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Dear FGS Friends and Customers,

Happy New Year from the Florida Geological Survey and welcome to the Winter edition of our newsletter! In this issue of News and Research, it’s our pleasure to share progress on geologic and potentiometric surface mapping, data preservation efforts and an informative article about the role of state geologists across the country.  

In other news, the FGS celebrated Earth Science Week in October and was honored to receive this proclamation, signed by Governor Rick Scott. Also, in case you missed it, check out the Weather Channel’s "Secrets of the Earth" series – you will see familiar karst in the Sinkholes episode, which aired last month.

Best Regards,

Jonathan D. Arthur, Ph.D., P.G.
Director and State Geologist
Office of the Florida Geological Survey
Florida Department of Environmental Protection

In This issue Bar

•GEOFACT - Iron and Redox Reactions in Florida Rocks   More…

•FGS Director Invests Time Serving as AASG President More…

•Middle Suwannee Basin Dye Traces Underway   More…

•FGS Receives Grant for Scanning and Data Development   More…

•FGS Provides Maps to National Geologic Database More…

•Potentiometric Surface Mapping Progresses at FGS More…

•See Previous Editions Of FGS News and Research More…

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Iron and Redox Reactions in Florida Rocks

Scanning electron micrograph showing iron sulfide framboids in carbonate rock Naturally occurring iron minerals in Florida’s subsurface rocks have a high sorption capacity, which is the ability to take up or hold other metals. Because of iron’s sorption ability, it can be associated with a variety of trace metals including arsenic, vanadium, antimony, molybdenum, and uranium. The amounts of these metals fluctuate depending on the local oxidation or reduction (redox) conditions and the minerals present. Iron is redox-sensitive and associates with iron sulfides under reducing conditions, and iron oxides under oxidizing conditions.

Of the trace metals mentioned above, the presence of arsenic in groundwater is of particular concern because of its toxicity, and its levels fluctuate. In Florida’s rocks, arsenic has been found to be mostly associated with iron oxides and iron sulfides which are present in very small amounts in limestone. Arsenic and other sorbed metals can be liberated from the surfaces of iron sulfide minerals, as iron sulfides are unstable and dissolve in the presence of oxidants. As a result of this process, the iron will form iron oxides. The liberated trace metals will sorb to the newly formed iron oxides, unless there are more strongly sorbing compounds present such as phosphate and bicarbonate. It is in this case that arsenic could remain in the groundwater.

Under anaerobic (oxygen-devoid) conditions, iron oxides are reductively dissolved by microbial processes, and arsenic and other trace metals will be released into the groundwater. If conditions remain reduced long enough, iron sulfides will form. However, because this process is slower than the oxidizing process, trace metals like arsenic may remain in solution longer during reduced conditions.

Human activities can directly influence redox conditions and the geochemical character of the subsurface. Over-pumping, aquifer recharge with oxygenated surface water, septic tanks, and introduction of organic carbon can disturb the geochemical environment by changing the location of the redox zone. This can lead to the release of unwanted trace metals into local groundwater.

Contact person/info: Cindy Fischler 

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FGS Director Invests Time Serving as AASG President

AASG logo

Florida Geological Survey Director Dr. Jon Arthur currently serves as President of the Association of American Geologists (AASG), and it seems appropriate to share with our FGS friends and colleagues why the time is invested. The AASG was founded in 1908 for the purpose of advancing the science and the practical application of geology in the United States. Its membership includes chief executives of each state’s geological survey. The objectives of the association are to improve the work of State Geological Surveys, improve methods of assembling data and disseminating the results and to achieve effective coordination of work with federal and state agencies.

The AASG routinely collaborates with many federal agencies, including the Department of Energy, Agriculture (National Resources Conservation Service, US Forest Service), Department of the Interior (National Park Service, the Bureau of Ocean and Energy Management, and the US Geological Survey [USGS]), the Environmental Protection Agency, and the National Aeronautics and Space Administration. Members of the AASG meet twice per year in Washington, D.C. to coordinate with and bring forward issues of national importance to a variety of public and private entities. In addition to the agencies listed above, the AASG meets with US House and Senate committees, Office of Science Technology Policy, National Research Council, Library of Congress, National Mining Association, Geological Society of America and the American Geosciences Institute, to name a few.

The AASG in cooperation with the USGS was instrumental in the enactment and subsequent reauthorizations of the National Geologic Mapping Act of 1992, which recognizes the importance of continued geologic mapping for exploration and development of mineral, energy, and water resources, characterizing sites for toxic and nuclear waste disposal, land use evaluation for environmental protection, earthquake hazards reduction, predicting volcanic hazards, reducing losses from landslides, mitigating effects of coastal and stream erosion, siting of critical facilities and basic earth-science research. The FGS actively participates in STATEMAP, the state geological mapping component of the National Cooperative Geological Mapping program supported by the 1992 Act.

A similar AASG - USGS partnership also helped bring forth the National Geological and Geophysical Data Preservation Program, established by the Energy Policy Act of 2005. Reauthorization of this act is currently proposed in HR 5066, which was recently supported by Dr. Arthur’s written and verbal testimony before the US House Subcommittee on Energy and Mineral Resources. The AASG also supports the USGS National 3D Elevation Project (see the FDEP Florida Fact Sheet).

Contact person/info: Dr. Jonathan Arthur 

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Middle Suwannee Basin Dye Traces Underway

Map of one middle Suwannee Basin study area.

As a component of the Suwannee River Water Management District-funded Middle Suwannee Basin Springshed Interpretation project, FGS researchers have recently initiated two dye trace studies aiming to refine Troy Spring’s springshed and determine Falmouth Spring’s interconnectivity with various other springs. Environmentally safe fluorescent dyes are a proven method for confirming groundwater flow connection in karst terrain.

Rhodamine dye was introduced into Falmouth Spring (which is actually a karst window) in Suwannee County in early September. Over the next 12 days, the dye was detected in Lime Spring (Little Gem), Lime Sink Run, Ellaville Springs, and Suwannacoochee Springs, confirming a groundwater connection. Automated water samplers, backed up by charcoal packets, were deployed at the springs to capture the dye as it arrived. Since the dye is not typically detectable to the naked eye downstream, samples were sent to a specialized laboratory for analysis.

The second dye trace was initiated in the Little River Trace (Suwannee County) in early October. Rhodamine dye was released into a karst window and fluorescein dye was released into a swallet. Both dye introduction sites were located using LiDAR imagery and field reconnaissance. Automated water samplers and charcoal packets were installed at Mearson, Troy and Little River Springs. None of the water samples for this trace have been analyzed at present, however, analysis of the first few sets of charcoal packets indicate both rhodamine and fluorescein dye emerged at Little River and Troy Springs with only fluorescein dye being detected at Mearson Spring. The results of these traces will be used in conjunction with other data in the interpretation of land areas contributing flow to some of the springs within the basin.

Contact person/info: Tom Greenhalgh  

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Geophysical log of the type to be scanned and digitized.

The FDEP/FGS has been approved to continue scanning and metadata development work started in 2011 for geophysical logs in the FGS sample collection. Approximately 5,300 of the 7,800 geophysical log documents stored at the FGS have been previously scanned and documented as part of the National Geological and Geophysical Data Preservation Program (NGGDPP) grant program awards. Metadata along with other important information from the log headers will be entered into the FGS wells database where it can be linked to other well information.

Resistivity, Gamma, and Neutron logs are the most valuable logs, especially at depths below the Avon Park formation. There is currently an increased interest in these lower geologic formations for both natural gas exploration and lower Floridan Aquifer studies. It is anticipated that an increase in requests for this information will occur in the near future from both the public and private sectors. In addition to completing the scanning of paper logs, the FGS is also digitizing these select logs into LAS files to improve utility and access to this valuable geologic information.

All geophysical logs will be made publicly available once scanning is completed. This NGGDPP project began in September 2014 and will end in September 2015.

Contact person/info: Michelle Ladle 

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FGS Provides Maps to National Geologic Database

Picture of NGMDB Florida map page.

The National Geologic Map Database (NGMDB) is a congressionally mandated project jointly led by the Association of American State Geologists (AASG) and the U.S. Geological Survey (USGS). The database is a compilation of over 88,000 geologic reports, maps and other geologic information, some of which date back to the 1800s. The database is searchable and also provides references for each geologic product found in the database.

The data in the NGMDB are served through a web-based viewer called MapView. This interactive and scalable viewer allows the user to scale up and down (zoom in and out) as needed, in areas where geologic map data exist. Users can see geologic map data from different time periods, map scales, and projects all by the click of a mouse. Instead of aerial imagery as used in databases like Google Earth, the viewer displays geologic data. For the first time, this project allows access to a large and searchable archive of geoscience information by selecting a geographic region of interest on an interactive map.

The FGS has been producing surficial and bedrock geologic maps since 1907. The latest geologic maps covering parts of Florida have been produced under the STATEMAP program. This program, which has been ongoing for the past 20 years in Florida, is jointly funded by the USGS and FGS. The maps, along with other FGS map products, have been incorporated into the NGMDB.  To view the NGMDB data, visit http://ngmdb.usgs.gov/maps/mapview/

Contact person/info: Harley Means 

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Picture of May, 2013 Potentiometric Surface Map of Florida

The FGS Applied Geoscience Services Section is actively engaged in the production of statewide potentiometric surface maps of the upper Floridan aquifer system. Potentiometric surface maps illustrate the elevation to which groundwater rises in cased wells, and can serve as one barometer of aquifer health. The mapping is being conducted in cooperation with the state’s five water management districts. The districts provide water-level measurements obtained from monitor wells twice a year in May and September. The data are converted using geo-statistical methods to 10 foot contour lines on the map representing the water-level surface of the aquifer. Maps are anticipated to be updated in December and July of each year.

Potentiometric surface maps represent a snap shot in time and do not represent the dynamic changes of water levels within the aquifer. They can, however, be compared with historic maps to determine regional water level changes over time. Such changes may also be correlated to both natural influences, such as seasonal rainfall or drought as well as anthropogenic influences.

Similar to the effort undertaken by the NGMDB, the FGS has recently produced an ArcGIS Online interactive map that depicts historic statewide upper Floridan aquifer potentiometric surface maps. Individual contour maps can be viewed by selecting the map of interest. These maps range from a pre-development upper Floridan aquifer potentiometric surface map to an upper Floridan aquifer map for September 2012. The map has colored contour lines and well points and can be viewed at different scales using a map viewer that is similar to MapView. It allows users to navigate various data layers, including the potentiometric surface layer.

Historic and current statewide potentiometric maps can be viewed on FDEP’s ArcGIS Online site at fdep.maps.arcgis.com

GIS data for historic and current statewide potentiometric surface maps can be downloaded at www.dep.state.fl.us/gis/datadir.htm

Contact person/info: Jim Cichon  

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