L Chlordane 0.19 U ug/L DDD-p,p' 0.019 UJ CCV ug/L DDE-p,p' 0.019 UJ CCV ug/L DDT-p,p' 0.029 U ug/L Dieldrin 0.019 U ug/L Endosulfan I 0.019 U ug/L Endosulfan II 0.019 U ug/L Endosulfan Sulfate 0.019 U ug/L Endrin 0.048 U ug/L Endrin Aldehyde 0.019 U ug/L Heptachlor 0.0095 U ug/L Heptachlor Epoxide 0.019 U ug/L Methoxychlor 0.048 UJ CCV ug/L Toxaphene 0.71 U ug/L PCB-1016 0.19 U ug/L PCB-1221 0.19 U ug/L PCB-1232 0.19 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 63 of 93 Field ID: 3 Z-13756 73rd St N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # PCB-1242 0.29 U ug/L PCB-1248 0.19 U ug/L PCB-1254 0.29 U ug/L PCB-1260 0.19 U ug/L DEP SOP: GC-012-3 (based Alachlor 0.57 UJ CCV ug/L on EPA 614, 619, 622, 633 and 507) Ametryn 0.048 U ug/L Atrazine 0.048 U ug/L Azinphos Methyl 0.19 UJ CCV ug/L Bromacil 0.19 U ug/L Butylate 0.19 UJ CCV ug/L Chlorpyrifos Ethyl 0.048 U ug/L Chlorpyrifos Methyl 0.095 U ug/L Diazinon 0.048 U ug/L Ethion 0.048 U ug/L Ethoprop 0.095 U ug/L Fenamiphos 0.19 U ug/L Fonofos 0.095 U ug/L Hexazinone 0.095 UJ CCV ug/L Malathion 0.14 U ug/L Metalaxyl 0.24 UJ CCV ug/L Metolachlor 0.48 UJ CCV ug/L Metribuzin 0.095 UJ CCV ug/L Mevinphos 0.19 U ug/L Naled 0.76 U ug/L Norflurazon 0.14 UJ CCV ug/L Parathion Ethyl 0.14 U ug/L Parathion Methyl 0.095 U ug/L Phorate 0.048 U ug/L Prometon 0.19 U ug/L Prometryn 0.14 U ug/L Simazine 0.048 UJ CCV ug/L 1206767 EPA 6010C Strontium 675 ug/L Titanium 0.50 U ug/L EPA 6020A Aluminum 5.6 I ug/L Arsenic 0.25 U ug/L Barium 14.9 ug/L Cadmium 0.030 U ug/L Chromium 0.62 I ug/L Copper 5.63 ug/L Lead 0.29 I ug/L Selenium 0.20 U ug/L Silver 0.025 U ug/L EPA 7470A Mercury 0.12 U MS ug/L 1206785 EPA 353.2 Rev. 2.0 NO2NO3-N 0.005 I mg N/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 64 of 93 Field ID: 3 Z-13756 73rd St N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Ref. Method and Comment: EPA 8260C QC failure(s) observed. EPA 8270D QC failure(s) observed. DEP SOP: GC-011-5 (based on EPA Methods 608, 617, 1656) Insufficient sample to perform MS duplicate due to loss of sample in sample preparation. QC failure(s) observed. DEP SOP: GC-012-3 (based on EPA 614, 619, 622, 633 and 507) Insufficient sample to perform MS duplicate due to loss of sample in sample preparation. QC failure(s) observed. Sample Location: ACREAGE Collection Date/Time: 08/05/2009 09:10 AM Field ID: 3 Z-13920 63rd Ln N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 1206390 EPA 903.1 and Ra-05 Radium 226 2.4 pCi/L E83033 Radium 226-Counting Error 0.4 pCi/L Radium 228 1.0 U pCi/L Radium 228-Counting Error 0.6 pCi/L 1206396 EPA 900.0 Alpha, Total 6.2 pCi/L Alpha-Counting Error 1.8 pCi/L 1206602 EPA 522 1,4-Dioxane** 0.20 U ug/L E31640 1206620 EPA 8260C Benzene 0.20 U ug/L Bromodichloromethane 0.20 U ug/L Bromoform 0.50 UJ LCS ug/L Bromomethane 0.50 UJ CCV,MS ug/L 2-Butanone 10 U ug/L Carbon tetrachloride 0.20 U ug/L Chlorobenzene 0.20 U ug/L Chloroethane 0.50 U MS ug/L Chloroform 0.20 U ug/L Chloromethane 0.50 U MS ug/L Dibromochloromethane 0.20 U ug/L 1,2-Dichlorobenzene 0.50 U ug/L 1,3-Dichlorobenzene 0.50 U ug/L 1,4-Dichlorobenzene 0.50 U ug/L 1,1-Dichloroethane 0.20 U ug/L 1,2-Dichloroethane 0.20 U ug/L 1,1-Dichloroethene 0.50 U ug/L cis-1,2-Dichloroethene 0.50 U ug/L trans-1,2-Dichloroethene 0.50 U ug/L 1,2-Dichloropropane 0.50 U ug/L cis-1,3-Dichloropropene 0.50 U MS ug/L trans-1,3-Dichloropropene 0.20 UJ LCS,MS ug/L Ethylbenzene 0.50 U ug/L Methylene chloride 0.50 U ug/L 1,1,2,2-Tetrachloroethane 0.50 UJ CCV ug/L Tetrachloroethene 0.50 U ug/L Toluene 0.50 U ug/L 1,1,1-Trichloroethane 0.20 U ug/L 1,1,2-Trichloroethane 0.20 U ug/L Trichloroethene 0.20 UJ CCV ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 65 of 93 Field ID: 3 Z-13920 63rd Ln N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Trichlorofluoromethane 0.50 U ug/L Vinyl chloride 0.50 U ug/L Methyl-t-butyl ether 0.50 U ug/L o-Xylene 0.20 U ug/L m,p-Xylene 0.50 U ug/L 1206638 DEP SOP: LC-001-2 2,4-D 0.21 U ug/L E31780 2,4,5-T 0.21 U ug/L Acifluorfen 0.21 U ug/L Silvex 0.21 U ug/L 1206660 EPA 8270D Acenaphthene 1.0 U ug/L Acenaphthylene 1.0 U ug/L Acetophenone 1.0 U ug/L 2-Acetylaminofluorene 1.0 U ug/L 4-Aminobiphenyl 4.0 U ug/L Aniline 1.0 U ug/L Anthracene 1.0 U ug/L Azobenzene/1,2-Diphenylhydrazine 1.0 U ug/L Benzidine 100 U ug/L Benzo(a)anthracene 1.0 U ug/L Benzo(a)pyrene 1.0 U ug/L Benzo(b)fluoranthene 1.0 U ug/L Benzo(k)fluoranthene 1.0 U ug/L Benzo(g,h,i)perylene 1.0 U ug/L Benzyl alcohol 1.0 U ug/L Bis(2-chloroethoxy)methane 1.0 U ug/L Bis(2-chloroethyl)ether 1.0 U ug/L Bis(2-chloroisopropyl)ether 3.0 U ug/L Bis(2-ethylhexyl)phthalate 15 U ug/L Butyl benzyl phthalate 5.0 U ug/L 4-Bromophenyl phenyl ether 1.0 U ug/L 4-Chloroaniline 1.0 U ug/L 2-Chloronaphthalene 1.0 U ug/L 4-Chlorophenyl phenyl ether 2.0 U ug/L Chrysene 1.0 U ug/L m,p-Cresols 2.0 U ug/L o-Cresol 2.0 U ug/L Di-n-butyl phthalate 5.0 U ug/L Di-n-octyl phthalate 1.0 U ug/L Dibenzo(a,h)anthracene 1.0 U ug/L Dibenzofuran 1.0 U ug/L 3,3'-Dichlorobenzidine 40 U ug/L Diethyl phthalate 1.0 U ug/L Dimethyl phthalate 10 U ug/L Dimethylaminoazobenzene 1.0 UJ CCV ug/L 7,12-Dimethylbenz(a)anthracene 1.0 U ug/L 3,3'-Dimethylbenzidine 20 U ug/L 1,3-Dinitrobenzene 2.0 U ug/L 2,4-Dinitrotoluene 1.0 U ug/L 2,6-Dinitrotoluene 1.0 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 66 of 93 Field ID: 3 Z-13920 63rd Ln N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Dinoseb** 4.0 U ug/L Ethyl methanesulfonate 1.0 U ug/L Fluoranthene 1.0 U ug/L Fluorene 1.0 U ug/L Hexachlorobenzene 1.0 U ug/L Hexachlorobutadiene 3.0 U ug/L Hexachlorocyclopentadiene 3.0 U ug/L Hexachloroethane 3.0 U ug/L Hexachloropropene 2.0 U ug/L Indeno(1,2,3-cd)pyrene 1.0 U ug/L Isophorone 1.0 U ug/L Isosafrole 1.0 U ug/L Methapyrilene 4.0 UJ CCV,LCS ug/L 3-Methylcholanthrene 1.0 U ug/L Methyl methanesulfonate 1.0 UJ CCV ug/L 2-Methylnaphthalene 1.0 U ug/L Naphthalene 1.0 U ug/L 1-Naphthylamine 10 U ug/L 2-Naphthylamine 1,4-Naphthoquinone 10 20 UJ UJ LCS,MS,RP D CCV,MS ug/L ug/L 2-Nitroaniline 1.0 U ug/L 3-Nitroaniline 1.0 U ug/L 4-Nitroaniline 1.0 UJ CCV ug/L Nitrobenzene 2.0 U ug/L Nitroquinoline-1-oxide 20 UJ LCS,MS ug/L 5-Nitro-o-toluidine 1.0 U ug/L N-Nitrosodiethylamine 1.0 U ug/L N-Nitrosodimethylamine 2.0 U ug/L N-Nitrosodi-n-propylamine 2.0 U ug/L N-Nitrosomethylethylamine 2.0 U ug/L N-Nitrosomorpholine 1.0 U ug/L N-Nitrosopiperidine 1.0 U ug/L N-Nitrosopyrrolidine 2.0 U ug/L Pentachlorobenzene 1.0 U ug/L Pentachloroethane** 50 U ug/L Pentachloronitrobenzene 1.0 U ug/L Phenacetin 4.0 U ug/L Phenanthrene 1.0 U ug/L 2-Picoline 1.0 U ug/L Pyrene 1.0 U ug/L Pyridine 4.0 U ug/L Safrole 1.0 U ug/L 1,2,4,5-Tetrachlorobenzene 1.0 U ug/L o-Toluidine 1.0 U ug/L 1,2,4-Trichlorobenzene 1.0 U ug/L 1,3,5-Trinitrobenzene 4.0 U ug/L 4-Chloro-3-methylphenol 1.0 U ug/L 2-Chlorophenol 1.0 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 67 of 93 Field ID: 3 Z-13920 63rd Ln N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 2,4-Dichlorophenol 1.0 U ug/L 2,6-Dichlorophenol 1.0 U ug/L 2,4-Dimethylphenol 10 U ug/L 2,4-Dinitrophenol 15 U ug/L 2-Methyl-4,6-dinitrophenol 3.0 U ug/L 2-Nitrophenol 1.0 U ug/L 4-Nitrophenol 15 U ug/L Pentachlorophenol 3.0 U ug/L Phenol 1.0 U ug/L 2,3,4,6-Tetrachlorophenol 2.0 U ug/L 2,4,5-Trichlorophenol 1.0 U ug/L 2,4,6-Trichlorophenol 1.0 UJ CCV ug/L N-Nitrosodiphenylamine/ Diphenylamine 3.0 U ug/L 1206678 FL-PRO TRPH 0.26 U mg/L 1206706 EPA 504 1,2-Dibromoethane 0.010 U ug/L 1206724 DEP SOP: GC-011-5 (based Aldrin 0.0096 U ug/L on EPA Methods 608, 617, 1656) Alpha-BHC 0.0096 U ug/L Beta-BHC 0.0096 U ug/L Delta-BHC 0.0096 U ug/L Gamma-BHC 0.0096 U ug/L Chlordane 0.19 U ug/L DDD-p,p' 0.019 U ug/L DDE-p,p' 0.019 U ug/L DDT-p,p' 0.029 U ug/L Dieldrin 0.019 U ug/L Endosulfan I 0.019 U ug/L Endosulfan II 0.019 U ug/L Endosulfan Sulfate 0.019 U ug/L Endrin 0.048 U ug/L Endrin Aldehyde 0.019 U ug/L Heptachlor 0.0096 U ug/L Heptachlor Epoxide 0.019 U ug/L Methoxychlor 0.048 U ug/L Toxaphene 0.72 U ug/L PCB-1016 0.19 U ug/L PCB-1221 0.19 U ug/L PCB-1232 0.19 U ug/L PCB-1242 0.29 U ug/L PCB-1248 0.19 U ug/L PCB-1254 0.29 U ug/L PCB-1260 0.19 U ug/L DEP SOP: GC-012-3 (based Alachlor 0.58 UJ CCV ug/L on EPA 614, 619, 622, 633 and 507) Ametryn 0.048 U ug/L Atrazine 0.048 U ug/L Azinphos Methyl 0.19 UJ CCV ug/L Bromacil 0.19 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 68 of 93 Field ID: 3 Z-13920 63rd Ln N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Butylate 0.19 UJ CCV ug/L Chlorpyrifos Ethyl 0.048 U ug/L Chlorpyrifos Methyl 0.096 U ug/L Diazinon 0.048 U ug/L Ethion 0.048 U ug/L Ethoprop 0.096 U ug/L Fenamiphos 0.19 U ug/L Fonofos 0.096 U ug/L Hexazinone 0.096 UJ CCV ug/L Malathion 0.14 U ug/L Metalaxyl 0.24 UJ CCV ug/L Metolachlor 0.48 UJ CCV ug/L Metribuzin 0.096 U ug/L Mevinphos 0.19 U ug/L Naled 0.77 U ug/L Norflurazon 0.14 UJ CCV ug/L Parathion Ethyl 0.14 U ug/L Parathion Methyl 0.096 U ug/L Phorate 0.048 U ug/L Prometon 0.19 U ug/L Prometryn 0.14 U ug/L Simazine 0.048 U ug/L 1206760 EPA 6010C Strontium 972 ug/L Titanium 0.50 U ug/L EPA 6020A Aluminum 6.4 I ug/L Arsenic 0.25 U ug/L Barium 33.1 ug/L Cadmium 0.030 U ug/L Chromium 0.48 I ug/L Copper 4.61 ug/L Lead 0.20 U ug/L Selenium 0.20 U ug/L Silver 0.025 U ug/L EPA 7470A Mercury 0.12 U ug/L 1206778 EPA 353.2 Rev. 2.0 NO2NO3-N 0.007 I mg N/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 69 of 93 Field ID: 3 Z-13920 63rd Ln N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Ref. Method and Comment: EPA 8260C QC failure(s) observed. EPA 8270D QC failure(s) observed. FL-PRO Insufficient sample to perform matrix spikes. DEP SOP: GC-011-5 (based on EPA Methods 608, 617, 1656) Insufficient sample to perform MS duplicate due to loss of sample in sample preparation. DEP SOP: GC-012-3 (based on EPA 614, 619, 622, 633 and 507) Insufficient sample to perform MS duplicate due to loss of sample in sample preparation. QC failure(s) observed. Sample Location: ACREAGE Collection Date/Time: 08/05/2009 10:26 AM Field ID: 3 Z-7655 WOODMUIR DR Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 1206590 EPA 900.0 Alpha, Total 1.5 U pCi/L E83033 Alpha-Counting Error 1.0 pCi/L 1206608 EPA 522 1,4-Dioxane** 0.20 U ug/L E31640 1206626 EPA 8260C Benzene 0.20 U ug/L Bromodichloromethane 0.20 U ug/L Bromoform 0.50 UJ LCS ug/L Bromomethane 0.50 UJ CCV,MS ug/L 2-Butanone 10 U ug/L Carbon tetrachloride 0.20 U ug/L Chlorobenzene 0.20 U ug/L Chloroethane 0.50 U MS ug/L Chloroform 0.20 U ug/L Chloromethane 0.50 U MS ug/L Dibromochloromethane 0.20 U ug/L 1,2-Dichlorobenzene 0.50 U ug/L 1,3-Dichlorobenzene 0.50 U ug/L 1,4-Dichlorobenzene 0.50 U ug/L 1,1-Dichloroethane 0.20 U ug/L 1,2-Dichloroethane 0.20 U ug/L 1,1-Dichloroethene 0.50 U ug/L cis-1,2-Dichloroethene 0.50 U ug/L trans-1,2-Dichloroethene 0.50 U ug/L 1,2-Dichloropropane 0.50 U ug/L cis-1,3-Dichloropropene 0.50 U MS ug/L trans-1,3-Dichloropropene 0.20 UJ LCS,MS ug/L Ethylbenzene 0.50 U ug/L Methylene chloride 0.50 U ug/L 1,1,2,2-Tetrachloroethane 0.50 UJ CCV ug/L Tetrachloroethene 0.50 U ug/L Toluene 0.50 U ug/L 1,1,1-Trichloroethane 0.20 U ug/L 1,1,2-Trichloroethane 0.20 U ug/L Trichloroethene 0.20 UJ CCV ug/L Trichlorofluoromethane 0.50 U ug/L Vinyl chloride 0.50 U ug/L Methyl-t-butyl ether 0.50 U ug/L o-Xylene 0.20 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 70 of 93 Field ID: 3 Z-7655 WOODMUIR DR Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # m,p-Xylene 0.50 U ug/L 1206644 DEP SOP: LC-001-2 2,4-D 0.21 U ug/L E31780 2,4,5-T 0.21 U ug/L Acifluorfen 0.21 U ug/L Silvex 0.21 U ug/L 1206666 EPA 8270D Acenaphthene 0.99 U ug/L Acenaphthylene 0.99 U ug/L Acetophenone 0.99 U ug/L 2-Acetylaminofluorene 0.99 U ug/L 4-Aminobiphenyl 4.0 U ug/L Aniline 0.99 U ug/L Anthracene 0.99 U ug/L Azobenzene/1,2-Diphenylhydrazine 0.99 U ug/L Benzidine 99 U ug/L Benzo(a)anthracene 0.99 U ug/L Benzo(a)pyrene 0.99 U ug/L Benzo(b)fluoranthene 0.99 U ug/L Benzo(k)fluoranthene 0.99 U ug/L Benzo(g,h,i)perylene 0.99 U ug/L Benzyl alcohol 0.99 U ug/L Bis(2-chloroethoxy)methane 0.99 U ug/L Bis(2-chloroethyl)ether 0.99 U ug/L Bis(2-chloroisopropyl)ether 3.0 U ug/L Bis(2-ethylhexyl)phthalate 15 U ug/L Butyl benzyl phthalate 4.9 U ug/L 4-Bromophenyl phenyl ether 0.99 U ug/L 4-Chloroaniline 0.99 U ug/L 2-Chloronaphthalene 0.99 U ug/L 4-Chlorophenyl phenyl ether 2.0 U ug/L Chrysene 0.99 U ug/L m,p-Cresols 2.0 U ug/L o-Cresol 2.0 U ug/L Di-n-butyl phthalate 4.9 U ug/L Di-n-octyl phthalate 0.99 U ug/L Dibenzo(a,h)anthracene 0.99 U ug/L Dibenzofuran 0.99 U ug/L 3,3'-Dichlorobenzidine 40 U ug/L Diethyl phthalate 0.99 U ug/L Dimethyl phthalate 9.9 U ug/L Dimethylaminoazobenzene 0.99 UJ CCV ug/L 7,12-Dimethylbenz(a)anthracene 0.99 U ug/L 3,3'-Dimethylbenzidine 20 U ug/L 1,3-Dinitrobenzene 2.0 U ug/L 2,4-Dinitrotoluene 0.99 U ug/L 2,6-Dinitrotoluene 0.99 U ug/L Dinoseb** 4.0 U ug/L Ethyl methanesulfonate 0.99 U ug/L Fluoranthene 0.99 U ug/L Fluorene 0.99 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 71 of 93 Field ID: 3 Z-7655 WOODMUIR DR Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Hexachlorobenzene 0.99 U ug/L Hexachlorobutadiene 3.0 U ug/L Hexachlorocyclopentadiene 3.0 U ug/L Hexachloroethane 3.0 U ug/L Hexachloropropene 2.0 U ug/L Indeno(1,2,3-cd)pyrene 0.99 U ug/L Isophorone 0.99 U ug/L Isosafrole 0.99 U ug/L Methapyrilene 4.0 UJ CCV,LCS ug/L 3-Methylcholanthrene 0.99 U ug/L Methyl methanesulfonate 0.99 UJ CCV ug/L 2-Methylnaphthalene 0.99 U ug/L Naphthalene 0.99 U ug/L 1-Naphthylamine 9.9 U ug/L 2-Naphthylamine 9.9 UJ LCS,MS,RP ug/L D 1,4-Naphthoquinone 20 UJ CCV,MS ug/L 2-Nitroaniline 0.99 U ug/L 3-Nitroaniline 0.99 U ug/L 4-Nitroaniline 0.99 UJ CCV ug/L Nitrobenzene 2.0 U ug/L Nitroquinoline-1-oxide 20 UJ LCS,MS ug/L 5-Nitro-o-toluidine 0.99 U ug/L N-Nitrosodiethylamine 0.99 U ug/L N-Nitrosodimethylamine 2.0 U ug/L N-Nitrosodi-n-propylamine 2.0 U ug/L N-Nitrosomethylethylamine 2.0 U ug/L N-Nitrosomorpholine 0.99 U ug/L N-Nitrosopiperidine 0.99 U ug/L N-Nitrosopyrrolidine 2.0 U ug/L Pentachlorobenzene 0.99 U ug/L Pentachloroethane** 49 U ug/L Pentachloronitrobenzene 0.99 U ug/L Phenacetin 4.0 U ug/L Phenanthrene 0.99 U ug/L 2-Picoline 0.99 U ug/L Pyrene 0.99 U ug/L Pyridine 4.0 U ug/L Safrole 0.99 U ug/L 1,2,4,5-Tetrachlorobenzene 0.99 U ug/L o-Toluidine 0.99 U ug/L 1,2,4-Trichlorobenzene 0.99 U ug/L 1,3,5-Trinitrobenzene 4.0 U ug/L 4-Chloro-3-methylphenol 0.99 U ug/L 2-Chlorophenol 0.99 U ug/L 2,4-Dichlorophenol 0.99 U ug/L 2,6-Dichlorophenol 0.99 U ug/L 2,4-Dimethylphenol 9.9 U ug/L 2,4-Dinitrophenol 15 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 72 of 93 Field ID: 3 Z-7655 WOODMUIR DR Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 2-Methyl-4,6-dinitrophenol 3.0 U ug/L 2-Nitrophenol 0.99 U ug/L 4-Nitrophenol 15 U ug/L Pentachlorophenol 3.0 U ug/L Phenol 0.99 U ug/L 2,3,4,6-Tetrachlorophenol 2.0 U ug/L 2,4,5-Trichlorophenol 0.99 U ug/L 2,4,6-Trichlorophenol 0.99 UJ CCV ug/L N-Nitrosodiphenylamine/ Diphenylamine 3.0 U ug/L 1206684 FL-PRO TRPH 0.24 U mg/L 1206712 EPA 504 1,2-Dibromoethane 0.010 U ug/L 1206730 DEP SOP: GC-011-5 (based Aldrin 0.0099 U ug/L on EPA Methods 608, 617, 1656) Alpha-BHC 0.0099 U ug/L Beta-BHC 0.0099 UJ CCV ug/L Delta-BHC 0.0099 UJ CCV ug/L Gamma-BHC 0.0099 U ug/L Chlordane 0.20 U ug/L DDD-p,p' 0.020 UJ CCV ug/L DDE-p,p' 0.020 UJ CCV ug/L DDT-p,p' 0.030 U ug/L Dieldrin 0.020 U ug/L Endosulfan I 0.020 U ug/L Endosulfan II 0.020 U ug/L Endosulfan Sulfate 0.020 U ug/L Endrin 0.050 U ug/L Endrin Aldehyde 0.020 U ug/L Heptachlor 0.0099 U ug/L Heptachlor Epoxide 0.020 U ug/L Methoxychlor 0.050 UJ CCV ug/L Toxaphene 0.74 U ug/L PCB-1016 0.20 U ug/L PCB-1221 0.20 U ug/L PCB-1232 0.20 U ug/L PCB-1242 0.30 U ug/L PCB-1248 0.20 U ug/L PCB-1254 0.30 U ug/L PCB-1260 0.20 U ug/L DEP SOP: GC-012-3 (based Alachlor 0.59 UJ CCV ug/L on EPA 614, 619, 622, 633 and 507) Ametryn 0.050 U ug/L Atrazine 0.050 U ug/L Azinphos Methyl 0.20 UJ CCV ug/L Bromacil 0.20 U ug/L Butylate 0.20 UJ CCV ug/L Chlorpyrifos Ethyl 0.050 U ug/L Chlorpyrifos Methyl 0.099 U ug/L Diazinon 0.050 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 73 of 93 Field ID: 3 Z-7655 WOODMUIR DR Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Ethion 0.050 U ug/L Ethoprop 0.099 U ug/L Fenamiphos 0.20 U ug/L Fonofos 0.099 U ug/L Hexazinone 0.099 UJ CCV ug/L Malathion 0.15 U ug/L Metalaxyl 0.25 UJ CCV ug/L Metolachlor 0.50 UJ CCV ug/L Metribuzin 0.099 UJ CCV ug/L Mevinphos 0.20 U ug/L Naled 0.79 U ug/L Norflurazon 0.15 UJ CCV ug/L Parathion Ethyl 0.15 U ug/L Parathion Methyl 0.099 U ug/L Phorate 0.050 U ug/L Prometon 0.20 U ug/L Prometryn 0.15 U ug/L Simazine 0.050 UJ CCV ug/L 1206766 EPA 6010C Strontium 648 A ug/L Titanium 0.50 U ug/L EPA 6020A Aluminum 5.0 U ug/L Arsenic 0.25 U ug/L Barium 12.6 A ug/L Cadmium 0.030 U ug/L Chromium 0.98 I ug/L Copper 2.71 A ug/L Lead 0.38 I ug/L Selenium 0.20 U ug/L Silver 0.025 U ug/L EPA 7470A Mercury 0.12 U MS ug/L 1206784 EPA 353.2 Rev. 2.0 NO2NO3-N 0.004 U mg N/L Ref. Method and Comment: EPA 8260C QC failure(s) observed. EPA 8270D QC failure(s) observed. DEP SOP: GC-011-5 (based on EPA Methods 608, 617, 1656) Insufficient sample to perform MS duplicate due to loss of sample in sample preparation. QC failure(s) observed. DEP SOP: GC-012-3 (based on EPA 614, 619, 622, 633 and 507) Insufficient sample to perform MS duplicate due to loss of sample in sample preparation. QC failure(s) observed. Sample Location: ACREAGE Collection Date/Time: 08/05/2009 12:15 PM Field ID: 4 Z-11060 56th PL N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 1206393 EPA 903.1 and Ra-05 Radium 226 0.6 pCi/L E83033 Radium 226-Counting Error 0.2 pCi/L Radium 228 0.9 U pCi/L Radium 228-Counting Error 0.6 pCi/L 1206399 EPA 900.0 Alpha, Total 1.8 U pCi/L Alpha-Counting Error 1.2 pCi/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 74 of 93 Field ID: 4 Z-11060 56th PL N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 1206613 EPA 522 1,4-Dioxane** 0.20 U ug/L E31640 1206631 EPA 8260C Benzene 0.20 U ug/L Bromodichloromethane 0.20 U ug/L Bromoform 0.50 UJ LCS ug/L Bromomethane 0.50 UJ CCV,MS ug/L 2-Butanone 10 U ug/L Carbon tetrachloride 0.20 U ug/L Chlorobenzene 0.20 U ug/L Chloroethane 0.50 U MS ug/L Chloroform 0.20 U ug/L Chloromethane 0.50 U MS ug/L Dibromochloromethane 0.20 U ug/L 1,2-Dichlorobenzene 0.50 U ug/L 1,3-Dichlorobenzene 0.50 U ug/L 1,4-Dichlorobenzene 0.50 U ug/L 1,1-Dichloroethane 0.20 U ug/L 1,2-Dichloroethane 0.20 U ug/L 1,1-Dichloroethene 0.50 U ug/L cis-1,2-Dichloroethene 0.50 U ug/L trans-1,2-Dichloroethene 0.50 U ug/L 1,2-Dichloropropane 0.50 U ug/L cis-1,3-Dichloropropene 0.50 U MS ug/L trans-1,3-Dichloropropene 0.20 UJ CCV,LCS, ug/L MS Ethylbenzene 0.50 U ug/L Methylene chloride 0.50 U ug/L 1,1,2,2-Tetrachloroethane 0.50 UJ CCV ug/L Tetrachloroethene 0.50 U ug/L Toluene 0.50 U ug/L 1,1,1-Trichloroethane 0.20 U ug/L 1,1,2-Trichloroethane 0.20 U ug/L Trichloroethene 0.20 UJ CCV ug/L Trichlorofluoromethane 0.50 U ug/L Vinyl chloride 0.50 U ug/L Methyl-t-butyl ether 0.50 U ug/L o-Xylene 0.20 U ug/L m,p-Xylene 0.50 U ug/L 1206649 DEP SOP: LC-001-2 2,4-D 0.20 U ug/L E31780 2,4,5-T 0.20 U ug/L Acifluorfen 0.20 U ug/L Silvex 0.20 U ug/L 1206671 EPA 8270D Acenaphthene 0.98 U ug/L Acenaphthylene 0.98 U ug/L Acetophenone 0.98 U ug/L 2-Acetylaminofluorene 0.98 U ug/L 4-Aminobiphenyl 3.9 U ug/L Aniline 0.98 U ug/L Anthracene 0.98 U ug/L Azobenzene/1,2-Diphenylhydrazine 0.98 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 75 of 93 Field ID: 4 Z-11060 56th PL N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Benzidine Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(k)fluoranthene Benzo(g,h,i)perylene Benzyl alcohol Bis(2-chloroethoxy)methane Bis(2-chloroethyl)ether Bis(2-chloroisopropyl)ether Bis(2-ethylhexyl)phthalate Butyl benzyl phthalate 4-Bromophenyl phenyl ether 4-Chloroaniline 2-Chloronaphthalene 4-Chlorophenyl phenyl ether Chrysene m,p-Cresols o-Cresol Di-n-butyl phthalate Di-n-octyl phthalate Dibenzo(a,h)anthracene Dibenzofuran 3,3'-Dichlorobenzidine Diethyl phthalate Dimethyl phthalate Dimethylaminoazobenzene 7,12-Dimethylbenz(a)anthracene 3,3'-Dimethylbenzidine 1,3-Dinitrobenzene 2,4-Dinitrotoluene 2,6-Dinitrotoluene Dinoseb** Ethyl methanesulfonate Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Hexachloropropene Indeno(1,2,3-cd)pyrene Isophorone Isosafrole Methapyrilene 3-Methylcholanthrene Methyl methanesulfonate 2-Methylnaphthalene Naphthalene 98 0.98 0.98 0.98 0.98 0.98 0.98 0.98 0.98 3.0 15 4.9 0.98 0.98 0.98 2.0 0.98 2.0 2.0 4.9 0.98 0.98 0.98 39 0.98 9.8 0.98 0.98 20 2.0 0.98 0.98 3.9 0.98 0.98 0.98 0.98 3.0 3.0 3.0 2.0 0.98 0.98 0.98 3.9 0.98 0.98 0.98 0.98 U U U U U U U U U U U U U U U U U U U U UJ U U U U U U U U U U U U U U U U U U U U U U U UJ U UJ U U CCV LCS CCV ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 76 of 93 Field ID: 4 Z-11060 56th PL N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 1-Naphthylamine 9.8 U ug/L 2-Naphthylamine 9.8 U MS ug/L 1,4-Naphthoquinone 20 UJ CCV ug/L 2-Nitroaniline 0.98 U ug/L 3-Nitroaniline 0.98 U ug/L 4-Nitroaniline 0.98 UJ CCV ug/L Nitrobenzene 2.0 U ug/L Nitroquinoline-1-oxide 20 U ug/L 5-Nitro-o-toluidine 0.98 U ug/L N-Nitrosodiethylamine 0.98 U ug/L N-Nitrosodimethylamine 2.0 U ug/L N-Nitrosodi-n-propylamine 2.0 U ug/L N-Nitrosomethylethylamine 2.0 U ug/L N-Nitrosomorpholine 0.98 U ug/L N-Nitrosopiperidine 0.98 U ug/L N-Nitrosopyrrolidine 2.0 U ug/L Pentachlorobenzene 0.98 U ug/L Pentachloroethane** 49 U ug/L Pentachloronitrobenzene 0.98 U ug/L Phenacetin 3.9 U ug/L Phenanthrene 0.98 U ug/L 2-Picoline 0.98 U ug/L Pyrene 0.98 U ug/L Pyridine 3.9 U ug/L Safrole 0.98 U ug/L 1,2,4,5-Tetrachlorobenzene 0.98 U ug/L o-Toluidine 0.98 U ug/L 1,2,4-Trichlorobenzene 0.98 U ug/L 1,3,5-Trinitrobenzene 3.9 U ug/L 4-Chloro-3-methylphenol 0.98 U ug/L 2-Chlorophenol 0.98 U ug/L 2,4-Dichlorophenol 0.98 U ug/L 2,6-Dichlorophenol 0.98 U ug/L 2,4-Dimethylphenol 9.8 U ug/L 2,4-Dinitrophenol 15 U ug/L 2-Methyl-4,6-dinitrophenol 3.0 U ug/L 2-Nitrophenol 0.98 U ug/L 4-Nitrophenol 15 U ug/L Pentachlorophenol 3.0 U ug/L Phenol 0.98 U ug/L 2,3,4,6-Tetrachlorophenol 2.0 U ug/L 2,4,5-Trichlorophenol 0.98 U ug/L 2,4,6-Trichlorophenol 0.98 U ug/L N-Nitrosodiphenylamine/ Diphenylamine 3.0 U ug/L 1206689 FL-PRO TRPH 0.25 U mg/L 1206717 EPA 504 1,2-Dibromoethane 0.010 U ug/L 1206735 DEP SOP: GC-011-5 (based Aldrin 0.0099 U ug/L on EPA Methods 608, 617, 1656) SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 77 of 93 Field ID: 4 Z-11060 56th PL N Sample ID Ref. Method DEP SOP: GC-012-3 (based on EPA 614, 619, 622, 633 and 507) Matrix: W-GROUND Component Result Code QC Failures Units Cert # Alpha-BHC 0.0099 U MS ug/L Beta-BHC 0.0099 U ug/L Delta-BHC 0.0099 U ug/L Gamma-BHC 0.0099 U ug/L Chlordane 0.20 U ug/L DDD-p,p' 0.020 U ug/L DDE-p,p' 0.020 U ug/L DDT-p,p' 0.030 U ug/L Dieldrin 0.020 U ug/L Endosulfan I 0.020 U ug/L Endosulfan II 0.020 U ug/L Endosulfan Sulfate 0.020 U ug/L Endrin 0.050 U ug/L Endrin Aldehyde 0.020 U ug/L Heptachlor 0.0099 U MS ug/L Heptachlor Epoxide 0.020 U ug/L Methoxychlor 0.050 U ug/L Toxaphene 0.74 U ug/L PCB-1016 0.20 U ug/L PCB-1221 0.20 U ug/L PCB-1232 0.20 U ug/L PCB-1242 0.30 U ug/L PCB-1248 0.20 U ug/L PCB-1254 0.30 U ug/L PCB-1260 0.20 U ug/L Alachlor 0.59 U ug/L Ametryn 0.050 U ug/L Atrazine 0.050 U ug/L Azinphos Methyl 0.20 U ug/L Bromacil 0.20 U ug/L Butylate 0.20 U ug/L Chlorpyrifos Ethyl 0.050 U MS ug/L Chlorpyrifos Methyl 0.099 U ug/L Diazinon 0.050 U ug/L Ethion 0.050 U MS ug/L Ethoprop 0.099 U ug/L Fenamiphos 0.20 U ug/L Fonofos 0.099 U ug/L Hexazinone 0.099 UJ CCV ug/L Malathion 0.15 U ug/L Metalaxyl 0.25 U ug/L Metolachlor 0.50 U ug/L Metribuzin 0.099 U ug/L Mevinphos 0.20 U ug/L Naled 0.79 U ug/L Norflurazon 0.15 UJ CCV ug/L Parathion Ethyl 0.15 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 78 of 93 Field ID: 4 Z-11060 56th PL N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Parathion Methyl 0.099 U ug/L Phorate 0.050 U ug/L Prometon 0.20 U ug/L Prometryn 0.15 U ug/L Simazine 0.050 U ug/L 1206771 EPA 6010C Strontium 222 ug/L Titanium 0.50 U ug/L EPA 6020A Aluminum 7.7 I ug/L Arsenic 0.54 I ug/L Barium 18.8 ug/L Cadmium 0.030 U ug/L Chromium 0.30 U ug/L Copper 1.85 ug/L Lead 0.20 U ug/L Selenium 0.20 U ug/L Silver 0.025 U ug/L EPA 7470A Mercury 0.12 U MS ug/L 1206789 EPA 353.2 Rev. 2.0 NO2NO3-N 0.004 U mg N/L Ref. Method and Comment: EPA 8260C QC failure(s) observed. EPA 8270D QC failure(s) observed. DEP SOP: GC-012-3 (based on EPA 614, 619, 622, 633 and 507) QC failure(s) observed. Sample Location: ACREAGE Collection Date/Time: 08/05/2009 01:10 PM Field ID: 4 Z-11499 51st Ct. N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 1206841 EPA 900.0 Alpha, Total 2.7 pCi/L E83033 Alpha-Counting Error 1.5 pCi/L 1206850 EPA 6010C Strontium 422 ug/L E31780 Titanium 0.50 U ug/L EPA 6020A Aluminum 5.0 U ug/L Arsenic 1.46 ug/L Barium 27.8 ug/L Cadmium 0.030 U ug/L Chromium 0.31 I ug/L Copper 1.58 ug/L Lead 0.20 U ug/L Selenium 0.20 U ug/L Silver 0.025 U ug/L EPA 7470A Mercury 0.12 U ug/L Page 79 of 93 SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Field ID: 4 Z-11499 51st Ct. N Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Sample Location: ACREAGE Collection Date/Time: 08/05/2009 02:05 PM Field ID: 4 Z-5806 COCONUT BLVD Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 1206842 EPA 900.0 Alpha, Total 2.1 U pCi/L E83033 Alpha-Counting Error 1.3 pCi/L 1206849 EPA 6010C Strontium 1.08E+03 ug/L E31780 Titanium 0.50 U ug/L EPA 6020A Aluminum 5.0 U ug/L Arsenic 0.25 U ug/L Barium 16.0 ug/L Cadmium 0.030 U ug/L Chromium 0.57 I ug/L Copper 2.51 ug/L Lead 0.20 U ug/L Selenium 0.20 U ug/L Silver 0.025 U ug/L EPA 7470A Mercury 0.12 U ug/L Sample Location: ACREAGE Collection Date/Time: 08/05/2009 02:05 PM Field ID: 5 Z-SID NO.3 Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # 1206394 EPA 903.1 and Ra-05 Radium 226 11.1 pCi/L E83033 Radium 226-Counting Error 0.8 pCi/L Radium 228 0.8 U pCi/L Radium 228-Counting Error 0.5 pCi/L 1206400 EPA 900.0 Alpha, Total 15.3 pCi/L Alpha-Counting Error 3.9 pCi/L 1206822 EPA 353.2 Rev. 2.0 NO2NO3-N 0.006 I mg N/L E31780 1206828 FL-PRO TRPH 0.25 U mg/L 1206851 EPA 6010C Strontium 1.59E+03 ug/L Titanium 0.86 I ug/L EPA 6020A Aluminum 5.0 U ug/L Arsenic 0.59 I ug/L Barium 127 ug/L Cadmium 0.10 U ug/L Chromium 0.34 I ug/L Copper 0.50 U RPD ug/L Lead 0.20 U ug/L Selenium 0.20 U MS ug/L Silver 0.025 U ug/L EPA 7470A Mercury 0.12 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 80 of 93 Field ID: 5 Z-SID NO.3 Matrix: W-GROUND Sample ID Ref. Method Component Result Code QC Failures Units Cert # Ref. Method and Comment: EPA 903.1 and Ra-05 Result value confirmed by re-analysis 8/27/09, with a second value of 11.2. EPA 6020A One of the barium matrix spike recoveries could not be assessed due to a high analyte concentration in the QC sample. The cadmium MDL was adjusted due to preparation background. Sample Location: ACREAGE Collection Date/Time: 08/05/2009 08:26 AM Field ID: EQUIPMENT BLK Matrix: W-EQPMT-BK Sample ID Ref. Method Component Result Code QC Failures Units Cert # 1206392 EPA 903.1 and Ra-05 Radium 226 0.1 pCi/L E83033 Radium 226-Counting Error 0.1 pCi/L Radium 228 0.8 U pCi/L Radium 228-Counting Error 0.6 pCi/L 1206398 EPA 900.0 Alpha, Total 1.9 pCi/L Alpha-Counting Error 0.7 pCi/L 1206770 EPA 6010C Strontium 2.0 U ug/L E31780 Titanium 0.50 U ug/L EPA 6020A Aluminum 5.0 U ug/L Arsenic 0.25 U ug/L Barium 0.20 U ug/L Cadmium 0.030 U ug/L Chromium 0.30 U ug/L Copper 1.18 ug/L Lead 0.20 U ug/L Selenium 0.20 U ug/L Silver 0.025 U ug/L EPA 7470A Mercury 0.12 U ug/L Ref. Method and Comment: EPA 900.0 Sample re-analyzed 8/26/09 with a result of 0.7 U. EPA 6020A The copper result was confirmed in the undigested sample on 8/12/2009. Sample Location: ACREAGE Collection Date/Time: 08/04/2009 03:05 PM Field ID: TRIP BLANK Matrix: W-TRIP-BLK Sample ID Ref. Method Component Result Code QC Failures Units Cert # 1206887 EPA 8260C Benzene 0.20 U ug/L E31640 Bromodichloromethane 0.20 U ug/L Bromoform 0.50 UJ LCS ug/L Bromomethane 0.50 UJ CCV,MS ug/L 2-Butanone 10 U ug/L Carbon tetrachloride 0.20 U ug/L Chlorobenzene 0.20 U ug/L Chloroethane 0.50 U MS ug/L Chloroform 0.20 U ug/L Chloromethane 0.50 U MS ug/L Dibromochloromethane 0.20 U ug/L 1,2-Dichlorobenzene 0.50 U ug/L 1,3-Dichlorobenzene 0.50 U ug/L 1,4-Dichlorobenzene 0.50 U ug/L SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 81 of 93 Field ID: TRIP BLANK Matrix: W-TRIP-BLK Sample ID Ref. Method Component Result Code QC Failures Units Cert # 1,1-Dichloroethane 0.20 U ug/L 1,2-Dichloroethane 0.20 U ug/L 1,1-Dichloroethene 0.50 U ug/L cis-1,2-Dichloroethene 0.50 U ug/L trans-1,2-Dichloroethene 0.50 U ug/L 1,2-Dichloropropane 0.50 U ug/L cis-1,3-Dichloropropene 0.50 U MS ug/L trans-1,3-Dichloropropene 0.20 UJ CCV,LCS, ug/L MS Ethylbenzene 0.50 U ug/L Methylene chloride 0.50 U ug/L 1,1,2,2-Tetrachloroethane 0.50 UJ CCV ug/L Tetrachloroethene 0.50 U ug/L Toluene 0.50 U ug/L 1,1,1-Trichloroethane 0.20 U ug/L 1,1,2-Trichloroethane 0.20 U ug/L Trichloroethene 0.20 UJ CCV ug/L Trichlorofluoromethane 0.50 U ug/L Vinyl chloride 0.50 U ug/L Methyl-t-butyl ether 0.50 U ug/L o-Xylene 0.20 U ug/L m,p-Xylene 0.50 U ug/L Ref. Method and Comment: EPA 8260C QC failure(s) observed. Quality Control Report Ref. Method Analyte LCS %Recovery MS %Recovery Precision LCS SMP MS EPA 522 1,4-Dioxane 103 99.8 92.9 100 2.91 7.60 1,4-Dioxane 90.5 98.4 88.6 81.0 8.38 8.98 EPA 8260C 1,1,1-Trichloroethane 77.8 80.4 83.6 81.9 3.29 2.04 1,1,2,2-Tetrachloroethane 92.0 80.8 114 116 13.0 1.74 1,1,2-Trichloroethane 94.4 98.2 102 99.4 3.95 3.07 1,1-Dichloroethane 90.3 94.4 96.7 95.8 4.44 0.935 1,1-Dichloroethene 84.6 88.5 79.8 78.7 4.51 1.39 1,2-Dichlorobenzene 100 102 105 102 2.27 2.91 1,2-Dichloroethane 84.1 92.0 89.4 92.3 8.97 3.18 1,2-Dichloropropane 95.7 101 101 101 5.59 0.495 1,3-Dichlorobenzene 95.2 98.5 99.6 98.2 3.41 1.41 1,4-Dichlorobenzene 102 106 106 102 3.28 4.13 Benzene 100 106 105 104 5.35 1.24 Bromodichloromethane 84.6 86.9 89.3 89.1 2.68 0.224 Bromoform 68.9* 70.6 70.5 72.1 2.44 2.24 Bromomethane 71.5 73.6 55.6* 56.5* 2.89 1.59 Carbon tetrachloride 72.2 75.3 76.2 76.7 4.20 0.654 Chlorobenzene 101 105 103 104 4.27 0.290 Chloroethane 96.4 101 288* 298* 4.26 3.48 Chloroform 88.0 91.6 95.2 93.0 4.01 2.34 Chloromethane 76.4 79.3 64.0* 63.5* 3.73 0.558 Dibromochloromethane 75.2 76.9 78.4 79.4 2.24 1.27 Ethylbenzene 96.8 102 99.1 99.5 4.74 0.403 Methyl-t-butyl ether 89.9 92.5 92.5 92.8 2.85 0.324 Methylene chloride 93.8 96.3 99.7 97.5 2.63 2.23 Tetrachloroethene 98.3 103 99.1 100 4.57 0.904 Toluene 103 108 105 106 4.17 0.849 Trichloroethene 91.0 105 89.7 88.2 14.2 1.68 Trichlorofluoromethane 93.8 98.3 105 102 4.69 2.99 SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 82 of 93 Quality Control Report Ref. Method Analyte LCS %Recovery MS %Recovery Precision LCS SMP MS Vinyl chloride 92.6 97.1 97.7 94.4 4.74 3.43 cis-1,3-Dichloropropene 79.1 80.6 68.9* 67.5* 1.88 2.04 m,p-Xylene 98.8 102 103 101 3.48 2.00 o-Xylene 98.8 102 104 102 3.38 2.42 trans-1,2-Dichloroethene 92.0 97.3 97.4 95.8 5.60 1.66 trans-1,3-Dichloropropene 68.9* 69.6* 65.1* 64.0* 1.01 1.70 DEP SOP: LC-001-2 2,4,5-T 104 106 106 107 1.90 3.76 2,4-D 112 109 117 125 2.71 9.42 Acifluorfen 101 100 95.5 100 0.995 7.42 Silvex 74.5 73.4 80.8 79.6 1.49 1.32 2,4,5-T 104 115 98.5 98.8 10.0 1.51 2,4-D 102 98.3 111 108 3.69 1.54 Acifluorfen 100 98.1 96.2 96.2 1.92 1.20 Silvex 92.2 90.9 103 96.9 1.42 4.90 2,4,5-T 101 101 102 104 0.0 7.53 2,4-D 87.3 97.9 102 113 11.4 15.8 Acifluorfen 90.7 92.9 96.4 95.0 2.40 4.14 Silvex 90.5 83.4 102 105 8.17 8.46 EPA 8270D 1,2,4,5-Tetrachlorobenzene 68.4 74.1 70.9 75.0 7.97 6.09 1,2,4-Trichlorobenzene 75.8 83.0 76.4 82.8 9.07 8.43 1,3,5-Trinitrobenzene 122 127 121 128 3.47 6.32 1,3-Dinitrobenzene 92.3 96.9 96.1 98.9 4.90 3.35 1,4-Naphthoquinone 101 105 177* 167* 4.01 5.53 1-Naphthylamine 33.4 49.8 45.6 42.2 39.3 7.25 2,3,4,6-Tetrachlorophenol 99.0 105 104 93.9 5.69 9.31 2,4,5-Trichlorophenol 93.5 100 96.6 100 6.90 3.95 2,4,6-Trichlorophenol 92.2 97.9 95.8 99.7 6.02 4.46 2,4-Dichlorophenol 87.6 91.6 90.0 92.7 4.51 3.47 2,4-Dimethylphenol 71.7 78.8 79.7 75.1 9.46 5.50 2,4-Dinitrophenol 72.8 97.0 101 82.1 28.5 19.7 2,4-Dinitrotoluene 104 109 105 109 4.78 4.60 2,6-Dichlorophenol 78.9 82.6 80.7 84.4 4.51 4.95 2,6-Dinitrotoluene 97.9 102 98.0 103 4.36 5.27 2-Acetylaminofluorene 110 111 113 115 0.794 1.62 2-Chloronaphthalene 85.5 93.4 87.0 91.4 8.77 5.38 2-Chlorophenol 81.6 88.4 84.8 86.8 8.05 2.78 2-Methyl-4,6-dinitrophenol 105 113 108 115 8.01 6.45 2-Methylnaphthalene 83.6 90.7 83.6 88.6 8.17 6.30 2-Naphthylamine 36.8* 51.8 16.2* 10.6* 33.9 41.4* 2-Nitroaniline 99.0 105 102 105 6.19 3.86 2-Nitrophenol 89.7 96.0 92.0 97.2 6.80 5.95 2-Picoline 67.6 72.6 66.6 69.0 7.19 4.15 3,3'-Dichlorobenzidine 138 139 131 131 1.17 0.738 3,3'-Dimethylbenzidine 70.0 101 39.5 26.5 36.5 39.0 3-Methylcholanthrene 94.8 94.7 94.8 99.0 0.169 4.83 3-Nitroaniline 98.5 105 103 105 6.81 2.00 4-Aminobiphenyl 60.5 68.9 65.2 69.2 13.0 6.39 4-Bromophenyl phenyl ether 99.0 104 99.0 103 5.12 4.45 4-Chloro-3-methylphenol 91.2 97.1 97.7 100 6.25 3.16 4-Chloroaniline 79.0 84.5 80.5 84.3 6.80 5.13 4-Chlorophenyl phenyl ether 91.8 97.9 93.4 96.8 6.41 4.07 4-Nitrophenol 46.2 49.8 59.6 48.0 7.42 21.0 5-Nitro-o-toluidine 96.2 102 99.5 100 5.97 1.17 7,12-Dimethylbenz(a)anthracene 99.8 101 99.5 103 1.59 3.58 Acenaphthene 89.0 95.5 89.2 94.1 7.03 5.91 Acenaphthylene 86.0 92.2 88.8 91.4 6.87 3.47 Acetophenone 79.6 84.2 79.1 83.4 5.66 5.86 Aniline 63.9 70.6 62.9 67.1 10.1 6.99 Anthracene 96.8 102 98.3 101 4.72 3.54 94.9Azobenzene/1,2-Diphenylhydrazine 99.6 94.4 99.6 4.81 5.89 Benzidine 31.1 41.3 11.7 12.2 28.2 4.69 Benzo(a)anthracene 103 107 104 109 4.03 5.55 SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 83 of 93 Quality Control Report Ref. Method Analyte LCS %Recovery MS %Recovery Precision LCS SMP MS Benzo(a)pyrene 98.3 102 98.3 101 3.91 2.85 Benzo(b)fluoranthene 106 113 107 114 6.49 7.28 Benzo(g,h,i)perylene 101 106 99.8 105 4.97 5.38 Benzo(k)fluoranthene 105 110 107 107 4.39 0.642 Benzyl alcohol 72.0 77.5 71.9 75.9 7.39 5.85 Bis(2-chloroethoxy)methane 88.4 94.4 89.4 94.1 6.61 5.68 Bis(2-chloroethyl)ether 79.3 84.4 78.2 82.8 6.21 6.26 Bis(2-chloroisopropyl)ether 87.8 95.4 88.6 94.6 8.30 6.96 Bis(2-ethylhexyl)phthalate 103 107 100 102 3.66 2.71 Butyl benzyl phthalate 102 106 104 106 4.09 2.28 Chrysene 98.0 103 101 102 4.90 1.95 Di-n-butyl phthalate 105 108 88.3 91.1 3.05 3.04 Di-n-octyl phthalate 106 110 104 108 4.04 4.68 Dibenzo(a,h)anthracene 99.0 105 99.6 103 5.58 4.16 Dibenzofuran 92.3 98.4 94.0 97.6 6.42 4.29 Diethyl phthalate 101 107 103 105 6.08 2.11 Dimethyl phthalate 100 105 102 103 4.76 1.35 Dimethylaminoazobenzene 85.6 89.0 95.0 92.0 3.85 2.72 Dinoseb 115 119 118 121 3.18 3.47 Ethyl methanesulfonate 78.0 85.5 81.2 84.0 9.20 3.88 Fluoranthene 102 108 103 107 5.30 4.50 Fluorene 93.8 99.0 95.6 98.8 5.40 3.79 Hexachlorobenzene 98.2 103 95.9 101 4.46 5.57 Hexachlorobutadiene 65.8 74.6 64.9 74.3 12.5 14.0 Hexachlorocyclopentadiene 31.1 36.9 38.0 46.4 17.1 20.3 Hexachloroethane 70.7 78.6 68.0 77.2 10.6 13.1 Hexachloropropene 58.0 63.8 64.8 68.8 9.46 6.48 Indeno(1,2,3-cd)pyrene 99.1 104 99.2 103 4.77 4.33 Isophorone 89.4 95.2 90.6 97.1 6.20 7.40 Isosafrole 78.4 81.6 79.1 82.0 4.05 4.07 Methapyrilene 43.7* 50.9 62.4 64.2 15.1 3.27 Methyl methanesulfonate 63.2 68.2 63.2 65.2 7.55 3.61 N-Nitrosodi-n-propylamine 92.4 99.3 92.7 99.7 7.22 7.77 N-Nitrosodiethylamine 75.0 80.0 74.9 79.7 6.40 6.70 N-Nitrosodimethylamine 65.7 67.2 67.4 68.4 2.17 1.97 N-Nitrosodiphenylamine/ 102 105 103 107 3.22 4.38 Diphenylamine N-Nitrosomethylethylamine 72.3 73.7 74.7 72.4 1.86 2.61 N-Nitrosomorpholine 81.6 85.9 82.1 86.5 5.11 5.76 N-Nitrosopiperidine 79.0 85.0 80.2 86.2 7.32 7.80 N-Nitrosopyrrolidine 67.9 71.6 67.2 71.8 5.22 7.17 Naphthalene 82.9 90.0 83.6 88.8 8.14 6.43 Nitrobenzene 88.1 94.1 89.9 94.4 6.63 5.33 Nitroquinoline-1-oxide 140* 141* 120 136* 0.742 12.7 Pentachlorobenzene 81.4 87.0 83.2 86.0 6.65 3.76 Pentachloroethane 66.6 71.4 68.8 73.4 6.96 6.96 Pentachloronitrobenzene 98.4 101 100 103 2.89 3.10 Pentachlorophenol 98.4 96.2 106 102 2.22 4.12 Phenacetin 99.4 102 102 104 2.58 3.10 Phenanthrene 101 105 100 103 4.08 2.82 Phenol 49.9 53.0 67.2 51.6 6.06 25.7 Pyrene 97.7 103 99.7 101 4.83 1.77 Pyridine 48.8 53.8 48.0 49.8 9.79 4.13 Safrole 77.0 79.6 76.6 80.7 3.37 5.68 m,p-Cresols 75.1 77.4 81.6 76.2 3.02 6.30 o-Cresol 74.6 80.9 85.0 80.7 8.08 4.72 o-Toluidine 71.7 78.2 71.3 75.7 8.70 6.48 FL-PRO TRPH 94.6 106 11.3 EPA 8270D 1,2,4,5-Tetrachlorobenzene 68.9 69.3 69.2 72.8 0.637 5.64 1,2,4-Trichlorobenzene 74.3 75.2 75.6 79.6 1.18 5.68 1,3,5-Trinitrobenzene 117 120 114 112 2.51 1.37 1,3-Dinitrobenzene 90.7 93.2 92.0 91.5 2.81 0.0292 SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 84 of 93 Quality Control Report Ref. Method Analyte LCS %Recovery MS %Recovery Precision LCS SMP MS 1,4-Naphthoquinone 91.2 91.0 84.0 84.0 0.132 0.574 1-Naphthylamine 51.6 57.5 67.4 65.0 10.8 3.17 2,3,4,6-Tetrachlorophenol 91.5 92.8 98.2 100 1.37 2.41 2,4,5-Trichlorophenol 94.4 87.6 93.0 93.1 7.48 0.746 2,4,6-Trichlorophenol 90.2 87.0 92.0 92.8 3.61 1.44 2,4-Dichlorophenol 86.7 86.5 87.4 88.0 0.231 1.26 2,4-Dimethylphenol 80.7 77.8 78.8 77.8 3.63 0.652 2,4-Dinitrophenol 71.4 56.6 90.7 76.1 23.2 16.9 2,4-Dinitrotoluene 102 99.6 101 100 2.46 0.0641 2,6-Dichlorophenol 78.0 79.6 79.3 83.0 2.08 5.11 2,6-Dinitrotoluene 97.2 93.8 95.7 94.9 3.52 0.307 2-Acetylaminofluorene 105 105 107 110 0.304 3.64 2-Chloronaphthalene 86.2 82.9 81.6 85.0 3.93 4.70 2-Chlorophenol 86.8 81.1 79.6 82.0 6.77 3.54 2-Methyl-4,6-dinitrophenol 91.4 95.1 98.1 97.0 3.99 0.574 2-Methylnaphthalene 83.5 79.9 78.5 82.0 4.36 4.91 2-Naphthylamine 52.8 58.8 49.3* 48.2* 10.8 1.64 2-Nitroaniline 99.2 97.8 96.9 98.3 1.46 2.01 2-Nitrophenol 92.6 89.2 89.4 90.5 3.74 1.73 2-Picoline 74.0 70.5 67.3 70.8 4.82 5.73 3,3'-Dichlorobenzidine 126 129 116 111 2.65 3.68 3,3'-Dimethylbenzidine 91.2 101 54.0 46.4 10.6 14.6 3-Methylcholanthrene 82.4 84.9 91.1 89.9 3.01 0.752 3-Nitroaniline 97.0 98.5 97.7 101 1.49 3.44 4-Aminobiphenyl 62.4 67.6 68.6 68.7 7.94 0.749 4-Bromophenyl phenyl ether 95.4 93.0 93.2 94.2 2.51 1.60 4-Chloro-3-methylphenol 91.5 91.9 93.6 96.2 0.393 3.40 4-Chloroaniline 77.7 78.6 76.2 79.3 1.13 4.56 4-Chlorophenyl phenyl ether 91.9 89.2 88.6 90.0 3.05 2.14 4-Nitrophenol 40.5 41.2 45.0 45.3 1.66 1.11 5-Nitro-o-toluidine 95.8 95.8 93.0 93.9 0.0835 1.52 7,12-Dimethylbenz(a)anthracene 95.2 99.6 84.6 92.0 4.56 9.00 Acenaphthene 89.1 86.1 85.0 87.5 3.42 3.40 Acenaphthylene 86.4 83.9 83.8 85.2 2.96 2.14 Acetophenone 81.4 77.9 78.6 80.5 4.32 3.04 Aniline 66.6 65.6 64.0 65.6 1.63 3.01 Anthracene 93.8 93.8 91.6 93.6 0.0853 2.78 95.2Azobenzene/1,2-Diphenylhydrazine 91.3 89.8 91.2 4.20 2.08 Benzidine 34.2 42.4 15.0 11.0 21.4 30.1 Benzo(a)anthracene 100 98.2 97.0 98.3 1.98 1.89 Benzo(a)pyrene 95.2 96.6 93.2 93.6 1.46 1.04 Benzo(b)fluoranthene 102 108 100 105 5.47 5.64 Benzo(g,h,i)perylene 92.2 92.6 93.0 95.0 0.390 2.74 Benzo(k)fluoranthene 103 96.2 97.7 98.7 6.51 1.63 Benzyl alcohol 75.0 70.1 67.8 70.0 6.76 3.77 Bis(2-chloroethoxy)methane 89.2 86.8 85.2 87.7 2.77 3.54 Bis(2-chloroethyl)ether 83.7 75.8 75.1 77.7 9.93 3.98 Bis(2-chloroisopropyl)ether 91.7 85.7 85.6 88.1 6.81 3.48 Bis(2-ethylhexyl)phthalate 98.8 94.6 93.4 95.6 4.30 2.82 Butyl benzyl phthalate 101 96.5 96.7 99.2 4.42 3.19 Chrysene 97.3 93.6 93.7 94.2 3.94 1.09 Di-n-butyl phthalate 99.5 101 98.2 99.3 1.56 1.66 Di-n-octyl phthalate 102 102 99.5 102 0.195 3.31 Dibenzo(a,h)anthracene 92.2 93.8 92.3 94.5 1.76 2.89 Dibenzofuran 91.4 88.7 87.9 89.4 3.06 2.20 Diethyl phthalate 98.7 97.7 96.5 97.8 1.02 1.92 Dimethyl phthalate 98.9 95.9 95.0 96.1 3.08 1.70 Dimethylaminoazobenzene 88.4 86.3 88.6 92.6 2.38 4.99 Dinoseb 102 108 107 108 5.71 1.58 Ethyl methanesulfonate 83.2 79.9 74.7 81.4 4.02 9.08 Fluoranthene 98.4 97.9 97.0 96.2 0.530 0.212 Fluorene 93.0 90.8 89.9 91.8 2.35 2.64 SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 85 of 93 Quality Control Report Ref. Method Analyte LCS %Recovery MS %Recovery Precision LCS SMP MS Hexachlorobenzene 95.0 92.3 92.6 93.8 2.82 1.90 Hexachlorobutadiene 65.6 67.6 68.3 74.6 3.06 9.47 Hexachlorocyclopentadiene 22.7 29.5 33.4 34.1 26.2 2.59 Hexachloroethane 70.9 70.3 72.6 78.1 0.793 7.85 Hexachloropropene 57.5 60.6 60.4 65.7 5.35 9.08 Indeno(1,2,3-cd)pyrene 92.3 92.9 92.0 95.4 0.648 4.12 Isophorone 90.8 88.0 86.7 89.2 3.13 3.35 Isosafrole 78.9 79.5 78.4 81.1 0.757 3.93 Methapyrilene 44.9* 50.1 82.5 82.4 10.9 0.429 Methyl methanesulfonate 65.3 62.0 60.6 64.3 5.22 6.46 N-Nitrosodi-n-propylamine 93.9 88.6 88.4 91.3 5.83 3.87 N-Nitrosodiethylamine 77.1 72.6 71.6 75.5 5.93 5.96 N-Nitrosodimethylamine 80.0 67.5 67.1 66.2 16.9 0.746 N-Nitrosodiphenylamine/ 98.2 100 99.3 104 2.21 4.83 Diphenylamine N-Nitrosomethylethylamine 84.2 73.0 70.7 73.7 14.3 4.73 N-Nitrosomorpholine 82.9 79.6 77.8 84.2 3.99 8.42 N-Nitrosopiperidine 80.8 78.0 77.8 79.6 3.48 2.86 N-Nitrosopyrrolidine 66.7 64.2 62.9 67.9 3.79 8.16 Naphthalene 82.9 80.5 82.5 85.9 2.94 4.56 Nitrobenzene 93.4 88.8 87.4 89.9 5.09 3.35 Nitroquinoline-1-oxide 68.2 80.8 66.6 59.4 16.9 10.8 Pentachlorobenzene 82.0 83.9 81.5 81.8 2.22 1.02 Pentachloroethane 68.6 66.3 67.5 72.8 3.44 8.21 Pentachloronitrobenzene 96.6 99.0 97.7 99.3 2.50 2.20 Pentachlorophenol 73.7 78.3 107 107 6.11 0.798 Phenacetin 97.0 99.0 96.4 98.8 2.12 2.99 Phenanthrene 95.7 95.5 95.0 95.3 0.209 0.911 Phenol 53.6 50.3 47.2 49.5 6.32 5.29 Pyrene 97.4 93.0 92.4 94.8 4.54 3.09 Pyridine 56.2 53.6 48.1 51.0 4.81 6.59 Safrole 76.5 75.3 74.3 77.7 1.53 5.05 m,p-Cresols 71.2 65.1 63.8 68.5 8.95 7.71 o-Cresol 79.9 74.1 71.7 73.9 7.48 3.60 o-Toluidine 74.4 72.0 71.2 72.1 3.33 1.91 1,2,4,5-Tetrachlorobenzene 82.1 82.0 77.8 79.7 0.146 4.00 1,2,4-Trichlorobenzene 85.1 89.5 85.6 86.8 5.04 3.10 1,3,5-Trinitrobenzene 123 131 110 99.2 6.87 8.77 1,3-Dinitrobenzene 104 107 102 107 3.31 6.60 1,4-Naphthoquinone 98.6 115 116 134* 15.1 16.1 1-Naphthylamine 59.3 58.4 24.8* 30.0* 1.63 20.5 2,3,4,6-Tetrachlorophenol 95.3 98.7 105 104 3.46 0.898 2,4,5-Trichlorophenol 95.1 95.6 102 105 0.545 4.95 2,4,6-Trichlorophenol 93.4 94.6 100 99.6 1.32 1.07 2,4-Dichlorophenol 98.4 102 98.8 101 3.56 3.79 2,4-Dimethylphenol 85.7 86.5 93.7 95.8 0.976 3.94 2,4-Dinitrophenol 69.8 73.6 76.4 81.6 5.25 8.19 2,4-Dinitrotoluene 105 108 107 107 3.16 1.48 2,6-Dichlorophenol 92.8 96.5 90.7 94.8 3.93 6.02 2,6-Dinitrotoluene 101 103 103 103 1.25 0.928 2-Acetylaminofluorene 87.9 95.6 95.7 96.6 8.37 2.58 2-Chloronaphthalene 89.6 92.6 90.9 90.1 3.34 0.782 2-Chlorophenol 91.7 93.2 90.3 90.0 1.60 1.31 2-Methyl-4,6-dinitrophenol 91.4 94.0 97.2 98.8 2.85 3.26 2-Methylnaphthalene 87.2 89.7 86.8 85.5 2.76 0.0874 2-Naphthylamine 52.2 51.6 6.04* 6.80* 1.00 13.5 2-Nitroaniline 106 107 108 109 0.678 2.44 2-Nitrophenol 102 104 102 101 1.75 0.444 2-Picoline 80.0 83.6 81.0 76.5 4.35 4.07 3,3'-Dichlorobenzidine 116 109 35.5 44.4 5.42 20.7 3,3'-Dimethylbenzidine 63.6 61.3 3.72 3-Methylcholanthrene 77.5 84.0 88.8 94.1 8.03 7.44 SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 86 of 93 Quality Control Report Ref. Method Analyte LCS %Recovery MS %Recovery Precision LCS SMP MS 3-Nitroaniline 104 105 101 105 0.917 5.70 4-Aminobiphenyl 66.7 69.8 34.3* 37.5* 4.57 10.7 4-Bromophenyl phenyl ether 96.8 102 97.4 99.3 5.43 3.58 4-Chloro-3-methylphenol 106 110 109 113 4.06 4.55 4-Chloroaniline 86.3 92.0 84.0 84.0 6.37 1.67 4-Chlorophenyl phenyl ether 96.4 97.0 97.2 97.2 0.662 1.62 4-Nitrophenol 39.2 38.5 45.8 48.2 1.75 6.77 5-Nitro-o-toluidine 103 106 101 101 2.82 2.18 7,12-Dimethylbenz(a)anthracene 94.6 100 89.5 98.0 5.51 10.8 Acenaphthene 94.4 96.2 93.6 94.2 1.89 2.26 Acenaphthylene 91.5 92.2 93.8 92.1 0.741 0.227 Acetophenone 90.5 94.0 88.9 89.5 3.82 2.38 Aniline 71.4 71.7 67.1 63.5 0.419 3.76 Anthracene 95.2 99.8 97.0 98.0 4.72 2.69 94.2Azobenzene/1,2-Diphenylhydrazine 99.8 98.6 97.9 5.73 0.974 Benzo(a)anthracene 84.4 88.5 85.8 85.4 4.77 1.20 Benzo(a)pyrene 91.4 93.7 89.4 89.5 2.42 1.75 Benzo(b)fluoranthene 98.8 108 100 104 9.34 5.86 Benzo(g,h,i)perylene 86.1 89.4 87.3 89.8 3.74 4.47 Benzo(k)fluoranthene 97.4 97.1 95.8 93.4 0.288 0.956 Benzyl alcohol 76.9 81.2 77.1 78.6 5.41 3.59 Bis(2-chloroethoxy)methane 101 104 101 100 2.73 0.635 Bis(2-chloroethyl)ether 87.6 94.2 90.4 83.8 7.26 5.91 Bis(2-chloroisopropyl)ether 98.0 99.9 99.1 96.3 1.98 1.16 Bis(2-ethylhexyl)phthalate 83.1 88.2 85.4 83.2 6.02 0.871 Butyl benzyl phthalate 84.0 91.0 89.8 87.0 7.95 1.48 Chrysene 80.7 84.4 83.3 81.2 4.50 0.814 Di-n-butyl phthalate 103 109 106 104 5.54 0.268 Di-n-octyl phthalate 98.6 106 101 101 7.64 1.15 Dibenzo(a,h)anthracene 84.6 88.7 85.2 88.6 4.75 5.67 Dibenzofuran 95.6 98.0 96.4 96.8 2.48 2.00 Diethyl phthalate 105 107 107 106 2.53 0.723 Dimethyl phthalate 104 106 104 104 2.63 2.09 Dimethylaminoazobenzene 72.4 81.7 75.9 72.4 12.0 3.08 Dinoseb 104 112 109 109 7.50 1.52 Ethyl methanesulfonate 90.9 91.4 91.9 89.0 0.571 1.47 Fluoranthene 100 104 102 102 3.87 2.37 Fluorene 97.7 100 96.8 98.3 2.31 3.14 Hexachlorobenzene 94.9 100 97.1 96.9 5.37 1.46 Hexachlorobutadiene 75.1 83.6 75.2 81.4 10.7 9.58 Hexachlorocyclopentadiene 29.1 22.6 27.0 30.7 25.3 14.4 Hexachloroethane 78.6 84.1 78.5 82.8 6.73 7.02 Hexachloropropene 67.9 66.0 66.3 67.8 2.87 3.99 Indeno(1,2,3-cd)pyrene 86.2 89.6 86.9 89.9 3.78 5.10 Isophorone 103 107 102 103 3.48 2.25 Isosafrole 93.8 97.8 89.4 94.6 4.13 7.36 Methapyrilene 44.1* 51.8 74.1 69.3 16.1 5.03 Methyl methanesulfonate 69.4 73.5 71.5 70.2 5.65 0.0841 N-Nitrosodi-n-propylamine 102 105 99.8 103 2.72 4.59 N-Nitrosodiethylamine 81.5 88.3 83.5 84.0 8.01 2.24 N-Nitrosodimethylamine 75.1 80.7 81.7 70.7 7.14 12.7 N-Nitrosodiphenylamine/ 103 110 105 106 6.48 2.87 Diphenylamine N-Nitrosomethylethylamine 79.6 91.8 81.4 80.4 14.3 0.430 N-Nitrosomorpholine 92.1 96.2 91.4 95.3 4.29 5.87 N-Nitrosopiperidine 88.9 92.1 87.8 90.1 3.49 4.27 N-Nitrosopyrrolidine 73.8 78.4 67.7 73.7 6.15 10.2 Naphthalene 94.0 97.6 93.1 92.6 3.80 1.11 Nitrobenzene 103 108 103 101 4.50 0.557 Nitroquinoline-1-oxide 68.6 69.6 29.5* 18.6* 1.45 43.8* Pentachlorobenzene 90.0 93.4 87.8 89.2 3.71 3.34 Pentachloroethane 75.9 77.0 74.2 74.8 1.52 2.42 SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 87 of 93 Quality Control Report Ref. Method Analyte LCS %Recovery MS %Recovery Precision LCS SMP MS Pentachloronitrobenzene 101 111 103 107 9.85 5.48 Pentachlorophenol 75.3 74.4 102 108 1.18 7.50 Phenacetin 102 109 104 105 7.06 2.62 Phenanthrene 98.2 104 99.2 101 5.47 3.74 Phenol 56.7 58.3 52.4 53.8 2.78 4.23 Pyrene 79.8 86.2 83.7 83.0 7.66 0.850 Pyridine 59.6 60.9 60.1 53.9 2.09 9.25 Safrole 88.9 91.9 85.8 89.8 3.32 6.22 m,p-Cresols 76.2 84.6 71.5 77.5 10.4 9.69 o-Cresol 83.9 87.0 85.4 86.3 3.65 2.69 o-Toluidine 80.2 84.7 76.8 73.5 5.38 2.65 FL-PRO TRPH 98.5 107 113 105 7.94 9.54 EPA 504 1,2-Dibromoethane 102 101 107 4.37 DEP SOP: GC-012-3 (based on Ametryn 81.3 83.7 80.7 2.81 EPA 614, 619, 622, 633 and 507) Atrazine 90.5 97.9 95.0 7.87 Chlorpyrifos Ethyl 89.5 99.9 95.2 11.0 Chlorpyrifos Methyl 97.5 107 103 8.84 Ethion 106 115 114 8.21 Ethoprop 101 109 104 7.14 Hexazinone 95.1 104 99.8 9.28 Malathion 91.0 99.7 97.1 9.18 Metribuzin 91.8 98.7 98.2 7.28 Mevinphos 111 121 111 8.46 Norflurazon 92.7 101 96.9 8.59 Phorate 89.5 98.2 94.0 9.30 Prometryn 90.9 97.2 92.8 6.65 Simazine 92.3 102 95.8 9.58 DEP SOP: GC-011-5 (based on Aldrin 90.3 88.4 81.6 2.08 EPA Methods 608, 617, 1656) Alpha-BHC 99.8 97.6 90.3 2.25 Beta-BHC 116 112 126 3.43 DDD-p,p' 109 108 103 1.59 DDE-p,p' 117 115 109 2.38 DDT-p,p' 113 115 104 1.44 Delta-BHC 108 107 118 1.15 Dieldrin 84.6 84.5 76.5 0.0852 Endosulfan I 103 101 95.1 1.50 Endosulfan II 101 100 93.6 0.825 Endosulfan Sulfate 100 98.3 94.7 1.89 Endrin 100 98.6 94.2 1.84 Endrin Aldehyde 102 101 94.3 1.23 Gamma-BHC 95.5 95.2 88.8 0.386 Heptachlor 93.4 93.3 85.1 0.141 Heptachlor Epoxide 108 103 87.9 4.51 Methoxychlor 112 111 106 0.803 Aldrin 89.3 98.7 94.4 4.44 Alpha-BHC 91.7 55.4* 47.5* 15.4 Beta-BHC 98.4 65.6 82.5 22.8 DDD-p,p' 112 70.2 76.9 9.01 DDE-p,p' 97.4 64.8 71.1 9.23 DDT-p,p' 105 76.7 65.4 15.9 Delta-BHC 101 62.8 62.2 0.999 Dieldrin 92.8 62.3 60.2 3.57 Endosulfan I 95.7 75.5 91.2 18.8 Endosulfan II 97.6 101 109 7.74 Endosulfan Sulfate 97.7 77.5 69.9 10.4 Endrin 106 68.3 70.7 3.44 Endrin Aldehyde 100 72.5 60.7 17.8 Gamma-BHC 93.3 68.8 75.3 8.98 Heptachlor 102 54.4* 71.0 26.6 Heptachlor Epoxide 95.2 62.6 83.8 28.9 SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 88 of 93 Quality Control Report Ref. Method Analyte LCS %Recovery MS %Recovery Precision LCS SMP MS Methoxychlor 117 95.0 97.8 2.88 DEP SOP: GC-012-3 (based on Ametryn 94.7 68.2 69.7 2.15 EPA 614, 619, 622, 633 and 507) Atrazine 96.3 73.9 72.3 2.14 Chlorpyrifos Ethyl 94.3 51.5* 48.8* 5.49 Chlorpyrifos Methyl 92.6 67.3 66.2 1.63 Ethion 113 49.2* 49.1* 0.207 Ethoprop 91.3 74.0 66.6 10.5 Hexazinone 105 94.3 94.4 0.0753 Malathion 94.6 63.7 60.8 4.61 Metribuzin 82.0 68.9 71.5 3.70 Mevinphos 107 92.5 98.4 6.11 Norflurazon 105 89.3 89.6 0.358 Phorate 90.7 62.8 60.0 4.49 Prometryn 99.0 70.5 79.1 11.5 Simazine 94.7 78.3 77.3 1.24 EPA 6020A Aluminum 93.7 92.8 92.7 0.744 92.0 Selenium 99.1 88.2 82.0 0.0813 82.0 Aluminum 93.9 91.8 88.1 2.41 90.3 Arsenic 93.2 91.8 89.7 0.968 90.6 Barium 96.5 96.8 98.2 1.64 Cadmium 96.4 95.2 88.7 0.0320 88.7 Chromium 97.3 97.6 92.7 2.97 95.5 Lead 94.6 103 97.2 2.54 99.7 Selenium 97.4 90.8 61.6* 4.05 64.2* Silver 93.4 92.1 90.0 1.40 91.2 EPA 7470A Mercury 106 104 103 98.7 1.53 4.04 Mercury 104 102 88.7 90.7 2.23 1.92 81.4* EPA 6020A Arsenic 97.2 96.9 94.4 2.54 94.5 Barium 99.6 104 101 2.84 98.4 Cadmium 93.1 95.9 98.1 2.22 97.4 Chromium 99.1 100 98.5 1.56 97.9 Copper 95.4 91.2 91.5 11.6 87.4 Lead 96.9 104 102 1.64 102 Silver 97.2 98.4 95.0 3.57 94.6 EPA 6010C Strontium 104 102 102 2.12 102 Titanium 101 101 99.5 1.36 98.6 Strontium 102 102 102 2.37 102 Titanium 103 105 108 3.40 105 EPA 6020A Copper 102 95.4 95.2 34.2* 95.8 EPA 7470A Mercury 101 110 101 101 8.56 0.577 EPA 353.2 Rev. 2.0 NO2NO3-N 97.0 100 99.4 0.966 SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 89 of 93 Quality Control Report Ref. Method Analyte LCS %Recovery MS %Recovery Precision LCS SMP MS NO2NO3-N 102 103 103 0.489 NO2NO3-N 104 104 105 1.44 Reference Method Descriptions Ref. Method: Description DEP SOP: GC-011-5 (based on EPA Organochlorine pesticides and PCBs in water matrices by GC/ECD. Methods 608, 617, 1656) DEP SOP: GC-012-3 (based on EPA Organonitrogen and phosphorus pesticides in water matrices by GC/NPD. 614, 619, 622, 633 and 507) DEP SOP: LC-001-2 Chlorinated (phenoxy acid) herbicides in water matrices by HPLC/MS/MS EPA 353.2 Rev. 2.0 Nitrite/Nitrate in aqueous matrices as mg N/L EPA 504 Fumigants in water matrices by GC/ECD. EPA 522 1,4-Dioxane in Aqueous Matrices by GC/MS using SIM EPA 6010C Total Recoverable Metals analysis using ICP emission spectroscopy for aqueous samples supporting RCRA Projects EPA 6020A Total Recoverable Metals analysis using ICP-MS for aqueous samples supporting RCRA Projects EPA 7470A Mercury in aqueous samples using cold vapor AA spectroscopy. EPA 8260C Volatile organic pollutants in acid preserved water matrices using GC/MS EPA 8270D EPA Method 8270, Semi-volatile organic pollutants including PAHs, excluding PCBs and Toxaphene, in water matrices by GC/MS. EPA 900.0 Gross Alpha in water by overflow lab EPA 903.1 and Ra-05 Radium 226 (903.1) and 228 (Ra-05) by overflow lab FL-PRO Total recoverable petroleum hydrocarbons in water samples by GC-FID. SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 90 of 93 Non-Conformance Report NCR ID:3171 Job(s)Event(s) SIS-2009-08-06-01 NCR Type: SHIPPING/RECEIVING Test(s)Sample(s) NCR Category: Receiving Observation: 1) For one site, the NO2NO3 container was not received (2Z-14390 Orange Blvd). 2) For one site there was no collection date written on the field sheet (5Z SID No.3). The collection date was written on the bottles. 3) Paperwork for one site was not received (2Z-14692 Tangerine Blvd). Resolution: 1) For the site 2Z 14390 Orange Blvd, an aliquot from the bottle for FLO-PRO analysis was poured out and labeled for NO2NO3 analysis. Sample preservation and storage for FLO-PRO analysis are the same for NO2NO3 analysis; the data quality is not affected by using the FLO-PRO aliquot. Customer was notified (Amber Igoe). 2) The collection date on the bottles was used. 3) The bottles were processed in LIMs using the information on the bottle labels. Customer was notified (Amber Igoe). She was not able to provide the paperwork. Authorized By / Date: Kathryn Brackett 8/14/2009 The Non-Conformance Report details exceptions or problems encountered with the events/jobs/samples/test. Please address questions to: Chemistry Tim Fitzpatrick (850) 245-8085 Biology David D. Whiting (850) 245-8177 SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 91 of 93 Preparation and Analysis Log Received Prep Analysis Date Date/Time Prepared by Date/Time Analyzed by Associated Samples Ref. Method DEP SOP: GC-011-5 (based on 8/6/2009 08/07/2009 Fe-Val Siddell 08/10/2009 Kristin L. Kline 1206719, 1206720, 1206721, 1206722, EPA Methods 608, 617, 1656) 1206724, 1206725, 1206726, 1206727, 1206728, 1206729, 1206730, 1206731, 1206732, 1206733, 1206832 DEP SOP: GC-011-5 (based on 8/6/2009 08/11/2009 Fe-Val Siddell 08/13/2009 Vandana T. Nagar 1206735 EPA Methods 608, 617, 1656) DEP SOP: GC-012-3 (based on 8/6/2009 08/07/2009 Fe-Val Siddell 08/08/2009 Marek Topolski 1206719, 1206720, 1206721, 1206722, EPA 614, 619, 622, 633 and 1206724, 1206725, 1206726, 1206727, 507) 1206728, 1206729, 1206730 DEP SOP: GC-012-3 (based on 8/6/2009 08/07/2009 Fe-Val Siddell 08/09/2009 Marek Topolski 1206731, 1206732, 1206733, 1206832 EPA 614, 619, 622, 633 and 507) DEP SOP: GC-012-3 (based on 8/6/2009 08/11/2009 Fe-Val Siddell 08/13/2009 Marek Topolski 1206735 EPA 614, 619, 622, 633 and 507) DEP SOP: LC-001-2 8/6/2009 08/07/2009 Hoor Shaik 08/09/2009 S. M. Reddy 1206633, 1206634, 1206635, 1206636 DEP SOP: LC-001-2 8/6/2009 08/08/2009 Hoor Shaik 08/09/2009 S. M. Reddy 1206638, 1206640, 1206642, 1206643, 1206644, 1206645, 1206646, 1206647, 1206649, 1206825 DEP SOP: LC-001-2 8/6/2009 08/10/2009 Hoor Shaik 08/11/2009 S. M. Reddy 1206639, 1206641 EPA 353.2 Rev. 2.0 8/6/2009 08/10/2009 Sima Feizi 1206773, 1206774, 1206775, 1206778, 1206780, 1206781, 1206782, 1206783, 1206784, 1206785, 1206786, 1206787, 1206789, 1206822, 1206823 EPA 353.2 Rev. 2.0 8/6/2009 08/12/2009 Beverly Y. Sanders 1206779 EPA 504 8/6/2009 08/07/2009 Vandana T. Nagar 08/08/2009 Vandana T. Nagar 1206701, 1206702, 1206703, 1206704, 1206706, 1206707, 1206708, 1206709, 1206710 EPA 504 8/6/2009 08/07/2009 Vandana T. Nagar 08/09/2009 Vandana T. Nagar 1206711, 1206712, 1206713, 1206714, 1206715, 1206717, 1206820 EPA 522 8/6/2009 08/08/2009 Rasheda Ghaffari 08/08/2009 Mohammad Ghaffari 1206597, 1206598, 1206599, 1206600, 1206602, 1206603, 1206604, 1206607 EPA 522 8/6/2009 08/09/2009 Rasheda Ghaffari 08/09/2009 Mohammad Ghaffari 1206605, 1206606, 1206608, 1206609, 1206610, 1206611, 1206613, 1206834 EPA 6010C 8/6/2009 08/10/2009 Elliott D. Healy 08/14/2009 Elisa J Lutz 1206851 SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 92 of 93 Preparation and Analysis Log Received Prep Analysis Date Date/Time Prepared by Date/Time Analyzed by Associated Samples Ref. Method EPA 6010C 8/6/2009 08/11/2009 Elliott D. Healy 08/13/2009 Elisa J Lutz 1206755, 1206756, 1206757, 1206758, 1206760, 1206761, 1206762, 1206763, 1206764, 1206765, 1206766, 1206767, 1206768, 1206769, 1206770, 1206771, 1206847, 1206848, 1206849, 1206850 EPA 6020A 8/6/2009 08/07/2009 Elliott D. Healy 08/10/2009 Charles J. Peterson 1206755, 1206756, 1206757, 1206758, 1206760, 1206761, 1206762, 1206763, 1206764, 1206765, 1206766, 1206767, 1206768, 1206769, 1206770, 1206771, 1206847, 1206848, 1206849, 1206850 EPA 6020A 8/6/2009 08/10/2009 Elliott D. Healy 08/10/2009 Charles J. Peterson 1206851 EPA 6020A 8/6/2009 08/11/2009 Elliott D. Healy 08/12/2009 Charles J. Peterson 1206755, 1206756, 1206757, 1206758, 1206760, 1206761, 1206762, 1206763, 1206764, 1206765, 1206766, 1206767, 1206768, 1206769, 1206770, 1206771, 1206847, 1206848, 1206849, 1206850 EPA 6020A 8/6/2009 08/13/2009 Elliott D. Healy 08/14/2009 Charles J. Peterson 1206851 EPA 7470A 8/6/2009 08/11/2009 Martin Acosta 08/12/2009 Martin Acosta 1206756, 1206757, 1206758, 1206761, 1206762, 1206763, 1206764, 1206765, 1206766, 1206767, 1206768, 1206769, 1206771, 1206847, 1206848, 1206849, 1206850, 1206851 EPA 7470A 8/6/2009 08/14/2009 Martin Acosta 08/17/2009 Martin Acosta 1206755, 1206760, 1206770 EPA 8260C 8/6/2009 08/07/2009 Farzad Booeshaghi 1206615, 1206616, 1206617, 1206619, 1206620, 1206621 EPA 8260C 8/6/2009 08/08/2009 Farzad Booeshaghi 1206622, 1206623, 1206624, 1206625, 1206626, 1206627, 1206628, 1206629, 1206631, 1206835, 1206887 EPA 8270D 8/6/2009 08/08/2009 Hoor Shaik 08/11/2009 Mohammad Ghaffari 1206658, 1206660, 1206661, 1206662, 1206663, 1206664 EPA 8270D 8/6/2009 08/08/2009 Hoor Shaik 08/12/2009 Mohammad Ghaffari 1206665, 1206666 EPA 8270D 8/6/2009 08/10/2009 Hoor Shaik 08/13/2009 Mohammad Ghaffari 1206655, 1206667, 1206668 EPA 8270D 8/6/2009 08/11/2009 Hoor Shaik 08/12/2009 Mohammad Ghaffari 1206656, 1206669, 1206827 EPA 8270D 8/6/2009 08/11/2009 Hoor Shaik 08/13/2009 Mohammad Ghaffari 1206657, 1206671 EPA 900.0 8/6/2009 08/12/2009 Florida RadioChemistry Service 1206395, 1206396, 1206397, 1206398, 1206399, 1206400, 1206579, 1206580, 1206581, 1206582 SIS-2009-08-06-01 Serial Number: 0043851 Chemical Analysis Report Page 93 of 93 Preparation and Analysis Log Received Prep Analysis Date Date/Time Prepared by Date/Time Analyzed by Associated Samples Ref. Method EPA 900.0 8/6/2009 08/13/2009 Florida RadioChemistry Service 1206586, 1206587, 1206588, 1206589, 1206590, 1206591, 1206592, 1206839, 1206840, 1206841, 1206842 EPA 903.1 and Ra-05 8/6/2009 08/17/2009 Florida RadioChemistry Service 1206389, 1206390, 1206391, 1206392, 1206393, 1206394 EPA 903.1 and Ra-05 8/6/2009 08/19/2009 Florida RadioChemistry Service 1206389, 1206390, 1206391, 1206392, 1206393, 1206394 FL-PRO 8/6/2009 08/07/2009 Hoor Shaik 08/11/2009 Mohammad Ghaffari 1206673, 1206674, 1206675, 1206676, 1206678, 1206679, 1206680, 1206681 FL-PRO 8/6/2009 08/09/2009 Hoor Shaik 08/12/2009 Mohammad Ghaffari 1206682, 1206684, 1206685, 1206686, 1206687, 1206689, 1206828, 1206829 FL-PRO 8/6/2009 08/09/2009 Hoor Shaik 08/13/2009 Mohammad Ghaffari 1206683